resumo
Chiral porous inorganic materials, lanthanide pyrophosphates, were prepared from chiral porous metal-organic framework precursors, which upon thermal decomposition transpose their chirality and porosity onto the inorganic framework. It is argued that this synthesis concept may be extended to other chiral porous inorganic solids.
palavras-chave
SPONTANEOUS RESOLUTION; SOLIDS; ZEOLITE
categoria
Chemistry
autores
Shi, FN; Paz, FAA; Ribeiro-Claro, P; Rocha, J
nossos autores
Fa-Nian Shi
Investigador
Filipe Alexandre Almeida Paz
Investigador Principal
João Rocha
Diretor
Paulo Jorge Almeida Ribeiro Claro
Professor Associado com AgregaçãoGrupos
1 - Nanomateriais inorgânicos funcionais e híbridos orgânico-inorgânico
6 - simulação computacional e modelação multi-escala
Projectos
Centre for Research in Ceramics and Composite Materials - CICECO (LA0011: 2013-2014) (PEst-C/CTM/LA0011/2013)
Nano-sized Functional Metal-Organic Frameworks Based on Lanthanide Polyphosphonates (PTDC/QUI-QUI/098098/2008)
Novel smart multi-functional Transition metal-Rare earth-Organic- Frameworks (TROFs) toward tunable magnetic and luminescent properties (PTDC/CTM-NAN/119994/2010)
agradecimentos
We thank Fundacao para a Ciencia e a Tecnologia (FCT), FEDER, QREN, COMPETE (PEst-C/CTM/LA0011/2013). F.-N. SHI acknowledges FCT for the Ciencia 2007 program and the project PTDC/CTM-NAN/119994/2010. F. A. A. P. also wishes to thank FCT for financial support through the R&D project PTDC/QUI-QUI/098098/2008. Drs Moises Pinto and Sergio Santos are acknowledged for, respectively, providing the gas adsorption data and some structure ab initio calculations.