CICECO » João Rocha

Perfil biográfico

Researcher ID: http://www.researcherid.com/rid/A-2486-2010

ORCID: http://orcid.org/0000-0002-0417-9402

Scopus Author ID: 7202074281

Google Scholar: http://scholar.google.com/citations?user=FVscvjQAAAAJ

João Rocha é Professor Catedrático de Química na Universidade de Aveiro, e Director do Instituto de Materiais de Aveiro-CICECO, o maior Instituto Nacional de Investigação em Ciência e Engenharia de Materiais.

PRÉMIOS E DISTINÇÕES

João Rocha (n. 1962) é membro da European Academy of Sciences (EURASC) e Académico Correspondente da Academia das Ciências de Lisboa (Química) desde 2006, Fellow da Royal Society of Chemistry e da Chemistry Europe, e Director do Laboratório Associado "Instituto de Materiais de Aveiro"-CICECO desde 2002. Entre 2012 e 2014 foi membro do Conselho Nacional de Ciência e Tecnologia (presidido pelo Primeiro Ministro). Em 2017 recebeu o prémio Ferreira da Silva (mais alta distinção) e em 2021 o prémio Romão Dias ambos da Sociedade Portuguesa de Química, em 2020 o prémio Luso-Francês da Société Chimique de France, em 2015 o prémio Medinabeitia-Lourenço, da Real Sociedad Española de Química, em 2004 o Prémio de Excelência Científica, da Fundação para a Ciência e a Tecnologia (FCT), e em 1990 um prémio do Emmanuel College, Cambridge (por ter terminado o doutoramento em 2 anos).

EDUCAÇÃO

Licenciou-se em Física e Química, via ensino, em 1985, tendo leccionado um ano na Escola Secundária de José Estêvão em Aveiro. Nesse mesmo ano, tornou-se Assistente Estagiário de Departamento de Química da Universidade de Aveiro.

Em 1988 partiu para Inglaterra onde se doutorou em 1990 no Department of Chemistry da University of Cambridge, com uma dissertação sobre Ressonância Magnética Nuclear (RMN) do Estado Sólido de caulinite e materiais relacionados, sob a orientação do Prof. Jacek Klinowski. Durante cerca de um ano, permaneceu neste Departamento e grupo como pós-doutorado, desenvolvendo estudos de RMN de sólidos de materiais zeolíticos.

Em meados de 1991 regressou ao Departamento de Química da Universidade de Aveiro, onde tem permanecido. Fez a Agregação em Química Inorgânica em 1997.

REGISTO CIENTÍFICO

João Rocha publicou cerca de 515 artigos em revistas do Science Citation Index e 25 capítulos de livro, que receberam (Google Scholar) ca. 24,500 citações, h index =76 (Scopus, respectivamente ca. 20,300 e 66), e 5 patentes. Proferiu mais de duas centenas e meia de palestras, muitas convidadas, a maior parte das quais em Congressos e instituições científicas internacionais. Orientou 43 pós-doutorados e 32 alunos de doutoramento. Coordenou mais de duas dezenas de projectos (6 Europeus, como PI nacional) e foi consultor de várias empresas.

ACTIVIDADE PROFISSIONAL

É Professor no Departamento de Química da Univdersidade de Aveiro desde 1991, tendo sido promovido a Professor catedrático em 1999. Em Cambridge, fez tutoriais de Química Inorgânica e de RMN. Em 2010 foi professor convidado da Universidade de Oviedo. Foi Vice-Director do European Multifunctional Materials Institute (follow up do European Network of Excellence, FAME).

João Rocha é membro do júri do prémio IBM Portugal desde 2011, Chair da Commission on Inorganic and Mineral Structures (findo) e consultor da Commission on NMR Crystallography and Related Methods da Internacional Union of Crystallography (IUCr). Foi avaliador do painel PE5 das European Research Council Senior & Starting Grants. Tem tido uma extensa actividade editorial, nomeadamente Royal Society of Chemistry Nanoscience and Nanotechnology Book Series Editor (finda), Chair do editorial board do European Journal of Inorganic Chemistry (até 2014), e membro dos editorial boards de Solid State NMR (findo), Chemistry a European Journal, Solid State Sciences e Editorial Advisor for BMC Chemical Engineering. É membro da Sociedade Portuguesa de Química (esteve na direcção como Secretário Adjunto em 1998-2000), American Chemical Society e Materials Research Society.

Representou a FTC em Chairman of the European Research Councils of Chemistry (2005-07) e no sincrotrão ESRF-Grenoble (2004-06). Foi membro do Conselho Científico (Ciências Exatas) da FCT (2005-06), Secretário Executivo do Instituto de Investigação da Universidade de Aveiro (1999-2000). Coordenou o painel de avaliação de bolsas da FCT na área das Ciências e Engenharia de Materiais. Em 2003 coordenou o painel que avaliou as Unidades de Investigação nesta área. Integra o painel de avaliação dos projectos franceses LABEX.

Tem estado envolvido em alguns projetos (incluindo QREN) com o sector empresarial, desenvolvendo uma atividade regular de consultoria técnico-científica.

O seu grande interesse em divulgação e promoção da Ciência foi motivado pela licenciatura em Ensino de Física e Química. Foi consultor de novos programas de Química do 10º, 11º e 12º anos (2000 – 2002). Em Outubro de 2004 coordenou uma equipa de trabalho que preparou, a pedido do Secretário de Estado da Educação, um documento sobre os principais problemas do ensino da Química em Portugal (Básico e Secundário).

OUTROS INTERESSES

Enquanto Secretário Adjunto da Sociedade Portuguesa de Química (1998-2000), relançou a “Divisão de Ensino e Divulgação da Química” e as “Olimpíadas Nacionais de Química”. Participou na organização em Aveiro da 6th European Conference on Research in Chemical Education. Faz anualmente palestras em Escolas Secundárias e participa em “Cafés de Ciência”, etc. Tem escrito pequenos artigos de divulgação para jornais regionais, Público e Expresso. Participou em alguns programas de rádio e de TV. É apaixonado pela Natureza e é um bird watcher experiente. Outras paixões sérias: karaté (1º Dan), jardinagem, música (ópera, em particular), fotografia da Natureza e poesia.

Interesses científicos

CONTRIBUIÇÕES CIENTÍFICAS PRINCIPAIS

- Concebeu uma nova classe de materiais semelhantes aos zeólitos: silicatos de metais de transição e de lantanídeos com nanoporos (cerca de uma centena de silicatos de Ti, Zr, V, Nb, Cu, Sn, Ca, Y, Ce e lantanídeos, denominados AV e AM). Clarificando, estes materiais são estequiométricos e não zeólitos dopados com metais, cujo arquétipo é o titanossilicato ETS-10 (Nature, 367: 347, 1994). Temos investigado aplicações em luminescência (J. Am. Chem. Soc., 137: 3051, 2015), catálise, adsorção e separação de gases, permute iónica, magnetismo e em agentes de contraste para MRI. Excepcionalmente, um silicato de zircónio nanoporoso encontrou aplicação comercial como fármaco para o tratamento da hipercalemia (excesso de potássio no sangue, Inorg. Chim Acta, 356: 19, 2003).

- Desenvolveu sofisticadas Redes Metalo-Orgânicas e polímeros de coordenação contendo iões lantanídeos (Angew. Chem. Int. Ed., 47: 1080, 2008), em particular para aplicação em nanotermometria (Adv. Funct. Mater., 25: 2824, 2015).

- Desevolveu materiais cristalino híbridos orgânico-inorgânicos ferroeléctricos fotorresponsivos com uma temperatura de Curie alta (423 K), um avanço importante no sentido do desenvolvimento de memórias ferroeléctricas multi-estado, interruptores ópticos, e diversos dispositivos optoelectrónicos (J. Am. Chem. Soc., 142: 16990, 2020).

- Desenvolveu nanopartículas de óxidos para uso como agentes de contraste (ACS Nano, 4: 5339, 2010), em imagem bimodal (Biomater., 33: 925, 2012), e em nanotermometria (Nature Nanotech, 11: 851, 2016; Adv. Mater., 35: 4868, 2013).

- Concebeu materiais para libertação controlada de moléculas pequenas com actividade farmacológica (incluindo NO, J. Am. Chem. Soc., 133: 6396, 2011).

- Concebeu materiais que podem contribuir para a criação de um Mundo mais sustentável (por exemplo, redes anti-mosquito, ACS Appl. Mater. Interfaces, 9: 22112, 2017; e captura do ião uranilo Angew. Chem., Intl. Ed., 58: 1, 2019).

- Criou ca. 40 catalisadores heterogéneos baseados em sílicas mesoporosas funcionalizadas com complexos metálicos (J. Mater. Chem., 12: 1735, 2002).

- Elucidou a estrutura de minerais (em particular argilas) usando técnicas de difracção de raios-X e ressonância magnética nuclear, RMN (J. Am. Chem. Soc., 113: 7100, 1991; J. Am. Chem. Soc., 114: 6867, 1992; Am. Mineral., 103: 812, 2018).

- Foi pioneiro no desenvolvimentos de técnicas de RMN de sólidos para o estudo de núcleos quadrupolares (I>1/2) (Solid State NMR, 21: 61, 2002; Magn. Reson. Chem., 41: 679, 2003) e de ¹H (J. Mag. Reson., 199: 111, 2009).

IMPACTO SOCIETAL

Rocha é conhecido principalmente por ter alargado o domínio dos materiais zeolíticos do alumínio aos metais de transição e lantanídeos tendo, nomeadamente, desenvolvido vários silicatos de zircónio nanoporosos. Um destes materiais, AV-13 (Inorg. Chim Acta, 356: 19, 2003), numa forma modificada, veio a ser estudado pela empresa Americana ZS Pharma, agora parte da AstraZeneca, para tratar doentes que sofrem de hipercalemia (excesso de K⁺ no sangue). Como resultado, o novo fármaco Lokelma (via oral) foi recentemente aprovado pelas agências americana (FDA) e europeia (EMA) do medicamento, estando prestes a chegar ao Mercado.

Principais colaboradores

Luís Carlos, Artur Silva, Filipe Paz, Luís Mafra, Zhi Lin, Duarte Ananias, Manuel Souto, Carlos Silva, Carlos Brites; Carlos Geraldes (Coimbra); Marie-Helene Delville (Bordeaux); Xiaogang Liu (NUS Singapore); Reda Abdelhameed (National Research Centre, Giza, Egipt)

Actividade pedagógica

O João encontra-se, presentemente, em licença sabática. Normalmente, rege disciplinas de Química Inorgânica e de Materiais e Espectroscopia de RMN de Sólidos.

Grupo de Investigação

João orientou 43 pós-docs e 32 Ph.D. students. Presentemente, o seu grupo tem forte associação/integra:

Colaboração intensa com os grupos dos Doutores Filipe Paz, Luís Mafra, Zhi Lin, e Prof. Manuel Souto

Investigadores - Duarte Ananias, Isabel Vieira

Técnicos doutorados - Paula Brandão (XRD), Paula Santos (NMR)

Pós-Doutorados - Wei Xu (Andrei Kholkin)

Alunos de doutoramento - Patrícia Vaz (Artur Silva, Samuel Guieu), Carlos Bornes (L Mafra), Orlando Oliveira (Laura Salonen), Celso Cardoso (Eduarda Pereira), Thiago Silva (Luís Carlos), Gonçalo Valente (Manuel Souto), Luis Fontes (Samuel Guieu , Artur Silva), Judite Resende (Sónia Santos, Armando Silvestre), Luís Veríssimo (Andrei Kholkin)

Bolseiros de investigação - Andrea Simões

Projectos

PROJECTOS TERMINADOS

Coordenou e participou em várias dezenas de projectos:
European - JOULE(II) and 2 Human Capital and Mobility; "Materials Network for the Atlantic Area" financed by INTERREG IIIB.
- COST Action MP1202, "RATIONAL DESIGN OF HYBRID ORGANIC-INORGANIC INTERFACES: THE NEXT
STEP TOWARDS ADVANCED FUNCTIONAL MATERIALS"
National - 3 PRAXIS XXI, STRIDE; 3 POCTI other small projects.
National(PORC-MaisCentro)
- “Biomaterials for Regenerative Medicine", SCT_2011_02_030_4872

PROJECTOS ACADÉMICOS EM CURSO

- European Joint Doctorate in Functional Materials Research, European Commission, Contract: 641640, Co-PI, 2015-06 to 2019-05.

- “Nanoheaters and nanothermometers playing together: towards applications in Brownian motion and hyperthermia, FCT, PTDC/CTMNAN/4647/2014; participant, 2016-07 to 2019-06.

- “From inexpensive raw materials to new luminescent glass materials”, FCT, PTDC/QEQQIN/3007/2014, Co-PI, 2016-05 to 2019-04.

- "Protein aggregation across the lifespan – pAGE", CENTRO-01-0145-FEDER-000003, Co-PI, 2017-2020

PROJECTOS COM EMPRESAS (detalhes confidenciais)

- Coma empresa americana ZS Pharma, agora integrada na Astra Zeneca, PI, 2016-04 to 2018-03
- "Smart Green Homes", com a Bosch Thermotechnology, Co-PI, 2016-10 to 2020-09.

PROJECTO FCT QUE FINANCIA OF LABORATÓRIO ASSOCIADO CICECO

FCT, UID/CTM/50011/2013, PI, 2015-01 to 2017-12

Publicações seleccionadas

1. MATERIAIS MICROPOROSOS

Silicatos de metais de transição (e Sn)

1) Anderson, M. W., Terasaki, O., Ohsuna, Philippou, A., MacKay, S. P., Ferreira, A., Rocha, J. and Lidin, S., "Structure of the microporous titanosilicate ETS-10" Nature, 367: 347 (1994).

2) Anderson, M. W., Philippou, A., Ferreira, A., Lin, Z. and Rocha, J., "Al, Ti, avoidance in the microporous titano-aluminosilicate ETAS-10", Angew. Chem., Int. Ed. Engl., 34: 1003 (1995).

3) Anderson, M. W., Agger, J. R., Luigie, D.-P., Baggaley, A. K. and Rocha, J., "Cation sites in ETS-10: 23Na 3Q MAS NMR and lattice energy minimisation calculations", J. Phys. Chem.Chem. Phys., 1: 2287 (1999).

4) Lin, Z., Rocha, J., Ferreira, P., Thursfield, A., Agger, J. R. and Anderson, M. W., "Synthesis and structural characterisation of microporous framework zirconium silicates", J. Phys. Chem. B, 103: 957 (1999).

5) Ferreira, A., Lin, Z., Rocha, J., Morais, C. M., Fernandez, C., “Ab initio structure determination of a small-pore framework sodium stannosilicate”, Inorg Chem., 40, 3330-3335 (2001).

6) Brandão, P., Almeida Paz, F. A. and Rocha, J., “A novel microporous copper silicate: Na₂Cu₂Si₄O₁₁×2H₂O”, Chem. Commun., 171-173 (2005).

7) Ananias, D., Almeida Paz, F. A., Carlos, L. D., Rocha, J., “Chiral microporous rare-earth silico-germanates: Synthesis, structure and photoluminescence properties”, Micropor. Mesopor. Mater., 166: 50-58 (2012).

8) Bornes, C., Sardo, M., Lin, Z., Amelse, J., Fernandes, A., Ribeiro, M. F., Geraldes, C., Rocha, J., Mafra, L., “¹H-³¹P HETCOR NMR elucidates the nature of acid sites in zeolite HZSM-5 probed with trimethylphosphine oxide”, Chem Commun., 55: 12635-12638 (2019).

Silicatos de Terras-Raras

1) Rocha, J., Ferreira, P. Carlos, L. D. and Ferreira, A., “The first example of a microporous framework cerium-silicate”, Angew. Chem Int Ed., 39: 3276-3279 (2000).

2) Ananias, D., Ferreira, A., Rocha, J., Ferreira, P., Rainho, J. P:, Morais, C. and Carlos, L. D., “Novel microporous framework europium and terbium silicates”, J. Am. Chem. Soc., 123, 5735-5742 (2001).

3) Ferreira, A., Ananias, D., Carlos, D., Morais, C. M. and Rocha, J., “Novel microporous lanthanide silicates with tobermorite-like structure”, J. Am. Chem. Soc., 125: 14573-14579 (2003).

4) Ananias, A., Paz, F. A. A., Carlos, L. D., Geraldes, F. G. C., Rocha, J., “Optical detection of solid-state chiral structures with unpolarized light and in the absence of external fields”, Angew. Chem. Int. Ed., 45: 7938-7942 (2006).

5) Ananias, D., Ferdov, S., Paz, F. A. A., Sá Ferreira, R. A., Ferreira, A., Geraldes, C. F. G. C., Carlos, L. D., Lin, Z., Rocha, J., “Photoluminescent layered lanthanide silicate nanoparticles”, Chem. Mater., 20: 205-212 (2008).

6) Ananias, D., Kostova, M., Paz, F. A. A., Neto, A. N. C., De Mora, R. T., Malta, O. L., Carlos, L. D., Rocha, J., "Molecule-like Eu³⁺ dimer enbedded in an extended system exhibits unique photoluminescence properties", J. Am. Chem. Soc., 131: 8620-8626 (2009).

7) Ananias, D., Almeida Paz, F. A., Yufit, D. S., Carlos, L. D., Rocha, J., “Photoluminescent thermometer based on a phase-transition lanthanide silicate with unusual structural disorder”, J. Am. Chem. Soc., 137: 3051-3058 (2015).

8) Figueiredo, R., de Melo, M. M. R., Portugal, I., Ananias, D., Rocha, J., Silva, C. M.,“Cs⁺removal and optical detection by microporous lanthanide silicate Eu-AV-20 in a fixed-bed column”, Chem. Eng. J.,286: 48-58 (2016).

9) Ananias, D., Paz, F. A. A., Carlos, L. D., Rocha, J., “Near-infrared ratiometric luminescent thermometer based on a new lanthanide silicate”, Chem. Eur. J., 24: 11962-11935 (2018).

Fosfatos

1) Rocha, J., Esculcas, A. P., Fernandez, C. and Amoureux, J. P., "Two-dimensional triple-quantum ²⁷Al MAS NMR spectroscopic study of the high-temperature phase transformation of microporous VPI-5", J. Phys. Chem., 100: 17889 (1996).

2) Rocha, J., Lourenço, J. P., Ribeiro, M. F., Fernandez, C. and Amoureux, J. P., "Multiple-quantum ²⁷Al MAS NMR spectroscopy of microporous AlPO-40 and SAPO-40", Zeolites, 19: 156 (1997).

3) Shi, Fanian, Almeida Paz, F. A., Ribeiro-Claro, P., Rocha, J., “Transposition of chirality from diphosphonate metal-organic framework precursors onto porous lanthanide pyrophosphates”, Chem. Commun., 49: 11668-11670 (2013). 

2. NANOTUBOS DE ÓXIDOS DE LANTANÍDEOS E NANOPARTÍCULAS DE FLUORETOS

1) Macedo, A. G., Ananias, D., André, P. S., Sá Ferreira, R. A., Kholkin, A. L., Carlos, L. D., Rocha, J., “Functionalization of atomic force microscope tips by dielectrophoretic assembly of Gd₂O₃:Eu³⁺ nanorods”, Nanotechnol., 19: 295702 (2008).

2) Macedo, A. G., Ferreira, R. A. S., Ananias, D., Reis, M. S., Amaral, V. S., Carlos L. D., Rocha, J., “Effects of phonon confinement on anomalous thermalization, energy transfer and upconversion in Ln³⁺-doped Gd₂O₃ nanotubes”, Adv. Funct. Mater., 20: 624-634 (2010).

3) Debasu, M. L., Ananias, D., Macedo, A. G., Rocha, J., Carlos, L. D., “Emission-decay curves, energy-transfer and effective-eefractive index in Gd₂O₃:Eu³⁺ nanorods”, J. Phys. Chem. C, 115: 15297–15303 (2011).

4) Debasu, M. L., Ananias, D., Pastoriza-Santos, I., Liz-Marzan, L. M., Rocha, J., Carlos L. D., “All-In-One OpticalHeater-Thermometer Nanoplatform Operative from Room Temperature to 2000 K”, Adv. Mater., 35: 4868-4874 (2013).

5) Balabhadra, S., Debasu, M. L., Brites, C. D. S., Nunes, L. A. O., Malta, O. L., Rocha, J., Bettinelli, M., Carlos, L. D.,“Boosting the sensitivity of Nd³⁺-based luminescent nanothermometers”, Nanoscale, 7: 17261-17267 (2015).

6) Balabhadra, S., Rocha, J., Debasu, M., Brites, C., Carlos L., “Implementing luminescence thermometry at 1.3 μm using(GdNd)₂O₃nanoparticles”, J. Luminescence, 180: 25–30 (2016).

7) Brites, C. D. S., Xie, X., Debasu, M. L., Qin, X., Rocha, J., Liu, X., Carlos, L. D., “Instantaneous Ballistic Velocity of Suspended Brownian Nanocrystals Measured by Upconversion Nanothermometry”, Nature Nanotech., 11, 851–856 (2016).

3. MATERIAIS HÍBRIDOS ORGÂNICOS-INORGÂNICOS

Redes Metalo-Orgânicas e Materiais Relacionados

1) Mafra, M., Almeida Paz, F. A., Shi, F.N., Rocha, J., Trindade, T., Fernandez, C., Makal, A., Wozniak, K., Klinowski, J., “Hydrothermal synthesis and structural characterization of a Ge-pmida binuclear complex: X-ray diffraction and HETCOR MAS NMR with FS-LG decoupling”, Chem. Eur. J., 12: 363-375 (2006).

2) Mafra, L., Paz, F. A. A., Shi, F-N., Sá Ferreira, R. A., Carlos, L. D., Trindade, T., Fernandez, C., Klinowski, J. and Rocha, J., “Crystal structure, Solid-State NMR spectroscopic and photoluminescence studies of Organic-Inorganic Hybrid Materials (HL)6[Ge6(OH)6(hedp)6]·2(L)·nH2O, L=hqn or phen”, Eur. J. Inorg. Chem., 4741-4751 (2006).

3) Cunha-Silva, L., Mafra, L., Ananias, D., Carlos, L. D., Rocha, J., Paz, F. A. A., “Photoluminescent lanthanide-organic 2D networks: a combined synchrotron powder X-ray diffraction and solid-state NMR study”, Chem. Mater., 19: 3527-3538 (2007).

4) Shi, F. N., Cunha-Silva, L., Sá Ferreira, R. A., Mafra, L., Trindade, T., Calos, L. D., Almeida Paz, F. A. and Rocha, J., “Interconvertable Modular Framework and Layered Lanthanide(III)-Etidronic Acid Coordination Polymers”, J. Am. Chem. Soc., 130: 150-167 (2008).

5) Harbuzaru, B. V., Corma, A., Rey, F., Atienzar, P., Jordá, J. L., García, H., Ananias, D., Carlos L. D. and Rocha, J., “Metal-organic nanoporous structures with anisotropic photoluminescence and magnetic properties and their use as sensors”, Angew. Chem. Int. Ed., 47: 1080-1083 (2008).

6) Harbuzaru, B. V., Corma A., Rey, F., Jordá, J. L., Ananias D., Carlos, L. D., Rocha, J., "A miniaturized linear pH sensor based on a highly photoluminescent self-assembled Europium(III) metal organic framework", Angew. Chem. Int. Ed., 48: 6476-6479 (2009).

7) Rocha, J., Shi, F. N., Almeida Raz, F. A., Mafra, L., Sardo, M., Cunha-Silva, L., Chisholm, J., Ribeiro-Claro, P. and Trindade, T., “2D-2D-0D stepwise deconstruction of a water Framework templated by a nanoporous organic-inorganic hybrid host”, Chem. Eur. J., 16: 7741-7749 (2010).

8) Rocha, J., Carlos, L. D., Paz, F. A. A., Ananias, D.,“Luminescent multifunctional lanthanides-based metal-organic frameworks”, Chem. Soc. Rev., 40: 926-940 (2011).

9) Silva, P., Vieira, F., Gomes, A. C., Ananias, D., Fernandes, J. A., Bruno, S. M., Soares, R., Valente, A. A., Rocha, J., Paz, F. A. A., “Thermal transformation of a layered multifunctional network into a metal-organic framework based on a polymeric organic linker”, J. Am. Chem. Soc., 133: 15120-15138 (2011).

10) Rocha, J., Carlos, L. D., Paz, F. A. A., Ananias, D.,“Luminescent multifunctional lanthanides-based metal-organic frameworks”, Chem. Soc. Rev., 40: 926-940 (2011).

11) Paz, F. A. A., Klinowski, J., Vilela, S. M. F., Tomé, J. P. C., Cavaleiro, J. A. S., “Ligand design for functional metal–organic frameworks”, Chem. Soc. Rev., 41: 1088-1110 (2012).

12) Liu, S. R., Ferreira, R. A. S., Almeida Paz, F. A., Cadiau, A., Carlos, L. D., Fu, L. S., Rocha, J., Shi, F. –N., “Highly emissive Zn-Ln metal organic frameworks with an unusual 3D inorganic subnetwork”, Chem. Commun., 48: 7964-7966 (2012).

13) Abdelhameed, R. M., Carlos, L. D., Silva, A., Rocha, J., “Near-infrared emitters based on post-synthetic modified Ln³⁺-IRMOF-3”, Chem. Commun., 49: 5019-5021 (2013).

14) Cadiau, A., Brites, C. D. S., Costa, P. M. F. J., Ferreira, R. A. S., Rocha, J., Carlos, L. D., “Rathiometric nanothermometer based on an emissive Ln³⁺- organic framework”, ACS Nano, 7: 7213–7218 (2013). 

15) Wang, Z., Ananias, D., Carné-Sánchez, A., Brites, C. D. S., Imaz, I., Maspoch, D., Rocha, J., Carlos, L.D., “Lanthanide organic framework nanothermometers prepared by spray drying”, Adv. Funct. Mater., 25: 2824-2830 (2015).

16) Shi, F. N., Almeida, J. C., Helguero, L. A., Fernandes, M. H. V., Knowles, J. C., Rocha, J., “Calcium phosphonate frameworks for treating bone tissue disorders”, Inorg Chem., 54: 9929–9935 (2015).

17) Abdelhameed, R., Kamel, O., Amr, A., Rocha, J., Silva, A., “Anti-mosquito activity of a titanium-based metal–organic framework supported on fabrics”, ACS Appl. Mater. Interfaces, 9: 22112–22120 (2017).

18) Ananias, D., Firmino, A. D. G., Mendes, R. F., Almeida Paz, F. A., Nolasco, M., Carlos, L. D., Rocha, J., “Excimer formation in a Tb-MOF assists luminescence thermometry”, Chem. Mater., 29: 9547-9554 (2017).

19) Wang, X.-F., Chen, Y., Song, L.-P., Fang, Z., Zhang, J., Shi, F., Lin, Y.-W., Sun, Y., Zhang, Y.-B., Rocha, J., “Cooperative capture of uranyl ion by a carbonyl-bearing hierarchical porous Cu-Organic Framework”, Angew. Chem., Intl. Ed., 58: 1-6 (2019).

20) Castells-Gil, J., Mañas-Valero, S., Vitórica-Yrezábal, I. J., Ananias, D., Rocha, J., Santiago, R., Bromley, S. T., Baldoví, J. J., Coronado, E., Souto, M., Espallargas, G. M., “Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal–Organic Frameworks”, Chemistry, Eur. J., 25: 12636-12643 (2019).

Híbridos Amorfos

1) Fu, L., Sá Ferreira, R. A., Silva N. J. O., Carlos, L. D., Zea Bermudez, V. and Rocha, J., “Photoluminescence and quantum yields of urea and urethane cross-linked nanohybrids derived from carboxylic acid solvolysis”, Chem. Mater., 16: 1507-1516 (2004).

2) Nunes, S. C., de Zea Bermudez, V., Cybinska, J., Ferreira E. A. S., Legendziewics, J., Carlos, L. D., Silva, M. M., Smith, M. J., Ostrovskii, D and Rocha, J., “Structure and photoluminescent features of di-amide cross-linked alkylene siloxane hybrids”, J. Mater. Chem., 15: 3876-3886 (2005).

3) Nunes, S. C., de Ze Bermudez, V., Silva, M. M., Smith, M. J., Ostrovskii, D., Sá Ferreira, R. A., Carlos, L. D., Rocha, J., Gonçalves, A., Fortunato, E., “Sol-gel derived potassium-based di-ureasils for smart windows", J. Mater. Chem., 17: 4239 (2007).

4) Carlos, L. D., de Zea Bermudez, Amaral, V. S., Nunes, S. C., Silva, N. J. O., Ferreira, R. A. S., .; Rocha, J, Santilli, C. V. and Ostrovskii, D., "Nanoscopic photoluminescence memory as a fingerprint of complexity in hierarchically-structured self-assembled alkylene/siloxane hybrids", Adv. Mater., 19: 341-348 (2007).

Materiais com Agentes Estruturantes ou com Espécies Intercaladas

1) Rocha, J., Duer, M. J. and Klinowski, J., "Solid-state NMR studies of the molecular motion in the kaolinite:DMSO intercalate", J. Am. Chem. Soc., 114: 6867 (1992).

2) Mafra, L., Paz, F. A. A., Rocha, J., Espina, A., Khainakov, S. A. and Garcia, J. R., “Structural characterisation of layered gamma-titanium phosphate (C6H13NH3)[Ti(HPO4)(PO4)]·H2O”, Chem. Mater., 17: 6287-6294 (2005).

3) Mafra, L., Rocha, J., Fernandez, C. and Paz, F. A. A., “Characterisation of microporous aluminophosphate IST-1 using ¹H Lee-Goldburg techniques”, J. Magn. Reson., 180: 235-243 (2006).

4) Karmaoui, M., Mafra, L., Sá Ferreira, R. A., Rocha, J., Carlos, L. D. and Pinna, N., "Photoluminescent Rare-Earth Based Biphenolate Lamellar Nanostructures", J. Phys. Chem. C, 111: 2539-2544 (2007 ). 

5) Pinto, M. L., Mafra, L., Guil, J. M., Pires, J., Rocha, J., “Adsorption and activation of CO₂ by amine-modified nanoporous materials studied by solid-state NMR and (CO₂)-C-13 adsorption”, Chem. Mater., 23: 1387-1395 (2011).

MCMs Funcionalizados e Organo-Sílicas Mesoporosas Periódicas

1) Nunes, C. D., Valente, A., Pillinger, M., Fernandes, A. C., Romão, C. C., Rocha, J., Gonçalves, I. S., “MCM-41 functionalised with bipyridyl groups and its use as a support for oxomolybdenum(VI) catalysts”, J. Mater. Chem., 12, 1735-1742 (2002).

2) Nunes, C. D., Valente, A. A., Pillinger, M., Rocha, J. and Gonçalves, I. I., “Molecular structure-activity relationship for the oxidation of organic compounds using mesoporous silica catalysts derivatised with bis(halogeno)dioxomolibdenum(VI) complexes”, Chem. Eur. J., 9: 4380-4390 (2003).

3) Bion, N., Ferreira, P., Valente, A., Gonçalves, I. S. and Rocha, J., “Ordered benzene-silica hybrids with molecular-scale periodicity in the walls and different mesopore sizes”, J. Mater. Chem., 13:1910-1913 (2003).

4) Abrantes, M., Gago, S:, Valente, A. A., Pillinger, M., Gonçalves, I. S:, Santos, T. M., Rocha, J. and Romão C. C., “Incorporation of a (cyclopentadienyl)molybdenum oxo complex in MCM-41 and its use as a catalysts for olefin epoxidation”, Eur. J. Inorg. Chem., 4914 (2004).

5) Fu, L., Sá Ferreira, R. A., Valente, A., Rocha, J and Carlos, L. D., “Optically functional nanocomposites with poly(oxyethylene)-based di-ureasils and mesoporous MCM-41”, Micropor. Mesopor. Mater., 94: 185-192 (2006). 

6) Coelho, A. C., Balula, S. S., Bruno, S.M., Alonso, J. C., Bion, N., Ferreira, P., Pillinger, M., Valente, A. A., Rocha, J. and Gonçalves, I. S., “Grafting of Molecularly Ordered Mesoporous Phenylene-Silica with Molybdenum Carbonyl Complexes: Efficient Heterogeneous Catalysts for the Epoxidation of Olefins”, Adv. Synth. Catal., 352: 1759-1769 (2010).

4. NANOMATERIAIS PARA APORTE DE FÁRMACOS E PARA IMAGEM

1) Lin, Z., Ferreira, A., Soares, M. R., Rocha, J., “Ab initio structure determination of novel small-pore metal-silicates: knots-and-crosses structures”, Inorg. Chim Acta, 356: 19-26 (2003).

2) del Arco, M., Cebadera, E., Gutiérrez, S., Martín, C., Montero, M. J., Rives, V., Rocha, J. and Sevilla, M. A., “Mg,Al layered double hydroxides with intercalated indomethacin: synthesis, characterisation and pharmacological study”, J. Pharmacol. Sci., 93: 1649-1658 (2004)

3) del Arco, M., Gutiérrez, S., Martín, C., Rives, V. and Rocha, J., “Synthesis and characterisation of layered double hydroxides (LDH) intercalated with non-steroidal anti-inflamatory (NSAID) drugs”, J. Solid State Chem., 177: 3954-3962 (2004).

4) Braga, S. S., Sá Ferreira, R. A., Gonçalves, I. S., Pillinger, M., Rocha, J., Teixeira-Dias, J. J. C. and Carlos, L. D., “Synthesis, characterisation and luminescence of gamma-cyclodextrin inclusion compounds containing europium(III) and gadolinium(III) tris(beta-diketonates)”, J. Phys. Chem., 106: 11430-11437 (2002).

5) Pereira, G. A., Ananias, D., Rocha, J., Muller, R. N., Vander Elst, L., Peters, J. A. and Geraldes, C. F. G. C., “NMR relaxivity of Ln3+-based zeolite-type materials”, J. Mater. Chem, 15: 3832-3837 (2005). 

6) Pereira, G. A., Norek, M., Peters, J. A., Ananias, D., Rocha, J., and Geraldes, C. F. G. C., “NMR transversal relaxivity of aqueous suspensions of particles of Ln3+-based zeolite type materials”, Dalton Trans., 2241-2247 (2008).

7) Pereira, G. A., Joop, P., Paz, F. A. A., Rocha, J., Geraldes, C., “Evaluation of [Ln(H2cmp)(H2O)] metal organic framework materials for potential application as MRI contrast agents", Inorg. Chem., 49: 2969-2974 (2010).

8) Pinho, S. L. C., Pereira, G. A., Voisin, P., Kassem, J., Bouchaud, V., Etienne, L., Peters, J. A., Carlos, L., Mornet, S., Geraldes, C. F. G. C., Rocha, J., DElville, M.-H., “Fine tuning of the relaxometry of gamma-Fe₂O₃@SiO₂ nanoparticles by tweaking the silica coating thickness”, ACS Nano, 4: 5339-5349 (2010).

9) Pinto, M. L., Rocha, J., Gomes, J. R. B., Pires, J., “Slow release of NO by microporous titanosilicate ETS-4”, J. Am. Chem. Soc., 133: 6396–6402 (2011). 

10) Pinho, S. L. C., Faneca, H., Geraldes, C. F. G. C., Delville, M.-H., Carlos, L. D., Rocha, J., “Lanthanide-DTPA grafted silica nanoparticles as bimodal-imaging contrast agents”, Biomater., 33: 925-935 (2012).

11) Pinto, M. L., Rocha, J., Gomes, J. R. B., Pires, J., “Slow release of NO by microporous titanosilicate ETS-4”, J. Am. Chem. Soc., 133: 6396–6402 (2011).

12) Vilaça, N., Morais-Santos, F., Machado, A. F., Sirkecioglu, A., Pereira, M. F. R., Sardo, M., Rocha, J., Parpot, Pier, Fonseca, A. M., Baltazar, F., Neves, I. C., “Micro and mesoporous structures as drug delivery carriers for salicylic acid”, J. Phys. Chem C, 119: 3589-3595 (2015).

13) Vilaça, N., Machado, A. F., Morais-Santos, F., Amorim, R., Neto, A. P., Logodin, E., Pereira, M. F. R., Sardo, M., Rocha, J., Parpot, P., Fonseca, A. M., Baltazar, F., Neves, I. C., “Comparison of different silica microporous structures as drug delivery systems for in vitro models of solid tumors”, RSC Adv., 7: 13104-13111 (2017).

14) André, V., Silva, A. R. F., Fernandes, A., Frade, R., Garcia, C., Rijo, Antunes, A., P., Rocha, J., Duarte, T., “Mg- and Mn-MOFs boost the antibiotic activity of nalidixic acid”, ACS Appl. Bio Mater., 2: 262347-2354 (2019).

15) Pinto, R. V., Fernandes, A. C., Antunes, F., Lin, Z., Rocha, J., Pinto, M. L., “New generation of nitric oxide-releasing porous materials: Assessment of their potential to regulate biological functions”, Nitric Oxide, 90: 29-36 (2019).

5. EMISSÃO DE LUZ INDUZIDA POR AGREGAÇÃO MOLECULAR (MATERIAIS ORGÂNICOS)

1) Guieu, S., Cardona, F., Rocha, J., Silva, A. M. S., “Luminescent bi-metallic fluoroborates derivatives of bulky salen ligands”, New J. Chem., 38: 5411-5414 (2014).

2) Guieu, S., Joana, P., Silva, V. L. M., Rocha, J., Silva, M. S., “Synthesis, post-modification and fluorescence properties of boron diketonate complexes”, Eur. J. Org. Chem., 3423-3426 (2015).

3) Vaz, P. A. A. M., Rocha, J., Silva, A. M. S., Guieu, S., “Aggregation-induced emission enhancement in halochalcones”, New J. Chem., 40: 8198 (2016).

4) Vaz, P., Guieu, S., Silva, A. M. S., Rocha, J., “Aggregation-induced emission enhancement of chiral boranils”, New J. Chem., 42: 18166-18171 (2018).

5) Guieu, S., Cardona, F., Rocha, J., Silva, A. M. S., "Tunable color of aggregation induced emission enhancement in a family of hydrogen-bonded azines and Schiff bases", Chem. Eur. J., 24: 17262 – 17267 (2018).

6. OUTROS MATERIAIS SELECCIONADOS

1) Rocha, J., Orion, I., Nahring, J., Heaton, B. T., Fernandez, C. and Amoureux, J. P., "Solid-state NMR studies of interstitial P atoms within rhodium carbonyl clusters", Solid State NMR, 8: 195 (1997).

2) Walfort, B., Lameyer, L., Weiss, W., Herbst-Irmer, R., Bertermann, R., Rocha, J., and Stalke, D., “{[(MeLi)₄.(DEM)_1.5]_¥ and [(thf)₃.Li₃Me(NtBu)₃S]}- How to reduce aggregation of parent methyllithium”, Chem. Eur. J., 7: 1417 (2001).

3) Abrantes, M., Valente, A. A., Pillinger, M., Gonçalves, I. S., Rocha, J. and Romão, C. C., “Preparation and characterization of organotin-oxomolybdate coordination polymers and their use in sulfoxidation catalysis", Chem.Eur. J., 9: 2685-2695 (2003).

4) Ananias, D. Ferreira, A., Carlos, L. D. and Rocha, J., “Multifunctional sodium lanthanide silicates: from blue emitters and infrared S-band amplifiers to X-ray phosphors ”, Adv. Mater., 15: 980-85 (2003).

5) Smirnova, O. A., Rocha, J., Nalbandyan, V. B., Kharton, V. V. and Marques, F. M. B., “Crystal structure, local sodium environments and ion dynamics in Na0.9Ni0.6Sb0.4O2, a new mixed antimonate”, Solid State Ion., 178: 1360-1365 (2007).

7. RESSONÂNCIA MAGNÉTICA NUCLEAR DO ESTADO SÓLIDO: UMA PAIXÃO ANTIGA

1) Rocha, J., Kolodziejski, W. and Klinowski, J., "Two-dimensional J-resolved¹³C NMR of a solid with restricted molecular motion", Chem. Phys. Lett., 176: 395 (1991).

2) Rocha, J., Klinowski, J., Barrie, P. J., Jelinek, R. and Pines, A., "Solid‑state ²⁷Al NMR studies of aluminophosphate molecular sieves: enhanced resolution by quadrupole nutation and double-rotation", Solid State NMR, 1: 217 (1992).

3) Jäger, C., Rocha, J. and Klinowski, J., "High-speed satellite transition ²⁷Al MAS NMR spectroscopy", Chem. Phys. Lett., 188, 208 (1992).

4) Duer, M. J. and Rocha, J., "A two-dimensional solid-state ²H exchange NMR study of the molecular motion in the kaolinite:DMSO intercalation compound", J. Magn. Reson., 98: 524 (1992).

5) 2) Rocha, J., Lin, Z., Fernandez, C. and Amoureux, J. P., "Multiple-quantum²⁷Al MAS NMR spectroscopy of microporous aluminium methylphosphonate AlMepO-alfa", Chem. Commun., 2513 (1996).

6) Orion, I., Rocha, J., Jobic, S., Abadie, V., Brec, R., Fernandez, C. and Amoureux, J. P., "¹²⁵Te solid-state NMR studies of transition metal ditellurides", J. Chem. Soc. Dalton Trans., 20: 3741 (1997).

7) Fernandez, C., Morais, C., Rocha, J. and Pruski, M., “High-resolution heteronuclear correlation spectra between ³¹P and ²⁷Al nuclei in microporous aluminophosphates”, Solid State NMR, 21, 61-79 (2002).

8) Delevoye, L., Fernandez, C., Morais, C. M., Amoureux, J. P., Montouillout, V. and Rocha, J., “Double-resonance decoupling for resolution enhancement of ³¹P solid-state MAS and ²⁷Al-31P MQ-HETCOR NMR ”, Solid State NMR, 22: 501-512 (2002).

9) Amoureux, J. P., Morais, C, M., Trebosc, J., Rocha, J. and Fernandez, C., “I-STMAS, a new high-resolution solid-state NMR method for half-integer quadrupolar nuclei”, Solid State NMR, 23: 213-223 (2003).

10) Morais, C. M., Lopes M., Fernandez, C, and Rocha, J., “Assessing the potential of fast amplitude modulation pulses for improving triple-quantum MAS NMR spectra of half-integer quadrupolar nuclei”, Magn. Reson. Chem., 41: 679-688 (2003).

11) Malicki, L., Mafra, L., Quoineaud, A.-A., Thibault-Starzyk, F., Rocha, J. and Fernandez, C., “Multiplex MQMAS NMR of quadrupolar nuclei”, Solid State NMR, 28: 13-21 (2005).

12) Mafra, L., Rocha, J., Fernandez, C. and Paz, F. A. A., “Characterisation of microporous aluminophosphate IST-1 using ¹H Lee-Goldburg techniques”, J. Magn. Reson., 180: 235-243 (2006).

13) Coelho C., Rocha, J, Madhu, P. K. and Mafra L., “Practical aspects of Lee-Goldburg based CRAMPS techniques for high-resolution ¹H NMR spectroscopy in solids: implementation and applications”, J. Mag Reson., 194: 264-282 (2008).

14) Morais C. M., Montouillout, V., Deschamps M., Iuga, D., Fayon, F., Paz, F. A. A., Rocha, J., Fernandez, C., and Massiot, D., “1D to 3D NMR study of microporous alumino-phosphate AlPO₄-40”, Magn. Reson. Chem., 47: 942-947 (2009).

15) Siegel, R., Rocha, J., Mafra, L., "Combining STMAS and CRAMPS NMR spectroscopy: high resolution HETCOR NMR spectra of quadrupolar and H-1 nuclei in solids", Chem. Phys. Lett., 470: 337-341 (2009).

16) Mafra, L., Coelho, C., Siegel, R., Rocha, J, “Assessing the performance of windowed ¹H CRAMPS methods, on biological solids, at high-field and MAS up to 35 kHz ” J. Mag. Reson., 197: 20-27 (2009).

17) Mafra, L., Siegel, R., Fernandez, C., Schneider, D., Aussenac, F., Rocha, J., “High-resolution ¹H homonuclear dipolar recoupling NMR spectra of biological solids at MAS rates up to 67 kHz”, J. Mag. Reson., 199: 111-114 (2009).

18) Sardo, M., Siegel, R., Santos, S. M., Rocha, J., Gomes, J. R. B., Mafra, L., “Combining multinuclear high-resolution solid-state MAS NMR and computational methods for resonance assignment of glutathione tripeptide”, J. Phys. Chem. A, 116: 6711-6719 (2012).

19) Santos, S. M., Rocha, J., Mafra, L., “NMR Crystallography: chemical shift-driven crystal structure determination of β-lactam antibiotic amoxicillin trihydrate”, Cryst. Grow Design, 13: 2390-95 (2013).

20) Rocha, J., Almeida Paz, F. A., Sardo M., Mafra, L., “Revisiting the crystal structure of dickite: X-ray diffraction, solid-state NMR and DFT calculations study”, Am. Mineral.,103: 812-818 (2018).

21) Bornes, C., Sardo, M., Lin, Z., Amelse, J., Fernandes, A., Ribeiro, M. F., Geraldes, C., Rocha, J., Mafra, L., “¹H-³¹P HETCOR NMR elucidates the nature of acid sites in zeolite HZSM-5 probed with trimethylphosphine oxide”, Chem Commun., 55: 12635-12638 (2019).

PALESTRAS SELECCIONADAS 2015-2019 (DE UM TOTAL DE Ca. 40)

----Palestras Convidadas e "Key Notes"----

J Rocha, “Luminescent silicates and coordination polymers: nanothermometry meets catalysis?”. UCRA2019 – International Conference on Unconventional Catalysis, Reactors and Applications. 16-18 October 2019, Zaragoza, Spain.

J Rocha, “A tale of two themes on microporous solids: lifesaving drugs and chirality imprinting”. European Conference on Solid State Chemistry, ECSSC 17. 1-4 September 2019, Lille, France.

J Rocha, "From functional silicates to organic-inorganic hybrids: climbing the ladder?”. 6th International Conference on Multifunctional, Hybrid and Nanomaterials, 11-15 March 2019, Sitges, Spain.

J Rocha, “Quo Vadis: inorganic and organic-inorganic hybrid materials. International Workshop on Advanced Materials for Healthcare Applications. 22-23 May 2018, University of Iceland, Reykjavik, Iceland.

J Rocha, “Functional MOFs and microporous silicates”. E-MRS 2018 Spring Meeting. 18 – 22 June 2018, Strasbourg.

J Rocha, “A Chemist’s Playground: MOFs, Silicates and Nanoparticles”, 4th International Conference on Advanced Complex Inorganic Nanomaterials (ACIN 2018). 16 - 20 July 2018, Namur, Belgium.

J Rocha, “Functional materials and their electronic, magnetic and optical properties”, 7th EuCheMS Chemistry Congress, 26 – 30 August 2018, Liverpool, UK.

J. Rocha, “Organic-inorganic hybrid nanomaterials for sensing molecules and temperature”. 5th International Conference on Multifunctional, Hybrid and Nanomaterials, 6-10 March 2017, Lisbon, Portugal.

J. Rocha, “Nanomaterials for temperature sensing”. Nano Portugal 2017, International Conference, 1-3 February 2017, Porto, Portugal.

J. Rocha, “Microporous lanthanide silicates and coordination polymers for optical sensing and nanothermometry”. Challenges and Prospects for Solid State Chemistry, EuCheMS Division on Solid State and Materials Chemistry, 9-10 September 2016, Seville, Spain.

J. Rocha, “Exploring new light emitting materials: calling the chemists in the playground”. EMRS Symposium E, Substitution of critical raw materials: synthesis, characterization and processing of new advanced materials in optoelectronic and magnetic devices, 2-6 May 2016, Lille, France.

J. Rocha, “Sensing and making sense of temperature and molecules at the nanoscale”. Third International Conference of Advanced Complex Inorganic Nanomaterials, 14 July 2015, University of Namur, Belgium.

J. Rocha, “Lanthanide-organic frameworks for optical sensing and nanothermometry”. 29th European Crystallographic Meeting, 25-30 August 2015, Rovinj, Croatia.

J. Rocha, “Lanthanide-organic frameworks for optical sensing and nanothermometry”. Pacifichem - 2015 International Chemical Congress of the Pacific Basin Societies, 15-20 December 2015, Honolulu, Hawaii.

----Palestras em Universidades e Academias----

J. Rocha, “Nanoporous materials: functional silicates and metal organic frameworks”. Lisbon Academy of Sciences, Lisbon, 10 October 2019.

J. Rocha, “Solid-state NMR of organic-inorganic hybrids: why bother?”. Workshop and Training school – Interaction at Organic-Inorganic Interfaces. Functional Hybrid materials: Structure elucidation from molecular to macro level, University of Stockholm 25-27 May 2016.

J. Rocha, “Materials science: sailing the wind of mineralogy”. Mineral Phases and Synthetic Analogues in Earth and Materials Science, Accademia dei Lincei, Rome 13-14 June 2016.

J. Rocha, “Sensing and making sense of temperature and molecules at the nanoscale”. Van 't Hoff Institute for Molecular Sciences of the University of Amsterdam, 16 January 2015.

J Rocha, “Materials Science, Culture and Ethics: personal accounts”. Symposium and the Ceremony of Awards 2014 of the European Academy of Sciences (EURASC), Porto, 27-28 October 2015.

Projectos

Agentes de Contraste Vectorizados para Imagem por Ressonância Magnética (IRM) e Cintigrafia Nuclear (ACV) (POCTI/QUI/47005/2002)

Coordenador LocalFundação para a Ciência e a Tecnologia

Agentes de Contraste Vectorizados Cintigrafia Nuclear IRM Reconhecimento Molecular

CAPACITAR O CICECO PARA INTERNACIONALIZAR A I&DT EM MATERIAIS E INCREMENTAR A COMPETITIVIDADE NACIONAL (CENTRO-07-0962-FEDER-002003 #1)

CoordenadorOther National

CAPACITAR O CICECO PARA INTERNACIONALIZAR A I&DT EM MATERIAIS E INCREMENTAR A COMPETITIVIDADE NACIONAL (CENTRO-07-0962-FEDER-002003 #2)

CoordenadorUA

Centro de Investigação em Materiais Cerâmicos e Compósitos - CICECO (LA0011: 2002-2010) (UI CICECO (UI 600/02) + POCI/LA11/2005)

CoordenadorFundação para a Ciência e a Tecnologia

Centro de Investigação em Materiais Cerâmicos e Compósitos - CICECO (LA0011: 2011-2012) (PEst-C/CTM/LA0011/2011)

CoordenadorFundação para a Ciência e a Tecnologia

Centro de Investigação em Materiais Cerâmicos e Compósitos - CICECO (LA0011: 2013-2014) (PEst-C/CTM/LA0011/2013)

CoordenadorFundação para a Ciência e a Tecnologia - R&D Unit Pluriannual funding

Centro de Investigação em Materiais Cerâmicos e Compósitos - CICECO - INCENTIVO (INCENTIVO/CTM/LA0011/2014)

CoordenadorFundação para a Ciência e a Tecnologia - R&D Unit Pluriannual funding

Centro de Investigação em Materiais Cerâmicos e Compósitos - CICECO - INCENTIVO 2013 (INCENTIVO/CTM/LA0011/2013)

CoordenadorFundação para a Ciência e a Tecnologia - R&D Unit Pluriannual funding

CICECO – Instituto de Materiais de Aveiro (UID/CTM/50011/2013)

CoordenadorFundação para a Ciência e a Tecnologia - R&D Unit Pluriannual funding

Desenvolver-se-ão materiais cerâmicos e inorgânicos, matéria mole, biopolímeros e híbridos orgânico-inorgânico, preparados e processados à “escala adequada”, ou hierarquicamente estruturados, frequentemente multifuncionais. Entre as suas aplicações incluem-se:- Fotónica verde, e.g., iluminação do estado sólido, conversão fotovoltaica...

CICECO – Instituto de Materiais de Aveiro (UIDP/50011/2020)

CoordenadorFundação para a Ciência e a Tecnologia

CICECO – Instituto de Materiais de Aveiro (UIDB/50011/2020)

CoordenadorFundação para a Ciência e a Tecnologia

CICECO – Instituto de Materiais de Aveiro (UID/CTM/50011/2019)

CoordenadorFundação para a Ciência e a Tecnologia - R&D Unit Pluriannual funding

Desenvolver-se-ão materiais cerâmicos e inorgânicos, matéria mole, biopolímeros e híbridos orgânico-inorgânico, preparados e processados à “escala adequada”, ou hierarquicamente estruturados, frequentemente multifuncionais. Entre as suas aplicações incluem-se: - Fotónica verde, e.g., iluminação do estado sólido, conversão fotovolta...

CICECO – Instituto de Materiais de Aveiro (UID/CTM/50011/2013)

CoordenadorFundação para a Ciência e a Tecnologia - R&D Unit Pluriannual funding

Controlo da escala de tamanho através de "Chimie Douce": de materiais funcionais inorgânicos a hìbridos orgânicos-inorgânicos (POCTI/CTM/46780/2002)

CoordenadorFundação para a Ciência e a Tecnologia

Materiais Funcionais Inorgânicos Chimie Douce HÌbridos Orgânicos-Inorgânicos Luminescente

Dadores de gasotransmissores NO e H2S terapêuticos baseados em materiais nanoporosos (PTDC/MED-QUI/28721/2017)

Coordenador LocalFundação para a Ciência e a Tecnologia

De Matérias primas baratas para novos materiais vitreos luminescentes (InLumGlass)

Coordenador LocalFundação para a Ciência e a Tecnologia

EJD-FUNMAT - European Joint Doctorate in Functional Materials Research (EJD-FUNMAT)

ParticipanteEuropean Comission

EJD-FunMat is a European Joint Doctoral programme in the field of functional materials research.EJD-FunMat is embedded in an existing research network, with previous experience in co-tutelle doctorates , but the project will add new major elements, with the strategic aim of becoming a permanent reference European Joint Doctoral Schoo...

ENERMATaa (ENERMATaa)

Coordenador LocalEuropean Comission

ENERMAT.aa is a European project whose goal is to implement a sustainable transnational network of cooperation between public research structures and small and medium industries of the Atlantic Area in the materials for energy field. ENERMAT.aa essentially focuses on developing transnational partnerships around European centers of excellence spe...

Especies de CO2 formadas a superficie de materiais porosos para aplicacoes ambientais caracterizadas por RMN de polarizacao nuclear dinamica (GAS2MAT-DNPSENS)

ParticipanteFundação para a Ciência e a Tecnologia

Fotossensibilizadores imobilizados como novos materiais no tratamento de águas (POCI/CTM/58183/2004)

ParticipanteFundação para a Ciência e a Tecnologia

Photosensitizers Silica based material Immobilization Microorganisms inactivation

Functionalised Advanced Materials and Engineering of Hybrids and Ceramics - FAME (FAME)

Coordenador LocalEuropean Comission

FAME will assemble, structure, integrate and expand a world class-team exhibiting a critical mass of researchers in multifunctional Hybrids and Ceramics remaining at the forefront of this emerging and strategically important family of materials technologies for tomorrow. Today the hybrids and ceramics communities are too fragmented to face up to...

Imobilização de arilióxidos de terras raras e actinídeos Activação de pequenas moléculas (CO2,CH4,C2H6) (POCTI/QUI/42919/2001)

Coordenador LocalFundação para a Ciência e a Tecnologia

Organometallic surface chemistry Immobilized catalysts Block f elements aryloxides Activation of CO2, CH4, C2H6

Luminescent Metal Organic Frameworks for anti-counterfeiting and logic computing (LUMIMOF)

CoordenadorEuropean Comission

Data security and protection is a global key concern, challenging industry, governments and customers. The EU-funded LUMIMOF project aims to develop ground-breaking luminescent metal–organic frameworks at the nanometer level to be used in anti-counterfeiting applications and in logic computing gates, able to be tailored to a variety of existing ...

Materiais para medicina regenerativa (CENTRO-07-0924-FEDER-002030)

CoordenadorOther National

Melhorar o Laboratório Central de Difracção de Raios - X da Universidade de Aveiro (REEQ/183/QUI/2005)

CoordenadorFundação para a Ciência e a Tecnologia

O sistema de difracção de raios-X de cristal único, com detector de área (CCD), encontra-se instalado no departamento de Química/CICECO desde de Setembro de 2006. Durante este período, o equipamento foi utilizado extensivamente na recolha de dados de difracção de raios X de moléculas pequenas e estruturas de framework com origem na investigação ...

MNAA - Centres of excellence in materials for the economic development of the Atlantic Area (MNAA - MATERIALS NETWORK FOR THE ATLANTIC AREA)

Coordenador LocalOther International

A network dedicated to industryGather academic human and materials resources-to create a critical mass sufficient to tackle high technology research-to exploit the complementarities of the partnersShare our best practices in Technology Transfer processIdentify weaknesses and...

Multiferróicos híbridos orgânico-inorgânicos foto-responsivos: Na senda da eletrónica multifuncional (PTDC/CTM-CTM/4044/2020)

ParticipanteFundação para a Ciência e a Tecnologia

Híbridos orgânico-inorgânico Multiferroicos Piezoelectricidade Ferroelectricidade

Nanogotas de Água em Materiais Microporosos e Híbridos Orgânicos-Inorgânicos (PTDC/QUI/65805/2006)

CoordenadorFundação para a Ciência e a Tecnologia

Cachos de moléculas de água Materiais microporosos Híbridos orgânicos-inorgânicos Nanoestruturas

Nanopartículas integrando aquecedores e termómetros: aplicações ao movimento Browniano e em hipertermia (nanoHYperTHerm)

ParticipanteFundação para a Ciência e a Tecnologia

Nanotubos e silicates microporosos de terras raras, fotoluminescentes (PTDC/CTM/73243/2006)

CoordenadorFundação para a Ciência e a Tecnologia

Nanotubos Microporoso Terras raras Fotoluminescência

Novas matrizes sólidas quelantes com hidroxipirimidinonas imobilizadas para aplicações ambientais e biológicas (PTDC/QUI/65647/2006)

Coordenador LocalFundação para a Ciência e a Tecnologia

Chelating matrices Specific chelators Hydroxypyrimidinones Hazardous metals

Novas Redes Lantanídeo-Orgânicas Multidimensionais: Síntese Hidrotérmica, Caracterização Estrutural e Aplicações (POCI/QUI/58377/2004)

ParticipanteFundação para a Ciência e a Tecnologia

Engenharia de Cristais Redes Lantanídeo-Orgânicas Polímeros de Coordenação Materiais Funcionais

Rational design of hybrid organic-inorganic interfaces: the next step towards advanced functional materials (HINT)

ParticipanteEuropean Comission

Hybrid organic-inorganic (HOI) materials synthesized using soft inorganic chemistry allow a combination of organic and inorganic units at molecular/nanoscale level, thereby opening access to a wide spectrum of multifunctionality not possible with traditional concepts of materials science. These innovative multifunctional materials will have a ma...

Rede Nacional de Ressonância Magnética Nuclear (PTNMR)

Coordenador LocalFundação para a Ciência e a Tecnologia - REDES

Regularidade e estabilidade de materiais com estrutura mesoporosa ordenada contendo alumínio e titânio (POCTI/CTM/45859/2002)

Coordenador LocalFundação para a Ciência e a Tecnologia

MCM estabilidade estrutura porosa modificação

Relação entre as propriedades de fotoluminescência e a estrutura em híbridos orgânicos/inorgânicos com aplicações ópticas (POCI/V.5/A0067/2005)

ParticipanteFundação para a Ciência e a Tecnologia

RNRMN - Rede Nacional de Ressonância Magnética Nuclear - Contrato Programa 2010-2012 (REDE/1517/RMN/2005)

Coordenador LocalFundação para a Ciência e a Tecnologia

The main mission of the Portuguese Nuclear Magnetic Resonance Network (PTNMR) is to provide to the scientific community with access to modern and up-to-date NMR spectrometers, housed in scientific institutions with competence and scientific expertise on the use of this type of equipment. The Portuguese NMR network was created with the support of...

SGH : Smart Green Homes (Smart Green Homes)

ParticipanteIndustry National

O Projeto Smart Green Homes (SGH) visa desenvolver soluções integradas de produtos e tecnologias para ambiente doméstico, elevando os padrões de conforto, segurança e satisfação de utilização a um novo nível e, ao mesmo tempo, dar resposta aos problemas de sustentabilidade do planeta, aumentando a eficiência energética e diminuindo as emissões d...

Síntese de Silicatos Luminescentes Utilizando Complexos de Lantanideos como Agentes Directores de Estrutura (POCI/CTM/58863/2004)

ParticipanteFundação para a Ciência e a Tecnologia

Materias Funcionais Inorgânicos Luminescência Silicatos Microporosos Complexos de Lantanídeos

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Participanteteste

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Publicações

Electroactive Organic Building Blocks for the Chemical Design of Functional Porous Frameworks (MOFs and COFs) in Electronics

Souto, M; Strutynski, K; Melle-Franco, M; Rocha, J
2020, CHEMISTRY-A EUROPEAN JOURNAL, 26, 48, 10912-10935.
ISBN: 1521-3765

CICECO-Aveiro Institute of Materials: A Journey into the Future

Rocha, J
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 22, 2119-2120.
ISBN: 1099-0682

Cryogenic Luminescent Ratiometric Thermometers Based on Tetragonal Na[LnSiO(4)]center dot xNaOH (Ln = Gd, Tb, Eu; x approximate to 0.2)

Ananias, D; Mongis, CM; Carlos, LD; Rocha, J
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 19, 1852-1859.
ISBN: 1099-0682

Easy Processing of Metal-Organic Frameworks into Pellets and Membranes

Figueira, F; Mendes, RE; Domingues, EM; Barbosa, P; Figueiredo, F; Paz, FAA; Rocha, J
2020, APPLIED SCIENCES-BASEL, 10, 3.
ISBN: 2076-3417

Nature of the multicomponent crystal of salicylic acid and 1,2-phenylenediamine

Tier, AZ; Wust, KM; Vieira, JCB; Sardo, M; Cendak, T; Mafra, L; Rocha, J; Gindri, IM; Horner, M; Frizzo, CP
2020, CRYSTENGCOMM, 22, 4, 708-719.

Quantification of Bronsted Acid Sites in Zeolites by Water Desorption Thermogravimetry

Bornes, C; Amelse, J; Peacock, M; Marshall, CL; Schwartz, M; Geraldes, CFGC; Rocha, J; Mafra, L
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 19, 1860-1866.
ISBN: 1099-0682

Synthesis and luminescence properties of analogues of the green fluorescent protein chromophore

Esteves, CIC; Fonseca, ID; Rocha, J; Silva, AMS; Guieu, S
2020, DYES AND PIGMENTS, 177.
ISBN: 1873-3743

Bone Tissue Disorders: Healing Through Coordination Chemistry

Barbosa, JS; Mendes, RF; Figueira, F; Gaspar, VM; Mano, JF; Braga, SS; Rocha, J; Paz, FAA
2020, CHEMISTRY-A EUROPEAN JOURNAL, 26, 67, 15416-15437.
ISBN: 1521-3765

Luminescent thin films of Eu-bearing UiO-66 metal organic framework prepared by ALD/MLD

Silva, RM; Carlos, LD; Rocha, J; Silva, RF
2020, APPLIED SURFACE SCIENCE, 527.
ISBN: 1873-5584

Photoresponsive Organic-Inorganic Hybrid Ferroelectric Designed at the Molecular Level

Xu, WJ; Romanyuk, K; Martinho, JMG; Zeng, Y; Zhang, XW; Ushakov, A; Shur, V; Zhang, WX; Chen, XM; Kholkin, A; Rocha, J
2020, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 142, 40, 16990-16998.
ISBN: 1520-5126

Hybrid organic-inorganic perovskites: Polar properties and applications

Xu, WJ; Kopyl, S; Kholkin, A; Rocha, J
2019, COORDINATION CHEMISTRY REVIEWS, 387, 398-414.
ISBN: 1873-3840

Hydrogen bonding networks in gabapentin protic pharmaceutical salts: NMR and in silico studies

Martins, ICB; Sardo, M; Cendak, T; Gomes, JRB; Rocha, J; Duarte, MT; Mafra, L
2019, MAGNETIC RESONANCE IN CHEMISTRY, 57, 5, 243-255.
ISBN: 1097-458X

Fluorescent Light-up Probe for the Detection of Protein Aggregates

da Silva, RN; Costa, CC; Santos, MJG; Alves, MQ; Braga, SS; Vieira, SI; Rocha, J; Silva, AMS; Guieu, S
2019, CHEMISTRY-AN ASIAN JOURNAL, 14, 6, 859-863.
ISBN: 1861-471X

Luminescent Nanothermometers Obtained by Post-Synthetic Modification of Metal-Organic Framework MIL-68

Abdelhameed, RM; Ananias, D; Silva, AMS; Rocha, J
2019, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 10, 1354-1359.
ISBN: 1099-0682

IRMOF-3 Biological Activity Enhancement by Post-Synthetic Modification

Abdelhameed, RM; Darwesh, OM; Rocha, J; Silva, AMS
2019, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 9, 1243-1249.
ISBN: 1099-0682

Electronic, Structural and Functional Versatility in Tetrathiafulvalene-Lanthanide Metal-Organic Frameworks

Castells-Gil, J; Manas-Valero, S; Vitorica-Yrezabal, IJ; Ananias, D; Rocha, J; Santiago, R; Bromley, ST; Baldovi, JJ; Coronado, E; Souto, M; Minguez Espallargas, G
2019, CHEMISTRY-A EUROPEAN JOURNAL, 25, 54, 12636-12643.
ISBN: 1521-3765

Cooperative Capture of Uranyl Ions by a Carbonyl-Bearing Hierarchical-Porous Cu-Organic Framework

Wang, XF; Chen, YY; Song, LP; Fang, Z; Zhang, J; Shi, FN; Lin, YW; Sun, YK; Zhang, YB; Rocha, J
2019, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 58, 52, 18808-18812.
ISBN: 1521-3773

One-dimensional ladder gallium coordination polymer

Simoes, AB; Figueira, F; Mendes, R; Barbosa, JS; Rocha, J; Paz, FAA
2019, ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 75, 1607-+.

H-1-P-31 HETCOR NMR elucidates the nature of acid sites in zeolite HZSM-5 probed with trimethylphosphine oxide

Bornes, C; Sardo, M; Lin, Z; Amelse, J; Fernandes, A; Ribeiro, MF; Geraldes, C; Rocha, J; Mafra, L
2019, CHEMICAL COMMUNICATIONS, 55, 84, 12635-12638.
ISBN: 1364-548X

Zooming in with QSPR on Friedel-Crafts acylation reactions over modified BEA zeolites

Aleixo, O; Elvas-Leitao, R; Martins, F; Carvalho, AP; Brigas, A; Nunes, R; Fernandes, A; Rocha, J; Martins, A; Nunes, N
2019, MOLECULAR CATALYSIS, 476.

New generation of nitric oxide-releasing porous materials: Assessment of their potential to regulate biological functions

Pinto, RV; Fernandes, AC; Antunes, F; Lin, Z; Rocha, J; Pires, J; Pinto, ML
2019, NITRIC OXIDE-BIOLOGY AND CHEMISTRY, 90, 29-36.
ISBN: 1089-8611

Detoxification of a Mustard-Gas Simulant by Nanosized Porphyrin-Based Metal-Organic Frameworks

Pereira, CF; Liu, YY; Howarth, A; Figueira, F; Rocha, J; Hupp, JT; Farha, OK; Tome, JPC; Paz, FAA
2019, ACS APPLIED NANO MATERIALS, 2, 1, 465-469.

Gd- and Eu-Loaded Iron Oxide@Silica Core-Shell Nanocomposites as Trimodal Contrast Agents for Magnetic Resonance Imaging and Optical Imaging

Pinho, SLC; Sereno, J; Abrunhosa, AJ; Delville, MH; Rocha, J; Carlos, LD; Geraldes, CFGC
2019, INORGANIC CHEMISTRY, 58, 24, 16618-16628.
ISBN: 1520-510X

Mg- A nd Mn-MOFs Boost the Antibiotic Activity of Nalidixic Acid

AndrŽ V.; Da Silva A.R.F.; Fernandes A.; Frade R.; Garcia C.; Rijo P.; Antunes A.M.M.; Rocha J.; Duarte M.T.
2019, ACS Applied Bio Materials, 2, 6.

Metal-Organic Frameworks assembled from tetraphosphonic ligands and lanthanides

Firmino, ADG; Figueira, F; Tome, JPC; Paz, FAA; Rocha, J
2018, COORDINATION CHEMISTRY REVIEWS, 355, 133-149.

Nitric oxide-releasing porous materials and their potential regulation of in-vitro biological functions

Pinto, R; Fernandes, C; Pires, J; Antunes, F; Rocha, J; Lin, Z; Pinto, M
2018, FREE RADICAL BIOLOGY AND MEDICINE, 120, S151-S151.

Revisiting the crystal structure of dickite: X-ray diffraction, solid-state NMR, and DFT calculations study

Rocha, J; Paz, FAA; Sardo, M; Mafra, L
2018, AMERICAN MINERALOGIST, 103, 5, 812-818.

Bifunctional Porphyrin-Based Nano-Metal-Organic Frameworks: Catalytic and Chemosensing Studies

Pereira, CF; Figueira, F; Mendes, RF; Rocha, J; Hupp, JT; Farha, OK; Simoes, MMQ; Tome, JPC; Paz, FAA
2018, INORGANIC CHEMISTRY, 57, 7, 3855-3864.

The role of Li+ in the upconversion emission enhancement of (YYbEr)(2)O-3 nanoparticles

Debasu, ML; Riedl, JC; Rocha, J; Carlos, LD
2018, NANOSCALE, 10, 33, 15799-15808.

Tunable Color of Aggregation-Induced Emission Enhancement in a Family of Hydrogen-Bonded Azines and Schiff Bases

Guieu, S; Cardona, F; Rocha, J; Silva, AMS
2018, CHEMISTRY-A EUROPEAN JOURNAL, 24, 65, 17262-17267.

Kinetic and equilibrium studies on the removal of C-14-ethion residues from wastewater by copper-based metal-organic framework

Abdelhameed, RM; Abdel-Gawad, H; Silva, CM; Rocha, J; Hegazi, B; Silva, AMS
2018, INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY, 15, 11, 2283-2294.

Magnetic and luminescent coordination networks based on imidazolium salts and lanthanides for sensitive ratiometric thermometry

Farger, P; Leuvrey, C; Gallart, M; Gilliot, P; Rogez, G; Rocha, J; Ananias, D; Rabu, P; Delahaye, E
2018, BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 9, 2775-2787.

Near-Infrared Ratiometric Luminescent Thermometer Based on a New Lanthanide Silicate

Ananias, D; Paz, FA; Carlos, LD; Rocha, J
2018, CHEMISTRY-A EUROPEAN JOURNAL, 24, 46, 11926-11935.

Rare-Earth Germanate Visible, Near-Infrared, and Up-Conversion Emitters

Ananias, D; Paz, FAA; Carlos, LD; Rocha, J
2018, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 20-21, 2444-2451.

Inorganic Ion Exchangers for Cesium Removal from Radioactive Wastewater

Figueiredo, BR; Cardoso, SP; Portugal, I; Rocha, J; Silva, CM
2018, SEPARATION AND PURIFICATION REVIEWS, 47, 4, 306-336.

Aggregation-induced emission enhancement of chiral boranils

Vaz, PAAM; Rocha, J; Silva, AMS; Guieu, S
2018, NEW JOURNAL OF CHEMISTRY, 42, 22, 18166-18171.

Unusual seeding mechanism for enhanced performance in solid-phase magnetic extraction of Rare Earth Elements

Legaria, EP; Rocha, J; Tai, CW; Kessler, VG; Seisenbaeva, GA
2017, SCIENTIFIC REPORTS, 7.

Microwave Synthesis of a photoluminescent Metal-Organic Framework based on a rigid tetraphosphonate linker

Firmino, ADG; Mendes, RF; Ananias, D; Vilela, SMF; Carlos, LD; Tome, JPC; Rocha, J; Paz, FAA
2017, INORGANICA CHIMICA ACTA, 455, 584-594.
ISBN: 1873-3255

Porphyrin-boron diketonate dyads

Costa, LD; Guieu, S; Rocha, J; Silva, AMS; Tome, AC
2017, NEW JOURNAL OF CHEMISTRY, 41, 5, 2186-2192.
ISBN: 1369-9261

Comparison of different silica microporous structures as drug delivery systems for in vitro models of solid tumors

Vilaca, N; Machado, AF; Morais-Santos, F; Amorim, R; Neto, AP; Logodin, E; Pereira, MFR; Sardo, M; Rocha, J; Parpot, P; Fonseca, AM; Baltazar, F; Neves, IC
2017, RSC ADVANCES, 7, 22, 13104-13111.

Halogen-bonded dimers and ribbons from the self-assembly of 3-halobenzophenones

Vaz, PAAM; Rocha, J; Silva, AMS; Guieu, S
2017, CRYSTENGCOMM, 19, 16, 2202-2206.

Building Light-Emitting Metal-Organic Frameworks by Post-Synthetic Modification

Abdelhameed, RM; Ananias, D; Silva, AMS; Rocha, J
2017, CHEMISTRYSELECT, 2, 1, 136-139.

Cu-BTC metal-organic framework natural fabric composites for fuel purification

Abdelhameed, RM; Emam, HE; Rocha, J; Silva, AMS
2017, FUEL PROCESSING TECHNOLOGY, 159, 306-312.

Photoluminescent Lanthanide-Organic Framework Based on a Tetraphosphonic Acid Linker

Mendes, RF; Ananias, D; Carlos, LD; Rocha, J; Paz, FAA
2017, CRYSTAL GROWTH & DESIGN, 17, 10, 5191-5199.
ISBN: 1528-7505

Antimosquito Activity of a Titanium-Organic Framework Supported on Fabrics

Abdelhameed, RM; Kamel, OMHM; Amr, A; Rocha, J; Silva, AMS
2017, ACS APPLIED MATERIALS & INTERFACES, 9, 27, 22112-22120.

Excimer Formation in a Terbium Metal-Organic Framework Assists Luminescence Thermometry

Ananias, D; Firmino, ADG; Mendes, RF; Paz, FAA; Nolasco, M; Carlos, LD; Rocha, J
2017, CHEMISTRY OF MATERIALS, 29, 21, 9547-9554.

Tb/Eu-AV-9: A lanthanide silicate for the sensing and removal of cesium ions from aqueous solutions

Figueiredo, BR; Ananias, D; Portugal, I; Rocha, J; Silva, CM
2016, CHEMICAL ENGINEERING JOURNAL, 286, 679-688.

Instantaneous ballistic velocity of suspended Brownian nanocrystals measured by upconversion nanothermometry

Brites, CDS; Xie, XJ; Debasu, ML; Qin, X; Chen, RF; Huang, W; Rocha, J; Liu, XG; Carlos, LD
2016, NATURE NANOTECHNOLOGY, 11, 10, 851-+.

Implementing luminescence thermometry at 1.3 mu m using (GdNd)(2)O-3 nanoparticles

Balabhadra, S; Debasu, ML; Brites, CDS; Rocha, J; Carlos, LD
2016, JOURNAL OF LUMINESCENCE, 180, 25-30.

Nanoplatforms for Plasmon-Induced Heating and Thermometry

Debasu, ML; Brites, CDS; Balabhadra, S; Oliveira, H; Rocha, J; Carlos, LD
2016, CHEMNANOMAT, 2, 6, 520-527.

A Lamellar Coordination Polymer with Remarkable Catalytic Activity

Mendes, RF; Antunes, MM; Silva, P; Barbosa, P; Figueiredo, F; Linden, A; Rocha, J; Valente, AA; Paz, FAA
2016, CHEMISTRY-A EUROPEAN JOURNAL, 22, 37, 13136-13146.

Aggregation-induced emission enhancement in halochalcones

Vaz, PAAM; Rocha, J; Silva, AMS; Guieu, S
2016, NEW JOURNAL OF CHEMISTRY, 40, 10, 8198-8201.

Analysis of equilibrium and kinetic parameters of water adsorption heating systems for different porous metal/metalloid oxide adsorbents

Pinheiro, JM; Salustio, S; Rocha, J; Valente, AA; Silva, CM
2016, APPLIED THERMAL ENGINEERING, 100, 215-226.

Cryogenic Nanothermometer Based on the MIL-103(Tb,Eu) Metal-Organic Framework

Ananias, D; Brites, CDS; Carlos, LD; Rocha, J
2016, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 13-14, 1967-1971.

Cs+ removal and optical detection by microporous lanthanide silicate Eu-AV-20 in a fixed-bed column

Figueiredo, BR; de Melo, MMR; Portugal, I; Ananias, D; Rocha, J; Silva, CM
2016, CHEMICAL ENGINEERING JOURNAL, 286, 48-58.

Fixed-bed removal of Cs+ from aqueous solutions by microporous silicate ETS-4: Measurement and modeling of loading-regeneration cycles

Figueiredo, BR; Portugal, I; Rocha, J; Silva, CM
2016, CHEMICAL ENGINEERING JOURNAL, 301, 276-284.

Lanthanide Organic Framework Luminescent Thermometers

Rocha, J; Brites, CDS; Carlos, LD
2016, CHEMISTRY-A EUROPEAN JOURNAL, 22, 42, 14782-14795.

Luminescence properties of lanthanide-containing layered double hydroxides

Vicente, P; Perez-Bernal, ME; Ruano-Casero, RJ; Ananias, D; Paz, PAA; Rocha, J; Rives, V
2016, MICROPOROUS AND MESOPOROUS MATERIALS, 226, 209-220.

Photoluminescent Nanocrystals in a Multicomponent Aluminoborosilicate Glass

Ruivo, A; Ferro, M; Andrade, SM; Rocha, J; Pina, F; Laia, CAT
2016, JOURNAL OF PHYSICAL CHEMISTRY C, 120, 43, 24925-24931.

Storage and delivery of nitric oxide by microporous titanosilicate ETS-10 and Al and Ga substituted analogues

Pinto, ML; Fernandes, AC; Antunes, F; Pires, J; Rocha, J
2016, MICROPOROUS AND MESOPOROUS MATERIALS, 229, 83-89.

The effect of natural zeolite on microstructure, mechanical and heavy metals adsorption properties of metakaolin based geopolymers

Andrejkovicova, S; Sudagar, A; Rocha, J; Patinha, C; Hajjaji, W; da Silva, EF; Velosa, A; Rocha, F
2016, APPLIED CLAY SCIENCE, 126, 141-152.

Visible-Light Excited Luminescent Thermometer Based on Single Lanthanide Organic Frameworks

Li, L; Zhu, YL; Zhou, XH; Brites, CDS; Ananias, D; Lin, Z; Paz, FAA; Rocha, J; Huang, W; Carlos, LD
2016, ADVANCED FUNCTIONAL MATERIALS, 26, 47, 8677-8684.

Calcium Phosphonate Frameworks for Treating Bone Tissue Disorders

Shi, FN; Almeida, JC; Helguero, LA; Fernandes, MHV; Knowles, JC; Rocha, J
2015, INORGANIC CHEMISTRY, 54, 20, 9929-9935.

Synthesis and structure of new microporous Nd(III) silicates of the rhodesite group

Munha, RF; Ananias, D; Paz, FAA; Rocha, J
2015, ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 230, 5, 353-362.

Lanthanide-Organic Framework Nanothermometers Prepared by Spray-Drying

Wang, ZP; Ananias, D; Carne-Sanchez, A; Brites, CDS; Imaz, I; Maspoch, D; Rocha, J; Carlos, LD
2015, ADVANCED FUNCTIONAL MATERIALS, 25, 19, 2824-2830.

Photoluminescent Thermometer Based on a Phase-Transition Lanthanide Silicate with Unusual Structural Disorder

Ananias, D; Paz, FAA; Yufit, DS; Carlos, LD; Rocha, J
2015, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 137, 8, 3051-3058.

Layered Zinc Hydroxide Salts Intercalated with Anionic Surfactants and Adsolubilized with UV Absorbing Organic Molecules

Cursino, ACT; Rives, V; Carlos, LD; Rocha, J; Wypych, F
2015, JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 26, 9, 1769-1780.

Application of the novel ETS-10/water pair in cyclic adsorption heating processes: Measurement of equilibrium and kinetics properties and simulation studies

Pinheiro, JM; Valente, AA; Salustio, S; Ferreira, N; Rocha, J; Silva, CM
2015, APPLIED THERMAL ENGINEERING, 87, 412-423.

Boosting the sensitivity of Nd3+-based luminescent nanothermometers

Balabhadra, S; Debasu, ML; Brites, CDS; Nunes, LAO; Malta, OL; Rocha, J; Bettinelli, M; Carlos, LD
2015, NANOSCALE, 7, 41, 17261-17267.

Enhanced Photocatalytic Activity of MIL-125 by Post-Synthetic Modification with Cr-III and Ag Nanoparticles

Abdelhameed, RM; Simoes, MMQ; Silva, AMS; Rocha, J
2015, CHEMISTRY-A EUROPEAN JOURNAL, 21, 31, 11072-11081.

Modelling the Luminescence of Phosphonate Lanthanide-Organic Frameworks

Nolasco, MM; Mendes, RF; Lima, PP; Paz, FAA; Carlos, LD; Rocha, J
2015, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 7, 1254-1260.

Influence of the Crystal Structure on the Luminescence Properties of Mixed Eu,La-(1,10-Phenanthroline) Complexes

Yang, TH; Fu, LS; Ferreira, RAS; Nolasco, MM; Rocha, J; Carlos, LD; Shi, FN
2015, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 29, 4861-4868.

Synthesis, Post-Modification and Fluorescence Properties of Boron Diketonate Complexes

Guieu, S; Pinto, J; Silva, VLM; Rocha, J; Silva, AMS
2015, EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 16, 3423-3426.

Cs+ ion exchange over lanthanide silicate Eu-AV-20: Experimental measurement and modelling

Figueiredo, BR; Ananias, D; Rocha, J; Silva, CM
2015, CHEMICAL ENGINEERING JOURNAL, 268, 208-218.

Micro- and Mesoporous Structures as Drug Delivery Carriers for Salicylic Acid

Vilaca, N; Morais-Santos, F; Machado, AF; Sirkecioglu, A; Pereira, MFR; Sardo, M; Rocha, J; Parpot, P; Fonseca, AM; Batazar, F; Neves, IC
2015, JOURNAL OF PHYSICAL CHEMISTRY C, 119, 7, 3589-3595.

Engineering lanthanide-optical centres in IRMOF-3 by post-synthetic modification

Abdelhameed, RM; Carlos, LD; Silva, AMS; Rocha, J
2015, NEW JOURNAL OF CHEMISTRY, 39, 6, 4249-4258.

Multifunctional micro-and nanosized metalorganic frameworks assembled from bisphosphonates and lanthanides

Vilela, SMF; Ananias, D; Fernandes, JA; Silva, P; Gomes, AC; Silva, NJO; Rodrigues, MO; Tome, JPC; Valente, AA; Ribeiro-Claro, P; Carlos, LD; Rocha, J; Paz, FAA
2014, JOURNAL OF MATERIALS CHEMISTRY C, 2, 17, 3311-3327.

Photoluminescent layered lanthanide-organic framework based on a novel trifluorotriphosphonate organic linker

Vilela, SMF; Fernandes, JA; Ananias, D; Carlos, LD; Rocha, J; Tome, JPC; Paz, FAA
2014, CRYSTENGCOMM, 16, 3, 344-358.

Designing Near-Infrared and Visible Light Emitters by Postsynthetic Modification of Ln(+3)-IRMOF-3

Abdelhameed, RM; Carlos, LD; Rabu, P; Santos, SM; Silva, AMS; Rocha, J
2014, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 31, 5285-5295.

Delta(1)-pyrroline based boranyls: Synthesis, crystal structures and luminescent properties

Cardona, F; Rocha, J; Silva, AMS; Guieu, S
2014, DYES AND PIGMENTS, 111, 16-20.

Cobalt(II)-pyrazine-chloride coordination polymers: synthesis, reactivity and magnetic properties

de Campos, EA; Silva, NJO; Shi, FN; Rocha, J
2014, CRYSTENGCOMM, 16, 45, 10439-10444.

Luminescent bi-metallic fluoroborate derivatives of bulky salen ligands

Guieu, S; Cardona, F; Rocha, J; Silva, AMS
2014, NEW JOURNAL OF CHEMISTRY, 38, 11, 5411-5414.

A Multidisciplinary Approach to Evaluate the Efficiency of a Clean-Up Technology to Remove Mercury from Water

Lopes, CB; Lopes, I; Rocha, LS; Duarte, AC; Soares, AMVM; Rocha, J; Pereira, E
2014, BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY, 93, 2, 138-143.

Catalytic behavior of alkali-treated Pt/HMOR in n-hexane hydroisomerization

Monteiro, R; Ania, CO; Rocha, J; Carvalho, AP; Martins, A
2014, APPLIED CATALYSIS A-GENERAL, 476, 148-157.

Monitoring hydration in lime-metakaolin composites using electrochemical impedance spectroscopy and nuclear magnetic resonance spectroscopy

Pesce, GL; Bowen, CR; Rocha, J; Sardo, M; Allen, GC; Walker, PJ; Denuault, G; Serrapede, M; Ball, RJ
2014, CLAY MINERALS, 49, 3, 341-358.

Microporous titanosilicates Cu2+- and Co2+-ETS-4 for storage and slow release of therapeutic nitric oxide

Pinto, ML; Fernandes, AC; Rocha, J; Ferreira, A; Antunes, F; Pires, J
2014, JOURNAL OF MATERIALS CHEMISTRY B, 2, 2, 224-230.

Formation of Photoluminescent Lead Bromide Nanoparticles on Aluminoborosilicate Glass

Ruivo, A; Andrade, SM; Rocha, J; Laia, CAT; Pina, F
2014, JOURNAL OF PHYSICAL CHEMISTRY C, 118, 23, 12436-12442.

Structure, topology, gas adsorption and photoluminescence of multifunctional porous RE3+-furan-2,5-dicarboxylate metal organic frameworks

Shi, FN; Pinto, ML; Ananias, D; Rocha, J
2014, MICROPOROUS AND MESOPOROUS MATERIALS, 188, 172-181.

Hybrid silica nanoparticles for sequestration and luminescence detection of trivalent rare-earth ions (Dy3+ and Nd3+) in solution

Topel, SD; Legaria, EP; Tiseanu, C; Rocha, J; Nedelec, JM; Kessler, VG; Seisenbaeva, GA
2014, JOURNAL OF NANOPARTICLE RESEARCH, 16, 12.

Coordination polymers based on a glycine-derivative ligand

Vilela, SMF; Ananias, D; Silva, P; Nolasco, M; Carlos, LD; Bermudez, VD; Rocha, J; Tome, JPC; Paz, FAA
2014, CRYSTENGCOMM, 16, 35, 8119-8137.

Crystal structure, topology, tiling and photoluminescence properties of 4d-4f hetero-metal organic frameworks based on 3,5-pyrazoledicaboxylate

Yang, TH; Ferreira, RAS; Carlos, LD; Rocha, J; Shi, FN
2014, RSC ADVANCES, 4, 15, 7818-7825.

Oxidation of cyclohexane by transition-metal complexes with biomimetic ligands

Silva, AR; Mourao, T; Rocha, J
2013, CATALYSIS TODAY, 203, 81-86.

Photoluminescent Epoxy/Gd2O3:Eu3+ UV-cured Nanocomposites

Roppolo, I; Debasu, ML; Ferreira, RAS; Rocha, J; Carlos, LD; Sangermano, M
2013, MACROMOLECULAR MATERIALS AND ENGINEERING, 298, 2, 181-189.

Chiral microporous rare-earth silico-germanates: Synthesis, structure and photoluminescence properties

Ananias, D; Paz, FAA; Carlos, LD; Rocha, J
2013, MICROPOROUS AND MESOPOROUS MATERIALS, 166, 50-58.

Core-shell magnetite-silica dithiocarbamate-derivatised particles achieve the Water Framework Directive quality criteria for mercury in surface waters

Lopes, CB; Figueira, P; Tavares, DS; Lin, Z; Daniel-da-Silva, AL; Duarte, AC; Rocha, J; Trindade, T; Pereira, E
2013, ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 20, 9, 5963-5974.

Synthesis and characterization of polymorphs of photoluminescent Eu(III)-(2,5-furandicarboxylic acid, oxalic acid) MOFs

Shi, FN; Ananias, D; Yang, TH; Rocha, J
2013, JOURNAL OF SOLID STATE CHEMISTRY, 204, 321-328.

meso-Tetraphenylbenzoporphyrin-2(2),2(3)-dicarboxylic Anhydride: A Platform to Benzoporphyrin Derivatives

Carvalho, CMB; Santos, SM; Neves, MGPMS; Tome, AC; Silva, AMS; Rocha, J; Cavaleiro, JAS
2013, JOURNAL OF ORGANIC CHEMISTRY, 78, 13, 6622-6631.

Supramolecular assemblies and magnetic behaviors of the M(II)/p-aminopyridine/malonate (M = Ni, Mn, Cu, Co) systems

Fernandes, RJ; Frem, RCG; da Silva, PB; Freitas, RS; Silva, P; Fernandes, JA; Rocha, J; Paz, FAA
2013, POLYHEDRON, 57, 112-117.

NMR Crystallography: Toward Chemical Shift-Driven Crystal Structure Determination of the beta-Lactam Antibiotic Amoxicillin Trihydrate

Santos, SM; Rocha, J; Mafra, L
2013, CRYSTAL GROWTH & DESIGN, 13, 6, 2390-2395.

Metal-Organic Frameworks Assembled From Erbium Tetramers and 2,5-Pyridinedicarboxylic Acid

Silva, P; Cunha-Silva, L; Silva, NJO; Rocha, J; Paz, FAA
2013, CRYSTAL GROWTH & DESIGN, 13, 6, 2607-2617.

Synthesis, crystal structure, and luminescence of tetrakis (4-methoxyphenyl)methane

Guieu, S; Rocha, J; Silva, AMS
2013, TETRAHEDRON LETTERS, 54, 22, 2870-2873.

Synthesis of Unsymmetrical Methylenebisphenol Derivatives

Guieu, S; Rocha, J; Silva, AMS
2013, SYNLETT, 24, 6, 762-764.

Supramolecular organization of bis(3-halo-4-dimethylaminobenzylidene)hydrazines

Guieu, S; Rocha, J; Silva, AMS
2013, JOURNAL OF MOLECULAR STRUCTURE, 1035, 1-5.

Efficient sorbents based on magnetite coated with siliceous hybrid shells for removal of mercury ions

Tavares, DS; Daniel-da-Silva, AL; Lopes, CB; Silva, NJO; Amaral, VS; Rocha, J; Pereira, E; Trindade, T
2013, JOURNAL OF MATERIALS CHEMISTRY A, 1, 28, 8134-8143.

Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties

Vilela, SMF; Firmino, ADG; Mendes, RF; Fernandes, JA; Ananias, D; Valente, AA; Ott, H; Carlos, LD; Rocha, J; Tome, JPC; Paz, FAA
2013, CHEMICAL COMMUNICATIONS, 49, 57, 6400-6402.

Near-infrared emitters based on post-synthetic modified Ln(3+)-IRMOF-3

Abdelhameed, RM; Carlos, LD; Silva, AMS; Rocha, J
2013, CHEMICAL COMMUNICATIONS, 49, 44, 5019-5021.

Mixed Cu(II)-Bi(III) metal organic framework with a 2D inorganic subnetwork and its catalytic activity

Shi, FN; Silva, AR; Yang, TH; Rocha, J
2013, CRYSTENGCOMM, 15, 19, 3776-3779.

Conversion of furfuryl alcohol to ethyl levulinate using porous aluminosilicate acid catalysts

Neves, P; Lima, S; Pillinger, M; Rocha, SM; Rocha, J; Valente, AA
2013, CATALYSIS TODAY, 218, 76-84.

All-In-One Optical Heater-Thermometer Nanoplatform Operative From 300 to 2000 K Based on Er3+ Emission and Blackbody Radiation

Debasu, ML; Ananias, D; Pastoriza-Santos, I; Liz-Marzan, LM; Rocha, J; Carlos, LD
2013, ADVANCED MATERIALS, 25, 35, 4868-4874.

Ratiometric Nanothermometer Based on an Emissive Ln(3+)-Organic Framework

Cadiau, A; Brites, CDS; Costa, PMFJ; Ferreira, RAS; Rocha, J; Carlos, LD
2013, ACS NANO, 7, 8, 7213-7218.

Transposition of chirality from diphosphonate metal-organic framework precursors onto porous lanthanide pyrophosphates

Shi, FN; Paz, FAA; Ribeiro-Claro, P; Rocha, J
2013, CHEMICAL COMMUNICATIONS, 49, 99, 11668-11670.

Energy-transfer from Gd(III) to Tb(III) in (Gd,Yb,Tb)PO4 nanocrystals

Debasu, ML; Ananias, D; Rocha, J; Malta, OL; Carlos, LD
2013, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 15, 37, 15565-15571.

Preparation of crystal-like periodic mesoporous phenylene-silica derivatized with ferrocene and its use as a catalyst for the oxidation of styrene

Gomes, AC; Ferreira, MJ; Bruno, SM; Bion, N; Ferreira, P; Valente, AA; Pillinger, M; Rocha, J; Goncalves, IS
2013, DALTON TRANSACTIONS, 42, 40, 14612-14620.

Potentiation of 5-fluorouracil encapsulated in zeolites as drug delivery systems for in vitro models of colorectal carcinoma

Vilaca, N; Amorim, R; Machado, AF; Parpot, P; Pereira, MFR; Sardo, M; Rocha, J; Fonseca, AM; Neves, IC; Baltazar, F
2013, COLLOIDS AND SURFACES B-BIOINTERFACES, 112, 237-244.

Photoluminescent Metal-Organic Frameworks - Rapid Preparation, Catalytic Activity, and Framework Relationships

Silva, P; Ananias, D; Bruno, SM; Valente, AA; Carlos, LD; Rocha, J; Paz, FAA
2013, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 32, 5576-5591.

Crystallization-induced light-emission enhancement of diphenylmethane derivatives

Guieu, S; Rocha, J; Silva, AMS
2013, TETRAHEDRON, 69, 44, 9329-9334.

Silica Nanoparticles for Bimodal MRI-Optical Imaging by Grafting Gd3+and Eu3+/Tb3+Complexes

Pinho, SLC; Faneca, H; Geraldes, CFGC; Rocha, J; Carlos, LD; Delville, MH
2012, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 16, 2828-2837.

Co-II/Zn-II-(L-Tyrosine) Magnetic Metal-Organic Frameworks

Zhou, B; Silva, NJO; Shi, FN; Palacio, F; Mafra, L; Rocha, J
2012, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 32, 5259-5268.

Composition of neutral lipid classes and content of fatty acids throughout sourdough breadmaking

Rocha, JM; Kalo, PJ; Malcata, FX
2012, EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 114, 3, 294-305.

Fatty Acid Composition of Non-Starch and Starch Neutral Lipid Extracts of Portuguese Sourdough Bread

Rocha, JM; Kalo, PJ; Malcata, FX
2012, JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 89, 11, 2025-2045.

Lanthanide-DTPA grafted silica nanoparticles as bimodal-imaging contrast agents

Pinho, SLC; Faneca, H; Geraldes, CFGC; Delville, MH; Carlos, LD; Rocha, J
2012, BIOMATERIALS, 33, 3, 925-935.

Modification of MCM-22 zeolite through sequential post-synthesis treatments. Implications on the acidic and catalytic behaviour

Machado, V; Rocha, J; Carvalho, AP; Martins, A
2012, APPLIED CATALYSIS A-GENERAL, 445, 329-338.

Series of Metal Organic Frameworks Assembled from Ln(III), Na(I), and Chiral Flexible-Achiral Rigid Dicarboxylates Exhibiting Tunable UV-vis-IR Light Emission

Amghouz, Z; Garcia-Granda, S; Garcia, JR; Ferreira, RAS; Mafra, L; Carlos, LD; Rocha, J
2012, INORGANIC CHEMISTRY, 51, 3, 1703-1716.

Relaxometric Studies of gamma-Fe2O3@SiO2 Core Shell Nanoparticles: When the Coating Matters

Pinho, SLC; Laurent, S; Rocha, J; Roch, A; Delville, MH; Mornet, S; Carlos, LD; Vander Elst, L; Muller, RN; Geraldes, CFGC
2012, JOURNAL OF PHYSICAL CHEMISTRY C, 116, 3, 2285-2291.

Combining Multinuclear High-Resolution Solid-State MAS NMR and Computational Methods for Resonance Assignment of Glutathione Tripeptide

Sardo, M; Siegel, R; Santos, SM; Rocha, J; Gomes, JRB; Mafra, L
2012, JOURNAL OF PHYSICAL CHEMISTRY A, 116, 25, 6711-6719.

Zeolite Structures Loading with an Anticancer Compound As Drug Delivery Systems

Amorim, R; Vilaca, N; Martinho, O; Reis, RM; Sardo, M; Rocha, J; Fonseca, AM; Baltazar, F; Neves, IC
2012, JOURNAL OF PHYSICAL CHEMISTRY C, 116, 48, 25642-25650.

Ligand design for functional metal-organic frameworks

Paz, FAA; Klinowski, J; Vilela, SMF; Tome, JPC; Cavaleiro, JAS; Rocha, J
2012, CHEMICAL SOCIETY REVIEWS, 41, 3, 1088-1110.

Highly emissive Zn-Ln metal-organic frameworks with an unusual 3D inorganic subnetwork

Liu, CB; Ferreira, RAS; Paz, FAA; Cadiau, A; Carlos, LD; Fu, LS; Rocha, J; Shi, FN
2012, CHEMICAL COMMUNICATIONS, 48, 64, 7964-7966.

Multi-functional metal-organic frameworks assembled from a tripodal organic linker

Vilela, SMF; Ananias, D; Gomes, AC; Valente, AA; Carlos, LD; Cavaleiro, JAS; Rocha, J; Tome, JPC; Paz, FAA
2012, JOURNAL OF MATERIALS CHEMISTRY, 22, 35, 18354-18371.

(Gd,Yb,Tb)PO4 up-conversion nanocrystals for bimodal luminescence-MR imaging

Debasu, ML; Ananias, D; Pinho, SLC; Geraldes, CFGC; Carlos, LD; Rocha, J
2012, NANOSCALE, 4, 16, 5154-5162.

Mixed-Metal d-f Phosphonate Frameworks - Photoluminescence and Magnetic Properties

Rocha, J; Paz, FAA; Shi, FN; Ananias, D; Silva, NJO; Carlos, LD; Trindade, T
2011, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 13, 2035-2044.

Desilication of MOR zeolite: Conventional versus microwave assisted heating

Paixao, V; Monteiro, R; Andrade, M; Fernandes, A; Rocha, J; Carvalho, AP; Martins, A
2011, APPLIED CATALYSIS A-GENERAL, 402, 1-2, 59-68.

Metal-organic framework based on copper(I) sulfate and 4,4 '-bipyridine catalyzes the cyclopropanation of styrene

Shi, FN; Silva, AR; Rocha, J
2011, JOURNAL OF SOLID STATE CHEMISTRY, 184, 8, 2196-2203.

Titanosilicate AM-3 membrane A new potential candidate for H-2 separation

Li, XW; Zhou, CF; Lin, Z; Rocha, J; Lito, PF; Santiago, AS; Silva, CM
2011, MICROPOROUS AND MESOPOROUS MATERIALS, 137, 1-3, 43-48.

Direct synthesis without addition of acid of Al-SBA-15 with controllable porosity and high hydrothermal stability

Lin, S; Shi, L; Carrott, MMLR; Carrott, PJM; Rocha, J; Li, MR; Zou, XD
2011, MICROPOROUS AND MESOPOROUS MATERIALS, 142, 2-3, 526-534.

Fixed-bed removal of Hg2+ from contaminated water by microporous titanosilicate ETS-4: Experimental and theoretical breakthrough curves

Lopes, CB; Pereira, E; Lin, Z; Pato, P; Otero, M; Silva, CM; Rocha, J; Duarte, AC
2011, MICROPOROUS AND MESOPOROUS MATERIALS, 145, 1-3, 32-40.

A new supramolecular organic-inorganic adduct: {[Eu(CH3OH)(H2O)(8)](2) [Eu(H2O)(8)][PW12O40](3)}center dot 8(C14H20O5)center dot 2(C28H40O10)center dot 6(CH3OH)center dot 6(H2O)

Soares-Santos, PCR; Cunha-Silva, L; Sousa, FL; Sousa, JLC; Gates, PJ; Klinowski, J; Trindade, T; Rocha, J; Cavaleiro, AMV; Paz, FAA; Nogueira, HIS
2011, JOURNAL OF MOLECULAR STRUCTURE, 989, 1-3, 80-85.

Syntheses, structures and properties of two cadmium compounds containing neutral or in situ protonized 1,4-diazabicyclo[2.2.2]octane

Wang, XF; Qi, XL; Shi, FN; Rocha, J
2011, JOURNAL OF MOLECULAR STRUCTURE, 1004, 1-3, 26-30.

Improving the H-1 indirect dimension resolution of 2D CRAMPS NMR spectra: A simulation and experimental investigation

Siegel, R; Mafra, L; Rocha, J
2011, SOLID STATE NUCLEAR MAGNETIC RESONANCE, 39, 3-4, 81-87.

Adsorption and Activation of CO2 by Amine-Modified Nanoporous Materials Studied by Solid-State NMR and (CO2)-C-13 Adsorption

Pinto, ML; Mafra, L; Guil, JM; Pires, J; Rocha, J
2011, CHEMISTRY OF MATERIALS, 23, 6, 1387-1395.

Multiwavelength Luminescence in Lanthanide-Doped Hydrocalumite and Mayenite

Dominguez, M; Perez-Bernal, ME; Ruano-Casero, RJ; Barriga, C; Rives, V; Ferreira, RAS; Carlos, LD; Rocha, J
2011, CHEMISTRY OF MATERIALS, 23, 7, 1993-2004.

Synthesis and Catalytic Properties of Molybdenum(VI) Complexes with Tris(3,5-dimethyl-1-pyrazolyl)methane

Neves, P; Gago, S; Balula, SS; Lopes, AD; Valente, AA; Cunha-Silva, L; Paz, FAA; Pillinger, M; Rocha, J; Silva, CM; Goncalves, IS
2011, INORGANIC CHEMISTRY, 50, 8, 3490-3500.

Slow Release of NO by Microporous Titanosilicate ETS-4

Pinto, ML; Rocha, J; Gomes, JRB; Pires, J
2011, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133, 16, 6396-6402.

Thermal Transformation of a Layered Multifunctional Network into a Metal-Organic Framework Based on a Polymeric Organic Linker

Silva, P; Vieira, F; Gomes, AC; Ananias, D; Fernandes, JA; Bruno, SM; Soares, R; Valente, AA; Rocha, J; Paz, FAA
2011, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133, 38, 15120-15138.

Emission-Decay Curves, Energy-Transfer and Effective-Refractive Index in Gd2O3:Eu3+ Nanorods

Debasu, ML; Ananias, D; Macedo, AG; Rocha, J; Carlos, LD
2011, JOURNAL OF PHYSICAL CHEMISTRY C, 115, 31, 15297-15303.

Luminescent multifunctional lanthanides-based metal-organic frameworks

Rocha, J; Carlos, LD; Paz, FAA; Ananias, D
2011, CHEMICAL SOCIETY REVIEWS, 40, 2, 926-940.

Microwave-Assisted Synthesis of Metal-Organic Frameworks

Klinowski, J; Paz, FAA; Silva, P; Rocha, J
2011, DALTON TRANSACTIONS, 40, 2, 321-330.

Inclusion of potassium 4,4 '-biphenyldicarboxylate into beta-cyclodextrin: the design and synthesis of an organic secondary building unit

Fernandes, JA; Paz, FAA; Braga, SS; Ribeiro-Claro, PJA; Rocha, J
2011, NEW JOURNAL OF CHEMISTRY, 35, 6, 1280-1290.

Layered titanosilicates

Lin, Z; Paz, FAA; Rocha, J
2011, LAYERED MINERAL STRUCTURES AND THEIR APPLICATION IN ADVANCED TECHNOLOGIES, 11, 123-149.
ISBN: 978-0-903056-29-8

Effects of Phonon Confinement on Anomalous Thermalization, Energy Transfer, and Upconversion in Ln(3+)-Doped Gd2O3 Nanotubes

Macedo, AG; Ferreira, RAS; Ananias, D; Reis, MS; Amaral, VS; Carlos, LD; Rocha, J
2010, ADVANCED FUNCTIONAL MATERIALS, 20, 4, 624-634.

Grafting of Molecularly Ordered Mesoporous Phenylene-Silica with Molybdenum Carbonyl Complexes: Efficient Heterogeneous Catalysts for the Epoxidation of Olefins

Coelho, AC; Balula, SS; Bruno, SM; Alonso, JC; Bion, N; Ferreira, P; Pillinger, M; Valente, AA; Rocha, J; Goncalves, IS
2010, ADVANCED SYNTHESIS & CATALYSIS, 352, 10, 1759-1769.

3D-2D-0D Stepwise Deconstruction of a Water Framework Templated by a Nanoporous Organic-Inorganic Hybrid Host

Rocha, J; Shi, FN; Paz, FAA; Mafra, L; Sardo, M; Cunha-Silva, L; Chisholm, J; Ribeiro-Claro, P; Trindade, T
2010, CHEMISTRY-A EUROPEAN JOURNAL, 16, 26, 7741-7749.

Synthesis, structures and magnetic properties of three metal-organic frameworks containing manganese(II)

Shi, FN; Reis, MS; Brandao, P; Souza, AM; Felix, V; Rocha, J
2010, TRANSITION METAL CHEMISTRY, 35, 7, 779-786.

Modelling gas permeation through new microporous titanosilicate AM-3 membranes

Lito, PF; Zhou, CF; Santiago, AS; Rodrigues, AE; Rocha, J; Lin, Z; Silva, CM
2010, CHEMICAL ENGINEERING JOURNAL, 165, 2, 395-404.

Physicochemical characterization of silylated functionalized materials

Borrego, T; Andrade, M; Pinto, ML; Silva, AR; Carvalho, AP; Rocha, J; Freire, C; Pires, J
2010, JOURNAL OF COLLOID AND INTERFACE SCIENCE, 344, 2, 603-610.

Effect of pH and temperature on Hg2+ water decontamination using ETS-4 titanosilicate

Lopes, CB; Otero, M; Lin, Z; Silva, CM; Pereira, E; Rocha, J; Duarte, AC
2010, JOURNAL OF HAZARDOUS MATERIALS, 175, 1-3, 439-444.

Novel microporous zirconium silicate (K2ZrSi3O9 center dot 2H(2)O) from high temperature phase transformation

Ferreira, A; Lin, Z; Soares, MR; Rocha, J
2010, JOURNAL OF SOLID STATE CHEMISTRY, 183, 12, 3067-3072.

Modification of MOR by desilication treatments: Structural, textural and acidic characterization

Paixao, V; Carvalho, AP; Rocha, J; Fernandes, A; Martins, A
2010, MICROPOROUS AND MESOPOROUS MATERIALS, 131, 1-3, 350-357.

Complexation of crystal-like mesoporous phenylene-silica with Cr(CO)(3) and catalytic performance in the oxidation of cyclooctene

Coelho, AC; Balula, SS; Antunes, MM; Gerganova, TI; Bion, N; Ferreira, P; Pillinger, M; Valente, AA; Rocha, J; Goncalves, IS
2010, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 332, 1-2, 13-18.

Luminescent SiO2-coated Gd2O3:Eu3+ nanorods/poly(styrene) nanocomposites by in situ polymerization

Macedo, AG; Martins, MA; Fernandes, SEM; Barros-Timmons, A; Trindade, T; Carlos, LD; Rocha, J
2010, OPTICAL MATERIALS, 32, 12, 1622-1628.

Crystal and supramolecular structures of dioxomolybdenum(VI) and dioxotungsten(VI) complexes of dihydroxybenzoic acids

Monteiro, B; Cunha-Silva, L; Gago, S; Klinowski, J; Paz, FAA; Rocha, J; Goncalves, IS; Pillinger, M
2010, POLYHEDRON, 29, 2, 719-730.

Fast Microwave Synthesis of a Microporous Lanthanide Organic Framework

Silva, P; Valente, AA; Rocha, J; Paz, FAA
2010, CRYSTAL GROWTH & DESIGN, 10, 5, 2025-2028.

Metal Organic Frameworks Assembled from Y(III), Na(I), and Chiral Flexible-Achiral Rigid Dicarboxylates

Amghouz, Z; Roces, L; Garcia-Granda, S; Garcia, JR; Souhail, B; Mafra, L; Shi, FN; Rocha, J
2010, INORGANIC CHEMISTRY, 49, 17, 7917-7926.

Revisiting the Thermal Decomposition of Layered gamma-Titanium Phosphate and Structural Elucidation of Its Intermediate Phases

Garcia-Granda, S; Khainakov, SA; Espina, A; Garcia, JR; Castro, GR; Rocha, J; Mafra, L
2010, INORGANIC CHEMISTRY, 49, 6, 2630-2638.

Evaluation of [Ln(H(2)cmp)(H2O)] Metal Organic Framework Materials for Potential Application as Magnetic Resonance Imaging Contrast Agents

Pereira, GA; Peters, JA; Paz, FAA; Rocha, J; Geraldes, CFGC
2010, INORGANIC CHEMISTRY, 49, 6, 2969-2974.

Photo luminescent Lanthanide-Organic Bilayer Networks with 2,3-Pyrazinedicarboxylate and Oxalate

Soares-Santos, PCR; Cunha-Silva, L; Paz, FAA; Ferreira, RAS; Rocha, J; Carlos, LD; Nogueira, HIS
2010, INORGANIC CHEMISTRY, 49, 7, 3428-3440.

Synthesis, Texture, and Photoluminescence of Lanthanide-Containing Chitosan-Silica Hybrids

Liu, FY; Carlos, LD; Ferreira, RAS; Rocha, J; Ferro, MC; Tourrette, A; Quignard, F; Robitzer, M
2010, JOURNAL OF PHYSICAL CHEMISTRY B, 114, 1, 77-83.

Fine Tuning of the Relaxometry of gamma-Fe2O3@SiO2 Nanoparticles by Tweaking the Silica Coating Thickness

Pinho, SLC; Pereira, GA; Voisin, P; Kassem, J; Bouchaud, V; Etienne, L; Peters, JA; Carlos, LD; Mornet, S; Geraldes, CFGC; Rocha, J; Delville, MH
2010, ACS NANO, 4, 9, 5339-5349.

Functional Cationic Nanomagnet - Porphyrin Hybrids for the Photoinactivation of Microorganisms

Carvalho, CMB; Alves, E; Costa, L; Tome, JPC; Faustino, MAF; Neves, MGPMS; Tome, AC; Cavaleiro, JAS; Almeida, A; Cunha, A; Lin, Z; Rocha, J
2010, ACS NANO, 4, 12, 7133-7140.

Diaquabis(ethylenediamine-kappa N-2,N ')copper(II) bis(4-phenylbenzoate) 2.66-hydrate

Fernandes, JA; Ramos, AI; Silva, P; Braga, SS; Ribeiro-Claro, P; Rocha, J; Paz, FAA
2010, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 66, M626-U324.

(R)-(1-Ammonioethyl)phosphonate

Fernandes, JA; Paz, FAA; Vilela, SMF; Tome, JPC; Cavaleiro, JAS; Ribeiro-Claro, PJA; Rocha, J
2010, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 66, O2271-U24.

trans-Bis(4,7-diphenyl-1,10-phenanthroline-kappa N-2,N ')bis(nitrato-kappa O-2,O ')zinc(II)

Fernandes, JA; Paz, FAA; Liu, FY; Cunha-Silva, L; Carlos, LD; Rocha, J
2010, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 66, M1608-U1159.

Trimethyl 2,2 ',2 ''-[1,3,5-triazine-2,4,6triyltris(azanediyl)]triacetate

Vilela, SMF; Paz, FAA; Tome, JPC; Bermudez, VD; Cavaleiro, JAS; Rocha, J
2010, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 66, O3243-U1308.

Catalytic Performance of Ceria Nanorods in Liquid-Phase Oxidations of Hydrocarbons with tert-Butyl Hydroperoxide

Macedo, AG; Fernandes, SEM; Valente, AA; Ferreira, RAS; Carlos, LD; Rocha, J
2010, MOLECULES, 15, 2, 747-765.

REMOVAL OF MERCURY FROM AQUEOUS SOLUTIONS BY ETS-4 MICROPOROUS TITANOSILICATE: EFFECT OF CONTACT TIME, TITANOSILICATE MASS AND INITIAL METAL CONCENTRATION

Lopes, CB; Otero, M; Lin, Z; Pereira, E; Silva, CM; Rocha, J; Duarte, AC
2009, ICEM2007: PROCEEDINGS OF THE 11TH INTERNATIONAL CONFERENCE ON ENVIRONMENTAL REMEDIATION AND RADIOACTIVE WASTE MANAGEMENT, PTS A AND B, 1019-1023.
ISBN: 978-0-7918-4339-0

A Miniaturized Linear pH Sensor Based on a Highly Photoluminescent Self-Assembled Europium(III) Metal-Organic Framework

Harbuzaru, BV; Corma, A; Rey, F; Jorda, JL; Ananias, D; Carlos, LD; Rocha, J
2009, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 48, 35, 6476-6479.

Photoluminescent Porous Modular Lanthanide-Vanadium-Organic Frameworks

Rocha, J; Paz, FAA; Shi, FN; Ferreira, RAS; Trindade, T; Carlos, LD
2009, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 33, 4931-4945.

1D to 3D NMR study of microporous alumino-phosphate AlPO4-40

Morais, CM; Montouillout, V; Deschamps, M; Iuga, D; Fayon, F; Paz, FAA; Rocha, J; Fernandez, C; Massiot, D
2009, MAGNETIC RESONANCE IN CHEMISTRY, 47, 11, 942-947.

Cadmium(II) removal from aqueous solution using microporous titanosilicate ETS-4

Ferreira, TR; Lopes, CB; Lito, PF; Otero, M; Lin, Z; Rocha, J; Pereira, E; Silva, CM; Duarte, A
2009, CHEMICAL ENGINEERING JOURNAL, 147, 2-3, 173-179.

Removal of Hg2+ ions from aqueous solution by ETS-4 microporous titanosilicate-Kinetic and equilibrium studies

Lopes, CB; Otero, M; Lin, Z; Silva, CM; Rocha, J; Pereira, E; Duarte, AC
2009, CHEMICAL ENGINEERING JOURNAL, 151, 1-3, 247-254.

Cadmium(II) removal from aqueous solution using microporous titanosilicate ETS-10

Camarinha, ED; Lito, PF; Antunes, BM; Otero, M; Lin, Z; Rocha, J; Pereira, E; Duarte, AC; Silva, CM
2009, CHEMICAL ENGINEERING JOURNAL, 155, 1-2, 108-114.

Effect of pH on cadmium (II) removal from aqueous solution using titanosilicate ETS-4

Barreira, LD; Lito, PF; Antunes, BM; Otero, M; Lin, Z; Rocha, J; Pereira, E; Duarte, AC; Silva, CM
2009, CHEMICAL ENGINEERING JOURNAL, 155, 3, 728-735.

Combining STMAS and CRAMPS NMR spectroscopy: High-resolution HETCOR NMR spectra of quadrupolar and H-1 nuclei in solids

Siegel, R; Rocha, J; Mafra, L
2009, CHEMICAL PHYSICS LETTERS, 470, 4-6, 337-341.

Priority pollutants (Hg2+ and Cd2+) removal from water by ETS-4 titanosilicate

Otero, M; Lopes, CB; Coimbra, J; Ferreira, TR; Silva, CM; Lin, Z; Rocha, J; Pereira, E; Duarte, AC
2009, DESALINATION, 249, 2, 742-747.

Supramolecular salts containing the anionic [Ge(C(2)O(4))(3)](2-) complex and heteroaromatic amines

Cunha-Silva, L; Shi, FN; Paz, FAA; Hardie, MJ; Klinowski, J; Trindade, T; Rocha, J
2009, INORGANICA CHIMICA ACTA, 362, 1, 263-270.

H-1-H-1 double-quantum CRAMPS NMR at very-fast MAS (nu(R)=35 kHz): A resolution enhancement method to probe H-1-H-1 proximities in solids

Mafra, L; Gomes, JRB; Trebosc, J; Rocha, J; Amoureux, JP
2009, JOURNAL OF MAGNETIC RESONANCE, 196, 1, 88-91.

Assessing the performance of windowed H-1 CRAMPS methods, on biological solids, at high-field and MAS up to 35 kHz

Mafra, L; Coelho, C; Siegel, R; Rocha, J
2009, JOURNAL OF MAGNETIC RESONANCE, 197, 1, 20-27.

High-resolution H-1 homonuclear dipolar recoupling NMR spectra of biological solids at MAS rates up to 67 kHz

Mafra, L; Siegel, R; Fernandez, C; Schneider, D; Aussenac, F; Rocha, J
2009, JOURNAL OF MAGNETIC RESONANCE, 199, 1, 111-114.

Carboxylate-intercalated layered double hydroxides aged under microwave-hydrothermal treatment

Benito, P; Labajos, FM; Mafra, L; Rocha, J; Rives, V
2009, JOURNAL OF SOLID STATE CHEMISTRY, 182, 1, 18-26.

Magnetic properties of KNaMSi4O10 compounds (M = Mn, Fe, Cu)

Brandao, P; Rocha, J; Reis, MS; dos Santos, AM; Jin, R
2009, JOURNAL OF SOLID STATE CHEMISTRY, 182, 2, 253-258.

Yttrium-succinates coordination polymers: Hydrothermal synthesis, crystal structure and thermal decomposition

Amghouz, Z; Roces, L; Garcia-Granda, S; Garcia, JR; Souhail, B; Mafra, L; Shi, FN; Rocha, J
2009, JOURNAL OF SOLID STATE CHEMISTRY, 182, 12, 3365-3373.

Preparation of stable MCM-48 tubular membranes

Pedernera, M; de la Iglesia, O; Mallada, R; Lin, Z; Rocha, J; Coronas, J; Santamaria, J
2009, JOURNAL OF MEMBRANE SCIENCE, 326, 1, 137-144.

Three-Dimensional Lanthanide-Organic Frameworks Based on Di-, Tetra-, and Hexameric Clusters

Shi, FN; Cunha-Silva, L; Trindade, T; Paz, FAA; Rocha, J
2009, CRYSTAL GROWTH & DESIGN, 9, 5, 2098-2109.

New Crystalline Layered Zinc Phosphate with 10-Membered-Ring Channels Perpendicular to Layers

Liu, L; Ferdov, S; Coelho, C; Kong, Y; Mafra, L; Li, JP; Dong, JX; Kolitsch, U; Ferreira, RAS; Tillmanns, E; Rocha, J; Lin, Z
2009, INORGANIC CHEMISTRY, 48, 11, 4598-4600.

Molecule-Like Eu3+-Dimers Embedded in an Extended System Exhibit Unique Photoluminescence Properties

Ananias, D; Kostova, M; Paz, FAA; Neto, ANC; De Moura, RT; Malta, OL; Carlos, LD; Rocha, J
2009, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 131, 24, 8620-8626.

Multi-functional rare-earth hybrid layered networks: photoluminescence and catalysis studies

Cunha-Silva, L; Lima, S; Ananias, D; Silva, P; Mafra, L; Carlos, LD; Pillinger, M; Valente, AA; Paz, FAA; Rocha, J
2009, JOURNAL OF MATERIALS CHEMISTRY, 19, 17, 2618-2632.

Glycine methyl ester hydrochloride

Vilela, SMF; Paz, FAA; Tome, JPC; Bermudez, VD; Cavaleiro, JAS; Rocha, J
2009, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 65, O1970-U3925.

Methyl 2-(4,6-dichloro-1,3,5-triazin-2-ylamino)acetate

Vilela, SMF; Paz, FAA; Tome, JPC; Bermudez, VD; Cavaleiro, JAS; Rocha, J
2009, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 65, O1985-U4085.

Entanglement temperature in molecular magnets composed of S-spin dimers

Soares-Pinto, DO; Souza, AM; Sarthour, RS; Oliveira, IS; Reis, MS; Brandao, P; Rocha, J; dos Santos, AM
2009, EPL, 87, 4.

Synchrotron powder structure of a new layered lanthanide-organic network

Cunha-Silva, L; Ananias, D; Carlos, LD; Paz, FAA; Rocha, J
2009, ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 224, 5-6, 261-272.

Enhancing the Scratch Resistance of Polycarbonate With Poly(Ethylene Oxide)-Silica Hybrid Coatings

Fabbri, P; Messori, M; Toselli, M; Veronesi, P; Rocha, J; Pilati, F
2008, ADVANCES IN POLYMER TECHNOLOGY, 27, 2, 117-126.

Metal-organic nanoporous structures with anisotropic photoluminescence and magnetic properties and their use as sensors

Harbuzaru, BV; Corma, A; Rey, F; Atienzar, P; Jorda, JL; Garcia, H; Ananias, D; Carlos, LD; Rocha, J
2008, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 47, 6, 1080-1083.

Photoluminescent Microporous Lanthanide Silicate AV-21 Frameworks

Kowalchuk, CM; Paz, FAA; Ananias, D; Pattison, P; Carlos, LD; Rocha, J
2008, CHEMISTRY-A EUROPEAN JOURNAL, 14, 27, 8157-8168.

Isomerization of D-glucose to D-fructose over metallosilicate solid bases

Lima, S; Dias, AS; Lin, Z; Brandao, P; Ferreira, P; Pillinger, M; Rocha, J; Calvino-Casilda, V; Valente, AA
2008, APPLIED CATALYSIS A-GENERAL, 339, 1, 21-27.

New waste based clinkers: Belite and lime formulations

Raupp-Pereira, F; Ball, RJ; Rocha, J; Labrincha, JA; Allen, GC
2008, CEMENT AND CONCRETE RESEARCH, 38, 4, 511-521.

Suitability evaluation of sol-gel derived Si-substituted hydroxyapatite for dental and maxillofacial applications through in vitro osteoblasts response

Balamurugan, A; Rebelo, AHS; Lemos, AF; Rocha, JHG; Ventura, JMG; Ferreira, JMF
2008, DENTAL MATERIALS, 24, 10, 1374-1380.

A novel germanium(IV) oxalate complex: [Ge(OH)(2)(C(2)O(4))(2)](2-)

Shi, FN; Cunha-Silva, L; Paz, FAA; Hardie, MJ; Klinowski, J; Rocha, J; Trindade, T
2008, INORGANIC CHEMISTRY COMMUNICATIONS, 11, 3, 283-287.

Photoluminescent layered Y/Er silicates

Kostova, MH; Ananias, D; Carlos, LD; Rocha, J
2008, JOURNAL OF ALLOYS AND COMPOUNDS, 451, 1-2, 624-626.

Spectroscopic studies of an europium(III) tris-beta-diketonate complex bearing a pyrazolylpyridine ligand

dos Santos, AM; Coelho, AC; Paz, FAA; Rocha, J; Goncalves, IS; Carlos, LD
2008, JOURNAL OF ALLOYS AND COMPOUNDS, 451, 1-2, 344-346.

Practical aspects of Lee-Goldburg based CRAMPS techniques for high-resolution (1)H NMR spectroscopy in solids: Implementation and applications

Coelho, C; Rocha, J; Madhu, PK; Mafra, L
2008, JOURNAL OF MAGNETIC RESONANCE, 194, 2, 264-282.

Synthesis, structure and magnetic behaviour of mixed metal leucophosphite

Shi, FN; dos Santos, AM; Cunha-Silva, L; Costa, BFO; Klinowski, J; Paz, FAA; Amaral, VS; Rocha, J; Trindade, T
2008, JOURNAL OF SOLID STATE CHEMISTRY, 181, 6, 1330-1336.

Improved Ti-silicate umbite membranes for the separation of H-2

Sebastian, V; Lin, Z; Rocha, J; Tellez, C; Santamaria, J; Coronas, J
2008, JOURNAL OF MEMBRANE SCIENCE, 323, 1, 207-212.

Microwave-hydrothermally aged Zn,Al hydrotalcite-like compounds: Influence of the composition and the irradiation conditions

Benito, P; Guinea, I; Labajos, FM; Rocha, J; Rives, V
2008, MICROPOROUS AND MESOPOROUS MATERIALS, 110, 2-3, 292-302.

Synthesis and catalytic properties of manganese(II) and oxovanadium(IV) complexes anchored to mesoporous MCM-41

Fernandes, TA; Nunes, CD; Vaz, PD; Calhorda, MJ; Brandao, P; Rocha, J; Goncalves, IS; Valente, AA; Ferreira, LP; Godinho, M; Ferreira, P
2008, MICROPOROUS AND MESOPOROUS MATERIALS, 112, 1-3, 14-25.

Mercury removal with titanosilicate ETS-4: Batch experiments and modelling

Lopes, CB; Lito, PF; Otero, M; Lin, Z; Rocha, J; Silva, CM; Pereira, E; Duarte, AC
2008, MICROPOROUS AND MESOPOROUS MATERIALS, 115, 1-2, 98-105.

Structure and catalytic activity of Al-MCM-48 materials synthesised at room temperature: Influence of the aluminium source and calcination conditions

Russo, PA; Carrott, MMLR; Carrott, PJM; Lopes, JM; Ribeiro, FR; Rocha, J
2008, MICROPOROUS AND MESOPOROUS MATERIALS, 114, 1-3, 293-302.

Two novel supramolecular organic-inorganic adducts containing dibenzo-30-crown-10 and H3PM12O40 (M = W or Mo)

Soares-Santos, PCR; Cunha-Silva, L; Sousa, FL; Mafra, L; Rocha, J; Cavaleiro, AMV; Trindade, T; Paz, FAA; Klinowski, J; Nogueira, HIS
2008, JOURNAL OF MOLECULAR STRUCTURE, 888, 1-3, 99-106.

Photoluminescence and quantum yields of organic/inorganic hybrids prepared through formic solvolysis

Fu, LS; Ferreira, RAS; Fernandes, M; Nunes, SC; Bermudez, VD; Hungerford, G; Rocha, J; Carlos, LD
2008, OPTICAL MATERIALS, 30, 7, 1058-1064.

Photoluminescent porous alginate hybrid materials containing lanthanide ions

Liu, FY; Carlos, LD; Ferreira, RAS; Rocha, J; Gaudino, MC; Robitzer, M; Quignard, F
2008, BIOMACROMOLECULES, 9, 7, 1945-1950.

Photoluminescent 3D lanthanide-organic frameworks with 2,5-pyridinedicarboxylic and 1,4-phenylenediacetic acids

Soares-Santos, PCR; Cunha-Silva, L; Paz, FAA; Ferreira, RAS; Rocha, J; Trindade, T; Carlos, LD; Nogueira, HIS
2008, CRYSTAL GROWTH & DESIGN, 8, 7, 2505-2516.

Hydro-Ionothermal Synthesis of Lanthanide-Organic Frameworks with 1,4-Phenylenebis(methylene)diphosphonate

Shi, FN; Trindade, T; Rocha, J; Paz, FAA
2008, CRYSTAL GROWTH & DESIGN, 8, 11, 3917-3920.

Photoluminescent layered lanthanide silicate nanoparticles

Ananias, D; Ferdov, S; Paz, FAA; Ferreira, RAS; Ferreira, A; Geraldes, CFGC; Carlos, LD; Lin, Z; Rocha, J
2008, CHEMISTRY OF MATERIALS, 20, 1, 205-212.

Characterization of layered gamma-titanium phosphate (C(2)H(5)NH(3))[Ti(H(1.5)PO(4))(PO(4))](2)center dot H(2)O intercalate: A combined NMR, synchrotron XRD, and DFT calculations study

Mafra, L; Rocha, J; Fernandez, C; Castro, GR; Garcia-Granda, S; Espina, A; Khainakov, SA; Garcia, JR
2008, CHEMISTRY OF MATERIALS, 20, 12, 3944-3953.

Interconvertable modular framework and layered lanthanide(III)-etidronic acid coordination polymers

Shi, FN; Cunha-Silva, L; Ferreira, RAS; Mafra, L; Trindade, T; Carlos, LD; Paz, FAA; Rocha, J
2008, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 130, 1, 150-167.

Energy transfer and emission decay kinetics in mixed microporous lanthanide silicates with unusual dimensionality

Evans, RC; Ananias, D; Douglas, A; Douglas, P; Carlos, LD; Rocha, J
2008, JOURNAL OF PHYSICAL CHEMISTRY C, 112, 1, 260-268.

Porous materials prepared from clays for the upgrade of landfill gas

Pinto, ML; Pires, J; Rocha, J
2008, JOURNAL OF PHYSICAL CHEMISTRY C, 112, 37, 14394-14402.

Tuning the emission colour in mixed lanthanide microporous silicates: energy transfer, composition and chromaticity

Evans, RC; Carlos, LD; Douglas, P; Rocha, J
2008, JOURNAL OF MATERIALS CHEMISTRY, 18, 10, 1100-1107.

NMR Transversal relaxivity of aqueous suspensions of particles of Ln(3+)-based zeolite type materials

Pereira, GA; Norek, M; Peters, JA; Ananias, D; Rocha, J; Geraldes, CFGC
2008, DALTON TRANSACTIONS, 17, 2241-2247.

Using pyridine amidoximes in 3d-metal cluster chemistry: a novel ferromagnetic Ni(12) complex from the use of pyridine-2-amidoxime

Papatriantafyllopoulou, C; Jones, LF; Nguyen, TD; Matamoros-Salvador, N; Cunha-Silva, L; Paz, FAA; Rocha, J; Evangelisti, M; Brechin, EK; Perlepes, SP
2008, DALTON TRANSACTIONS, 24, 3153-3155.

Photoluminescence of Eu(III)-doped lamellar bridged silsesquioxanes self-templated through a hydrogen bonding array

Nobre, SS; Brites, CDS; Ferreira, RAS; Bermudez, VD; Carcel, C; Moreau, JJE; Rocha, J; Man, MWC; Carlos, LD
2008, JOURNAL OF MATERIALS CHEMISTRY, 18, 35, 4172-4182.

Functionalization of atomic force microscope tips by dielectrophoretic assembly of Gd2O3 : Eu3+ nanorods

Macedo, AG; Ananias, D; Andre, PS; Ferreira, RAS; Kholkin, AL; Carlos, LD; Rocha, J
2008, NANOTECHNOLOGY, 19, 29.

Decaaquadioxidobis[mu(3)-N-(phosphonatomethyl) iminodiacetato]dizinc(II)divanadium(IV)dihydrate

Cunha-Silva, L; Shi, FN; Klinowski, J; Trindade, T; Rocha, J; Paz, FAA
2008, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 64, M39-U422.

Bis(tetramethylamonium) bis(2,4,5-carboxybenzoate)-benzene-1,2,4,5-tetracarboxylic acid (1/1)

Cunha-Silva, L; Girginova, PI; Trindade, T; Rocha, J; Klinowski, J; Paz, FAA
2008, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 64, O69-U3138.

The dehydrated copper silicate Na-2[Cu2Si4O11]: a three-dimensional microporous framework with a linear Si-O-Si linkage

Cunha-Silva, L; Brandao, P; Rocha, J; Paz, FAA
2008, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 64, I13-U47.

Poly[[aqua-mu(3)-picolinato-mu(2)-picolinato-dipicolinatopotassium(I)terbium(III)] 2.5-hydrate]

Cunha-Silva, L; Soares-Santos, PCR; Nogueira, HIS; Trindade, T; Klinowski, J; Rocha, J; Paz, FAA
2008, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 64, M529-U188.

Al-27 and Si-29 NMR and XRD characterisation of clinkers: standard phases and new waste based formulations

Raupp-Pereira, F; Segadaes, AM; Silva, AS; Rocha, J; Labrincha, JA
2008, ADVANCES IN APPLIED CERAMICS, 107, 1, 37-45.

Immobilisation of Ferricinium Cation into ETS-10 by Ion Exchange under Microwave Irradiation

Coelho, AC; Brandao, P; dos Santos, AM; Rocha, J; Goncalves, IS
2008, ADVANCED MATERIALS FORUM IV, 587-588, 453-457.

Engineering optical centres in microporous silicates and MOFs

Rocha, J
2008, ZEOLITES AND RELATED MATERIALS: TRENDS, TARGETS AND CHALLENGES, PROCEEDINGS OF THE 4TH INTERNATIONAL FEZA CONFERENCE, 174, 79-84.
ISBN: 978-0-444-53297-8

Catalytic Performance of Copper-Substituted Polyoxotungstate Materials and X-ray Structure of a New Sandwich-Type Compound

Balula, SS; Cunha-Silva, L; Santos, ICMS; Paz, FAA; Rocha, J; Nogueira, HIS; Cavaleiro, AMV
2008, ADVANCED MATERIALS FORUM IV, 587-588, 538-+.

Uptake of Hg2+ from aqueous solutions by microporous titano- and zircono-silicates

Lopes, CB; Coimbra, J; Otero, M; Pereira, E; Duarte, AC; Lin, Z; Rocha, J
2008, QUIMICA NOVA, 31, 2, 321-325.

Nanoscopic photoluminescence memory as a fingerprint of complexity in self-assembled alkyl/siloxane hybrids

Carlos, LD; Bermudez, VD; Amaral, VS; Nunes, SC; Silva, NJO; Ferreira, RAS; Rocha, J; Santilli, CV; Ostrovskii, D
2007, ADVANCED MATERIALS, 19, 3, 341-+.

Structural and catalytic studies of a trimethyltin vanadate coordination polymer

Abrantes, M; Balula, MS; Valente, AA; Paz, FAA; Pillinger, M; Romao, CC; Rocha, J; Goncalves, IS
2007, JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 17, 1, 215-222.

Fluorine-substituted hydroxyapatite scaffolds hydrothermally grown from aragonitic cuttlefish bones

Kannan, S; Rocha, JHG; Agathopoulos, S; Ferreira, JMF
2007, ACTA BIOMATERIALIA, 3, 2, 243-249.

Morphology and miscibility of chitosan/soy protein blended membranes

Silva, SS; Goodfellow, BJ; Benesch, J; Rocha, J; Mano, JF; Reis, RL
2007, CARBOHYDRATE POLYMERS, 70, 1, 25-31.

In situ synthesis of lanthanide complex in urea cross-linked organic/inorganic di-ureasil hybrids via carboxylic acid solvolysis

Fu, LS; Ferreira, RAS; Nobre, SS; Carlos, LD; Rocha, J
2007, JOURNAL OF LUMINESCENCE, 122, 265-267.

A zirconosilicate system suitable for lanthanide framework incorporation

Lin, Z; Domingues, JP; Rocha, J; Carlos, LD
2007, JOURNAL OF LUMINESCENCE, 122, 902-904.

Photoinactivation of bacteria in wastewater by porphyrins: Bacterial beta-galactosidase activity and leucine-uptake as methods to monitor the process

Carvalho, CMB; Gomes, ATPC; Fernandes, SCD; Prata, ACB; Almeida, MA; Cunha, MA; Tome, JPC; Faustino, MAF; Neves, MGPMS; Tome, AC; Cavaleiro, JAS; Lin, Z; Rainho, JP; Rocha, J
2007, JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY, 88, 2-3, 112-118.

Synthesis, crystal structure and magnetic characterization of Na2CU5(Si2O7)2: An inorganic ferrimagnetic chain

dos Santos, AM; Brandao, P; Fitch, A; Reis, MS; Amaral, VS; Rocha, J
2007, JOURNAL OF SOLID STATE CHEMISTRY, 180, 1, 16-21.

Removal of low concentration Hg2+ from natural waters by microporous and layered titanosilicates

Lopes, CB; Otero, M; Coimbra, J; Pereira, E; Rocha, J; Lin, Z; Duarte, A
2007, MICROPOROUS AND MESOPOROUS MATERIALS, 103, 1-3, 325-332.

Crystal structure, local sodium environments and ion dynamics in Na0.8Ni0.6Sb0.4O2, a new mixed antimonate

Smirnova, OA; Rocha, J; Nalbandyan, VB; Kharton, VV; Marques, FMB
2007, SOLID STATE IONICS, 178, 23-24, 1360-1365.

Photoluminescent lanthanide-organic 2D networks: A combined synchrotron powder X-ray diffraction and solid-state NMR study

Cunha-Silva, L; Mafra, L; Ananias, D; Carlos, LD; Rocha, J; Paz, FAA
2007, CHEMISTRY OF MATERIALS, 19, 14, 3527-3538.

Heterodimetallic germanium(IV) complex structures with transition metals

Shi, FN; Cunha-Silva, L; Hardie, MJ; Trindade, T; Paz, FAA; Rocha, J
2007, INORGANIC CHEMISTRY, 46, 16, 6502-6515.

Photoluminescent rare-earth based biphenolate lamellar nanostructures

Karmaoui, M; Mafra, L; Ferreira, RAS; Rocha, J; Carlos, LD; Pinna, N
2007, JOURNAL OF PHYSICAL CHEMISTRY C, 111, 6, 2539-2544.

Evolution of photoluminescence across dimensionality in lanthanide silicates

Kostova, MH; Ananias, D; Paz, FAA; Ferreira, A; Rocha, J; Carlos, LD
2007, JOURNAL OF PHYSICAL CHEMISTRY B, 111, 14, 3576-3582.

Selective adsorption of volatile organic compounds in micropore aluminum methylphosphonate-alpha: A combined molecular simulation-experimental approach

Herdes, C; Valente, A; Lin, Z; Rocha, J; Coutinho, JAP; Medina, F; Vega, LF
2007, LANGMUIR, 23, 13, 7299-7305.

Crystal structure and photoluminescence properties of lanthanide diphosphonates

Liu, FY; Roces, L; Ferreira, RAS; Garcia-Granda, S; Garcia, JR; Carlos, LD; Rocha, J
2007, JOURNAL OF MATERIALS CHEMISTRY, 17, 35, 3696-3701.

Sol-gel-derived potassium-based di-ureasils for "smart windows''

Nunes, SC; Bermudez, VD; Silva, MM; Smith, MJ; Ostrovskii, D; Ferreira, RAS; Carlos, LD; Rocha, J; Goncalves, A; Fortunato, E
2007, JOURNAL OF MATERIALS CHEMISTRY, 17, 40, 4239-4248.

Specific heat of clustered low dimensional magnetic systems

Sreis, MS; dos Santos, AM; Amaral, VS; Souza, AM; Brandao, P; Rocha, J; Tristan, N; Klingeler, R; Buchner, B; Volkova, O; Vasiliev, AN
2007, JOURNAL OF PHYSICS-CONDENSED MATTER, 19, 44.

Decaaquadioxobis[mu(3)-N-(phosphonomethyl)iminodiacetato] dimanganesedivanadium dihydrate

Cunha-Silva, L; Shi, FN; Klinowski, J; Trindade, T; Rocha, J; Paz, FAA
2007, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 63, M372-M375.

Redetermination of dipotassium mu-oxo-bis[aqua(oxalato-kappa O-2,O ') dioxomolybdate(VI)] at 150 K

Cunha-Silva, L; Monteiro, B; Pillinger, M; Goncalves, IS; Rocha, J; Paz, FAA
2007, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 63, M376-M378.

Crystallization of microporous titanosilicate membranes from clear solutions

Lin, Z; Rocha, J
2007, FROM ZEOLITES TO POROUS MOF MATERIALS: THE 40TH ANNIVERSARY OF INTERNATIONAL ZEOLITE CONFERENCE, PROCEEDINGS OF THE 15TH INTERNATIONAL ZEOLITE CONFERENCE, 170, 493-498.
ISBN: 978-0-444-53068-4

Optical detection of solid-state chiral structures with unpolarized light and in the absence of external fields

Ananias, D; Paz, FAA; Carlos, LD; Geraldes, CFGC; Rocha, J
2006, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 45, 47, 7938-7942.

X-ray diffraction and solid-state NMR studies of a germanium binuclear complex

Mafra, L; Paz, FAA; Shi, FN; Rocha, J; Trindade, T; Fernandez, C; Makal, A; Wozniak, K; Klinowski, J
2006, CHEMISTRY-A EUROPEAN JOURNAL, 12, 2, 363-375.

Crystal structure, solid-state NMR spectroscopic and photoluminescence studies of organic-inorganic hybrid materials (HL)(6)[Ge-6(OH)(6)(hedp)(6)]center dot 2(L)center dot nH(2)O, L = hqn or phen

Mafra, L; Paz, FAA; Shi, FN; Ferreira, RAS; Carlos, LD; Trindade, T; Fernandez, C; Klinowski, J; Rocha, J
2006, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 23, 4741-4751.

Hydrothermal growth of hydroxyapatite scaffolds from aragonitic cuttlefish bones

Rocha, JHG; Lemos, AF; Agathopoulos, S; Kannan, S; Valerio, P; Ferreira, JMF
2006, JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 77A, 1, 160-168.

Sol-gel derived Li+-doped poly(epsilon-caprolactone)/siloxane biohybrid electrolytes

Nunes, SC; Bermudez, VD; Silva, MM; Smith, MJ; Morales, E; Carlos, LD; Ferreira, RAS; Rocha, J
2006, JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 10, 4, 203-210.

Liquid-phase dehydration of D-xylose over microporous and mesoporous niobium silicates

Dias, AS; Lima, S; Brandao, P; Pillinger, M; Rocha, J; Valente, AA
2006, CATALYSIS LETTERS, 108, 3-4, 179-186.

Methane oxidation over nanocrystalline Ce0.45Zr0.45La0.10O2-delta/Pt and Ce0.9Sm0.1O2-delta/Pt anodes

Yaremchenko, AA; Kharton, VV; Valente, AA; Frolova, EV; Ivanovskaya, MI; Kovalevsky, AV; Marques, FMB; Rocha, J
2006, CATALYSIS LETTERS, 112, 1-2, 19-26.

Characterization of Y zeolites dealuminated by solid-state reaction with ammonium hexafluorosilicate

Pires, J; Carvalho, A; Pinto, M; Rocha, J
2006, JOURNAL OF POROUS MATERIALS, 13, 2, 107-114.

Dioxomolybdenum(VI) modified mesoporous materials for the catalytic epoxidation of olefins

Bruno, SM; Fernandes, JA; Martins, LS; Goncalves, IS; Pillinger, M; Ribeiro-Claro, P; Rocha, J; Valente, AA
2006, CATALYSIS TODAY, 114, 2-3, 263-271.

Hydrothermal synthesis, structural characterisation and magnetic behaviour of (4,4 '-bpyH)(2)[M(4,4 '-bpy)(H2O)(4)]-[V2O2(pmida)(2)]center dot 2H(2)O (M=Mn2+ and CO2+)

Shi, FN; Paz, FAA; Girginova, PI; Amaral, VS; Rocha, J; Klinowski, J; Trindade, T
2006, INORGANICA CHIMICA ACTA, 359, 4, 1147-1158.

A pentanuclear oxovanadium(V) phosphate complex with phenanthroline

Mafra, L; Paz, FAA; Shi, FN; Fernandez, C; Trindade, T; Klinowski, J; Rocha, J
2006, INORGANIC CHEMISTRY COMMUNICATIONS, 9, 1, 34-38.

Hydroxyapatite nano-powders produced hydrothermally from nacreous material

Lemos, AF; Rocha, JHG; Quaresma, SSF; Kannan, S; Oktar, FN; Agathopoulos, S; Ferreira, JMF
2006, JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 26, 16, 3639-3646.

Characterization of microporous aluminophosphate IST-1 using H-1 Lee-Goldburg techniques

Mafra, L; Rocha, J; Fernandez, C; Paz, FAA
2006, JOURNAL OF MAGNETIC RESONANCE, 180, 2, 236-244.

A novel cobalt(II)-molybdenum(V) phosphate organic-inorganic hybrid polymer

Shi, FN; Paz, FAA; Girginova, PI; Nogueira, HIS; Rocha, J; Amaral, VS; Klinowski, J; Trindade, T
2006, JOURNAL OF SOLID STATE CHEMISTRY, 179, 5, 1497-1505.

Synthesis of hydroxy-chlorapatites solid solutions

Kannan, S; Rocha, JHG; Ferreira, JMF
2006, MATERIALS LETTERS, 60, 7, 864-868.

Synthesis and characterization of MCM-48 tubular membranes

de la Iglesia, O; Pedernera, M; Mallada, R; Lin, Z; Rocha, J; Coronas, J; Santamaria, J
2006, JOURNAL OF MEMBRANE SCIENCE, 280, 1-2, 867-875.

Two new aluminophosphates, IST-1 and IST-2: First examples of a dual templating role of water and methylamine in generating microporous structures

Fernandes, A; Ribeiro, MF; Borges, C; Lourenco, JP; Rocha, J; Gabelica, Z
2006, MICROPOROUS AND MESOPOROUS MATERIALS, 90, 1-3, 112-128.

Comparative study of Al-MCM materials prepared at room temperature with different aluminium sources and by some hydrothermal methods

Carrott, MMLR; Conceicao, FL; Lopes, JM; Carrott, PJM; Bernardes, C; Rocha, J; Ribeiro, FR
2006, MICROPOROUS AND MESOPOROUS MATERIALS, 92, 1-3, 270-285.

Influence of microwave radiation on the textural properties of layered double hydroxides

Benito, P; LabajoS, FM; Rocha, J; Rives, V
2006, MICROPOROUS AND MESOPOROUS MATERIALS, 94, 1-3, 148-158.

Optically functional nanocomposites with poly(oxyethylene)-based di-ureasils and mesoporous MCM-41

Fu, LS; Ferreira, RAS; Valente, A; Rocha, J; Carlos, LD
2006, MICROPOROUS AND MESOPOROUS MATERIALS, 94, 1-3, 185-192.

Synthesis and characterisation of a stannosilicate with the structure of penkvilksite-1M

Lin, Z; Rocha, J
2006, MICROPOROUS AND MESOPOROUS MATERIALS, 94, 1-3, 173-178.

One-dimensional coordination polymer of N-(phosphonomethyl) iminodiacetic acid with iron(II)

Shi, FN; Paz, FAA; Girginova, P; Rocha, J; Amaral, VS; Klinowski, J; Trindade, T
2006, JOURNAL OF MOLECULAR STRUCTURE, 789, 1-3, 200-208.

Unusual full-colour phosphors: Na(3)LnSi(3)O(9)

Ananias, D; Carlos, LD; Rocha, J
2006, OPTICAL MATERIALS, 28, 6-7, 582-586.

Study of sol-gel derived di-ureasils doped with zinc triflate

Nunes, SC; Bermudez, VD; Silva, MM; Smith, MJ; Morales, E; Ferreira, RAS; Carlos, LD; Rocha, J
2006, SOLID STATE SCIENCES, 8, 12, 1484-1491.

Mixed conductivity and electrocatalytic performance of SrFeO3-delta-SrAl2O4 composite membranes

Yaremchenko, AA; Kharton, VV; Valente, AA; Shaula, AL; Marques, FMB; Rocha, J
2006, SOLID STATE IONICS, 177, 26-32, 2285-2289.

Methane oxidation over SOFC anodes with nanocrystalline ceria-based phases

Kharton, VV; Yaremchenko, AA; Valente, AA; Frolova, EV; Ivanovskaya, MI; Frade, JR; Marques, FMB; Rocha, J
2006, SOLID STATE IONICS, 177, 19-25, 2179-2183.

Synthesis and characterisation of hybrid mesoporous materials with the 1,4-diazobutadiene ligand

Nunes, CD; Vaz, PD; Brandao, P; Rocha, J; Ferreira, P; Bion, N; Calhorda, MJ
2006, MICROPOROUS AND MESOPOROUS MATERIALS, 95, 1-3, 104-111.

Synthesis, characterization, and separation properties of Sn- and Ti-silicate umbite membranes

Sebastian, V; Lin, Z; Rocha, J; Tellez, C; Santamaria, J; Coronas, J
2006, CHEMISTRY OF MATERIALS, 18, 10, 2472-2479.

Photoluminescent layered Y(III) and Tb(III) silicates doped with Ce(III)

Kostova, MH; Ferreira, RAS; Ananias, D; Carlos, LD; Rocha, J
2006, JOURNAL OF PHYSICAL CHEMISTRY B, 110, 31, 15312-15316.

Synthesis and thermal stability of sodium, magnesium co-substituted hydroxyapatites

Kannan, S; Rocha, JHG; Ferreira, JMF
2006, JOURNAL OF MATERIALS CHEMISTRY, 16, 3, 286-291.

Photoluminescence of lanthanide NASICONs: Na(5)LnSi(4)O(12), Ln = Eu, Tb

dos Santos, AM; Marques, FMB; Carlos, LD; Rocha, J
2006, JOURNAL OF MATERIALS CHEMISTRY, 16, 30, 3139-3144.

Homometallic ferrimagnetism in the zig-zag chain compound Na2Cu5Si4O14

Reis, MS; dos Santos, AM; Amaral, VS; Brandao, P; Rocha, J
2006, PHYSICAL REVIEW B, 73, 21.

[N-(2-ammonioethyl)ethylenediamine-kappa N-2,N '][hydrogen N-(phosphonatomethyl)-iminodiacetato]copper(II) sesquihydrate

Shi, FN; Paz, FAA; Trindade, T; Rocha, J
2006, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 62, M335-M338.

Characterization and mechanical performance of the Mg-stabilized beta-Ca-3(PO4)(2) prepared from mg-substituted Ca-deficient apatite

Kannan, S; Lemos, AF; Rocha, JHG; Ferreira, JMF
2006, JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 89, 9, 2757-2761.

Organically modified silica-based xerogels derived from 3-aminopropyltrimethoxysilane and 3-isocyanatepropyltriethoxysilane through carboxylic acid solvolysis

Fu, LS; Ferreira, RAS; Nobre, SS; Carlos, LD; Rocha, J
2006, ADVANCED MATERIALS FORUM III, PTS 1 AND 2, 514-516, 108-112.

Preparation of photoluminescent materials from a lanthanide-doped microporous titanosilicate precursor

Lin, Z; Rainho, JP; Rocha, J; Carlos, LD
2006, ADVANCED MATERIALS FORUM III, PTS 1 AND 2, 514-516, 123-127.

Hydrophobic porous benzene-silica hybrid clay heterostructure and its application in the adsorption of volatile organic compounds

Ferreira, P; Nunes, CD; Pires, J; Carvalho, AP; Brandao, P; Rocha, J
2006, ADVANCED MATERIALS FORUM III, PTS 1 AND 2, 514-516, 470-474.

Luminescent polyoxotungstoeuropate anion-pillared layered double hydroxides

Sousa, FL; Pillinger, M; Ferreira, RAS; Granadeiro, CM; Cavaleiro, AMV; Rocha, J; Carlos, LD; Trindade, T; Nogueira, HIS
2006, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 4, 726-734.

Transport and electrocatalytic properties of La0.3Sr0.7Co0.8Ga0.2O3-delta membranes

Kharton, VV; Tsipis, EV; Marozau, IP; Yaremchenko, AA; Valente, AA; Viskup, AP; Frade, JR; Naumovich, EN; Rocha, J
2005, JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 9, 1, 10-20.

Mossbauer spectra and catalytic behavior of perovskite-like SrFe0.7Al0.3O3-delta

Kharton, VV; Waerenborgh, JC; Rojas, DP; Yaremchenko, AA; Valente, AA; Shaula, AL; Patrakeev, MV; Marques, FMB; Rocha, J
2005, CATALYSIS LETTERS, 99, 3-4, 249-255.

Scaffolds for bone restoration from cuttlefish

Rocha, JHG; Lemos, AF; Agathopoulos, S; Valerio, P; Kannan, S; Oktar, FN; Ferreira, JMF
2005, BONE, 37, 6, 850-857.

Synthesis and characterisation of a new vanadyl oxalatophosphate compound: (C10H10N2)[(VO)(HPO4)](2)(C2O4)

Shi, FN; Paz, FAA; Rocha, J; Klinowski, J; Trindade, T
2005, INORGANICA CHIMICA ACTA, 358, 4, 927-932.

The first one-dimensional lanthanopolyoxotungstoborate

Sousa, FL; Paz, FAA; Granadeiro, CMCE; Cavaleiro, AMV; Rocha, J; Klinowski, J; Nogueira, HIS
2005, INORGANIC CHEMISTRY COMMUNICATIONS, 8, 10, 924-927.

Morphological micro-patterning of tubular-windows on crystalline K2V3O8 sheets

Shi, FN; Rocha, J; Lopes, AB; Trindade, T
2005, JOURNAL OF CRYSTAL GROWTH, 273, 3-4, 572-576.

Synthetic NaMnPO4 microtubules

Shi, FN; Rocha, J; Trindade, T
2005, MATERIALS LETTERS, 59, 6, 652-655.

Processing, stability and oxygen permeability of Sr(Fe, Al)O-3-based ceramic membranes

Kharton, VV; Shaula, AL; Snijkers, FMM; Cooymans, JFC; Luyten, JJ; Yaremchenko, AA; Valente, AA; Tsipis, EV; Frade, JR; Marques, FMB; Rocha, J
2005, JOURNAL OF MEMBRANE SCIENCE, 252, 1-2, 215-225.

Photoluminescent films of microporous titanosilicate ETS-10 doped with europium(III)

Lin, Z; Rainho, JP; Domingues, J; Carlos, LD; Rocha, J
2005, MICROPOROUS AND MESOPOROUS MATERIALS, 79, 1-3, 13-19.

Asymmetric cationic methyl pyridyl and pentafluorophenyl porphyrin encapsulated in zeolites: A cytochrome P-450 model

Skrobot, FC; Rosa, ILV; Marques, APA; Martins, PR; Rocha, J; Valente, AA; Iamamoto, Y
2005, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 237, 1-2, 86-92.

Hydrothermal synthesis, structural characterisation and magnetic behaviour of hybrid complexes of N-(phosphonomethyl)iminodiacetate

Shi, FN; Paz, FAA; Girginova, PI; Mafra, L; Amaral, VS; Rocha, J; Makal, A; Wozniak, K; Klinowski, J; Trindade, T
2005, JOURNAL OF MOLECULAR STRUCTURE, 754, 1-3, 51-60.

Hybrid mesoporous MCM-41 type material containing 1,4-diazobutadiene chelate ligand in the walls

Ferreira, P; Nunes, CD; Vaz, PD; Bion, N; Brandao, P; Rocha, J
2005, PROGRESS IN SOLID STATE CHEMISTRY, 33, 2-4, 163-170.

Optimised hydrothermal synthesis of multi-dimensional hybrid coordination polymers containing flexible organic ligands

Paz, FAA; Rocha, J; Klinowski, J; Trindade, T; Shi, FN; Mafra, L
2005, PROGRESS IN SOLID STATE CHEMISTRY, 33, 2-4, 113-125.

Effect of Ca/P ratio of precursors on the formation of different calcium apatitic ceramics - An X-ray diffraction study

Kannan, S; Rocha, JHG; Ventura, JMG; Lemos, AF; Ferreira, JMF
2005, SCRIPTA MATERIALIA, 53, 11, 1259-1262.

Methane oxidation over Fe-, Co-, Ni- and V-containing mixed conductors

Kharton, VV; Yaremchenko, AA; Valente, AA; Sobyanin, VA; Belyaev, VD; Semin, GL; Veniaminov, SA; Tsipis, EV; Shaula, AL; Frade, JR; Rocha, J
2005, SOLID STATE IONICS, 176, 7-8, 781-791.

Di-ureasil ormolytes doped with Mg2+ ions. Part 1: Morphological, thermal and electrochemical properties

Nunes, SC; Bermudez, VDZ; Silva, MM; Barros, S; Smith, MJ; Morales, E; Carlos, LD; Rocha, J
2005, SOLID STATE IONICS, 176, 17-18, 1591-1599.

Multiplex MQMAS NMR of quadrupolar nuclei

Malicki, N; Mafra, L; Quoineaud, AA; Rocha, J; Thibault-Starzyk, F; Fernandez, C
2005, SOLID STATE NUCLEAR MAGNETIC RESONANCE, 28, 1, 13-21.

Structural characterization of layered gamma-titanium phosphate (C6H13NH3)[Ti(HPO4)(PO4)]center dot H2O

Mafra, L; Paz, FAA; Rocha, J; Espina, A; Khainakov, SA; Garcia, JR; Fernandez, C
2005, CHEMISTRY OF MATERIALS, 17, 25, 6287-6294.

Matrix assisted formation of ferrihydrite nanoparticles in a siloxane/poly(oxyethylene) nanohybrid

Silva, NJO; Amaral, VS; Bermudez, VD; Nunes, SC; Ostrovskii, D; Rocha, J; Carlos, LD
2005, JOURNAL OF MATERIALS CHEMISTRY, 15, 4, 484-490.

A novel microporous copper silicate: Na2Cu2Si4O11 center dot 2H(2)O

Brandao, P; Paz, FAA; Rocha, J
2005, CHEMICAL COMMUNICATIONS, 2, 171-173.

A new titanosilicate umbite membrane for the separation of H-2

Sebastian, V; Lin, Z; Rocha, J; Tellez, C; Santamaria, JS; Coronas, J
2005, CHEMICAL COMMUNICATIONS, 24, 3036-3037.

NMR relaxivity of Ln(3+)-based zeolite-type materials

Pereira, GA; Ananias, D; Rocha, J; Amaral, VS; Muller, RN; Elst, LV; Toth, E; Peters, JA; Geraldes, CFGC
2005, JOURNAL OF MATERIALS CHEMISTRY, 15, 35-36, 3832-3837.

Structure and photoluminescent features of di-amide cross-linked alkylene siloxane hybrids

Nunes, SC; Bermudez, VDZ; Cybinska, J; Ferreira, RAS; Legendziewicz, J; Carlos, LD; Silva, MM; Smith, MJ; Ostrovskii, D; Rocha, J
2005, JOURNAL OF MATERIALS CHEMISTRY, 15, 35-36, 3876-3886.

Functional nanostructured chitosan-siloxane hybrids

Silva, SS; Ferreira, RAS; Fu, LS; Carlos, LD; Mano, JF; Reis, RL; Rocha, J
2005, JOURNAL OF MATERIALS CHEMISTRY, 15, 35-36, 3952-3961.

Hydroxyapatite scaffolds hydrothermally grown from aragonitic cuttlefish bones

Rocha, JHG; Lemos, AF; Kannan, S; Agathopoulos, S; Ferreira, JMF
2005, JOURNAL OF MATERIALS CHEMISTRY, 15, 47, 5007-5011.

Singlet ground state determined by isolated Cu2+ chain topology in microporous Na2Cu2Si4O11 center dot 2H(2)O and Na2Cu2Si4O11

dos Santos, AM; Amaral, VS; Brandao, P; Paz, FAA; Rocha, J; Ferreira, LP; Godinho, M; Volkova, O; Vasiliev, A
2005, PHYSICAL REVIEW B, 72, 9.

[Co(H2O)(6)]{[Co( C4H4N2)(H2O)(2)][V2O2(pmida)(2)]}center dot-2H(2)O [H(4)pmida is N-(phosphonomethyl)iminodiacetic acid]: the first two-dimensional hybrid framework containing [V2O2(pmida)2](4-) building blocks

Paz, FAA; Shi, FN; Mafra, LS; Makal, A; Wozniak, K; Trindade, T; Klinowski, J; Rocha, J
2005, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 61, M1628-M1632.

[Hydrogen N-(phosphonomethyl)iminodiacetato](1,10-phenanthroline)copper(II) trihydrate: a low-temperature redetermination

Paz, FAA; Shi, FN; Trindade, T; Klinowski, J; Rocha, J
2005, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 61, M2247-M2250.

Hydrothermal synthesis of the tin analogue of penkvilksite-2O

Lin, Z; Rocha, J
2005, EUROPEAN JOURNAL OF MINERALOGY, 17, 6, 869-873.

Diurea cross-linked poly(oxyethylene)/siloxane ormolytes for lithium batteries

Nunes, SC; Bermudez, VD; Ostrovskii, A; Silva, MM; Barros, S; Smith, MJ; Carlos, LD; Rocha, J; Morales, E
2005, JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 152, 2, A429-A438.

A method for simultaneously precipitating and dispersing nano-sized calcium phosphate suspensions

Lemos, AF; Rebelo, AHS; Rocha, JHG; Ferreira, JMF
2005, BIOCERAMICS, VOL 17, 284-286, 67-70.
ISBN: 0-87849-961-X

Method for tailoring and control the morphology, size and porosity of calcium phosphate granules

Lemos, AF; Rocha, JHG; Ventura, JM; Ferreira, JMF
2005, BIOCERAMICS, VOL 17, 284-286, 309-312.
ISBN: 0-87849-961-X

Preparation of titanosilicate ETS-10 and vanadosilicate AM-6 membranes

Tiscornia, I; Lin, Z; Rocha, J; Tellez, C; Coronas, J; Santamaria, J
2005, MOLECULAR SIEVES: FROM BASIC RESEARCH TO INDUSTRIAL APPLICATIONS, PTS A AND B, 158, 423-430.
ISBN: 0-444-52082-1

Si-29 MAS NMR and Raman spectroscopy studies of synthetic microporous (Zr,Hf)-umbite

Lin, Z; Rocha, J
2005, MOLECULAR SIEVES: FROM BASIC RESEARCH TO INDUSTRIAL APPLICATIONS, PTS A AND B, 158, 861-868.
ISBN: 0-444-52082-1

Progress in multiple-quantum magic-angle spinning NMR spectroscopy

Rocha, J; Morais, CM; Fernandez, C
2005, NEW TECHNIQUES IN SOLID-STATE NMR, 246, 141-194.
ISBN: 3-540-22168-9

Microporous mixed octahedral-pentahedral-tetrahedral framework silicates

Rocha, J; Lin, Z
2005, MICRO- AND MESOPOROUS MINERAL PHASES, 57, 173-201.

Synthesis and properties of Zn-Al layered double hydroxides containing ferrocenecarboxylate anions

Gago, S; Pillinger, M; Santos, TM; Rocha, J; Goncalves, IS
2004, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 7, 1389-1395.

Synthesis and characterisation of the first three-dimensional mixed-metal-center inorganic-organic hybrid framework with N-(phosphonomethyl)iminodiacetate

Paz, FAA; Shi, FN; Klinowski, J; Rocha, J; Trindade, T
2004, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 13, 2759-2768.

Novel phosphovanadate layered structure assembled from a tetrametallic cubane-like V-v cluster

Shi, FN; Paz, FAA; Rocha, J; Klinowski, J; Trindade, T
2004, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 15, 3031-3037.

Incorporation of a (cyclopentadienyl)molybdenum oxo complex in MCM-41 and its use as a catalyst for olefin epoxidation

Abrantes, M; Gago, S; Valente, AA; Pillinger, M; Goncalves, IS; Santos, TM; Rocha, J; Romao, CC
2004, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 24, 4914-4920.

Mg,Al layered double hydroxides with intercalated indomethacin: Synthesis, characterization, and pharmacological study

Del Arco, M; Cebadera, E; Gutierrez, S; Martin, C; Montero, MJ; Rives, V; Rocha, J; Sevilla, MA
2004, JOURNAL OF PHARMACEUTICAL SCIENCES, 93, 6, 1649-1658.

Characterization of mixed-conducting La2Ni0.9Co0.1O4+delta membranes for dry methane oxidation

Kharton, VV; Yaremchenko, AA; Tsipis, EV; Valente, AA; Patrakeev, MV; Shaula, AL; Frade, JR; Rocha, J
2004, APPLIED CATALYSIS A-GENERAL, 261, 1, 25-35.

Eu3+ doped polyphosphate-aminosilane organic-inorganic hybrids

Dias, FA; Ribeiro, SJL; Goncalves, RR; Messaddeq, Y; Carlos, LD; Bermudez, VD; Rocha, J
2004, JOURNAL OF ALLOYS AND COMPOUNDS, 374, 1-2, 74-78.

Photoluminescence and local structure of Eu(III)-doped zirconium silicates

Rainho, JP; Ananias, D; Lin, Z; Ferreira, A; Carlos, LD; Rocha, J
2004, JOURNAL OF ALLOYS AND COMPOUNDS, 374, 1-2, 185-189.

The first examples of X-ray phosphors, and C-band infrared emitters based on microporous lanthanide silicates

Ananias, D; Rainho, JP; Ferreira, A; Rocha, J; Carlos, LD
2004, JOURNAL OF ALLOYS AND COMPOUNDS, 374, 1-2, 219-222.

Non-stoichlometric mixed lead and tin niobates

Cruz, LP; Savariault, JM; Morais, CM; Fernandez, C; de Jesus, JDP; Rocha, J
2004, JOURNAL OF SOLID STATE CHEMISTRY, 177, 4-5, 1549-1558.

Synthesis and characterization of layered double hydroxides (LDH) intercalated with non-steroidal anti-inflammatory drugs (NSAID)

del Arco, M; Gutierrez, S; Martin, C; Rives, V; Rocha, J
2004, JOURNAL OF SOLID STATE CHEMISTRY, 177, 11, 3954-3962.

Synthesis and characterization of tungsten trioxide powders prepared from tungstic acids

Nogueira, HIS; Cavaleiro, AMV; Rocha, J; Trindade, T; de Jesus, JDP
2004, MATERIALS RESEARCH BULLETIN, 39, 4-5, 683-693.

Synthesis and characterisation of titanosilicate ETS-10 membranes

Lin, Z; Rocha, J; Navajas, A; Tellez, C; Coronas, J; Santamaria, J
2004, MICROPOROUS AND MESOPOROUS MATERIALS, 67, 1, 79-86.

First stoichiometric large-pore chromium(III) silicate catalyst

Brandao, P; Valente, A; Ferreira, A; Amaral, VS; Rocha, J
2004, MICROPOROUS AND MESOPOROUS MATERIALS, 69, 3, 209-215.

Small-pore framework zirconium and hafnium silicates with the structure of mineral tumchaite

Lin, Z; Rocha, J
2004, MICROPOROUS AND MESOPOROUS MATERIALS, 76, 1-3, 99-104.

Optically functional Di-urethanesil nanohybrids containing Eu3+ ions

Goncalves, MC; Bermudez, VD; Ferreira, RAS; Carlos, LD; Ostrovskii, D; Rocha, J
2004, CHEMISTRY OF MATERIALS, 16, 13, 2530-2543.

Photoluminescence and quantum yields of urea and urethane cross-linked nanohybrids derived from carboxylic acid solvolysis

Fu, LS; Ferreira, RAS; Silva, NJO; Carlos, LD; Bermudez, VD; Rocha, J
2004, CHEMISTRY OF MATERIALS, 16, 8, 1507-1516.

Immobilization of oxomolybdenum species in a layered double hydroxide pillared by 2,2 '-bipyridine-5,5 '-dicarboxylate anions

Gago, S; Pillinger, M; Valente, AA; Santos, TM; Rocha, J; Goncalves, IS
2004, INORGANIC CHEMISTRY, 43, 17, 5422-5431.

Photoluminescent layered lanthanide silicates

Ananias, D; Kostova, M; Paz, FAA; Ferreira, A; Carlos, LD; Klinowski, J; Rocha, J
2004, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 126, 33, 10410-10417.

Lanthanopolyoxotungstoborates: Synthesis, characterization, and layer-by-layer assembly of europium photoluminescent nanostructured films

Sousa, FL; Ferreira, ACAS; Ferreira, RAS; Cavaleiro, AMV; Carlos, LD; Nogueira, HIS; Rocha, J; Trindade, T
2004, JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 4, 1-2, 214-220.

Novel microporous and layered luminescent lanthanide silicates

Rocha, J; Carlos, LD; Ferreira, A; Rainho, J; Ananias, D; Lin, Z
2004, ADVANCED MATERIALS FORUM II, 455-456, 527-531.
ISBN: 0-87849-941-5

Novel microporous luminescenteuropium(III) silicate

Rocha, J; Carlos, LD; Paz, FAA; Ananias, D; Klinowski, J
2004, RECENT ADVANCES IN THE SCIENCE AND TECHNOLOGY OF ZEOLITES AND RELATED MATERIALS, PTS A - C, 154, 3028-3035.
ISBN: 0-444-51805-3

Hydrothermal synthesis and characterisation of two novel large-pore framework vanadium silicates

Brandao, P; Valente, A; Philippou, A; Ferreira, A; Anderson, MW; Rocha, J
2003, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 6, 1175-1180.

Multifunctional sodium lanthanide silicates: From blue emitters and infrared S-band amplifiers to X-ray phosphors

Ananias, D; Ferreira, A; Carlos, LD; Rocha, J
2003, ADVANCED MATERIALS, 15, 12, 980-+.

Preparation and characterization of organotin - Oxomolybdate coordination polymers and their use in sulfoxidation catalysis

Abrantes, M; Valente, AA; Pillinger, M; Goncalves, IS; Rocha, J; Romao, CC
2003, CHEMISTRY-A EUROPEAN JOURNAL, 9, 12, 2685-+.

Molecular structure - Activity relationships for the oxidation of organic compounds using mesoporous silica catalysts derivatised with bis(halogeno)dioxomolybdenum(VI) complexes

Nunes, CD; Valente, AA; Pillinger, M; Rocha, J; Goncalves, IS
2003, CHEMISTRY-A EUROPEAN JOURNAL, 9, 18, 4380-4390.

Dioxomolybdenum(VI)-modified mesoporous MCM-41 and MCM-48 materials for the catalytic epoxidation of olefins

Nunes, CD; Pillinger, M; Valente, AA; Rocha, J; Lopes, AD; Goncalves, IS
2003, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 21, 3870-3877.

Assessing the potential of fast amplitude modulation pulses for improving triple-quantum magic angle spinning NMR spectra of half-integer quadrupolar nuclei

Morais, CM; Lopes, M; Fernandez, C; Rocha, J
2003, MAGNETIC RESONANCE IN CHEMISTRY, 41, 9, 679-688.

Microporous materials containing lanthanide metals

Rocha, J; Carlos, LD
2003, CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 7, 3, 199-205.

Lanthanide complexes of 2-hydroxynicotinic acid: synthesis, luminescence properties and the crystal structures of [Ln(HnicO)(2)(mu-HnicO)(H2O)] center dot nH(2)O (Ln = Tb, Eu)

Soares-Santos, PCR; Nogueira, HIS; Rocha, J; Felix, V; Drew, MGB; Ferreira, RAS; Carlos, LD; Trindade, T
2003, POLYHEDRON, 22, 27, 3529-3539.

Ab initio structure determination of novel small-pore metal-silicates: knots-and-crosses structures

Ferreira, A; Lin, Z; Soares, MR; Rocha, J
2003, INORGANICA CHIMICA ACTA, 356, 19-26.

Controlling hydrolysis and dispersion of AlN powders in aqueous media

Oliveira, M; Olhero, S; Rocha, J; Ferreira, JMF
2003, JOURNAL OF COLLOID AND INTERFACE SCIENCE, 261, 2, 456-463.

Synthesis and structural characterization of novel tin and titanium potassium silicates K4M2Si6O18

Lin, Z; Ferreira, A; Rocha, J
2003, JOURNAL OF SOLID STATE CHEMISTRY, 175, 2, 258-263.

Structure analysis of the novel microporous aluminophosphate IST-1 using synchrotron powder diffraction data and HETCOR MAS NMR

Jorda, JL; McCusker, LB; Baerlocher, C; Morais, CM; Rocha, J; Fernandez, C; Borges, C; Lourenco, JP; Ribeiro, MF; Gabelica, Z
2003, MICROPOROUS AND MESOPOROUS MATERIALS, 65, 1, 43-57.

Direct oxidation of dry methane on nanocrystalline Ce0.8Gd0.2O2-delta/Pt anodes

Yaremchenko, AA; Valente, AA; Kharton, VV; Bashmakov, IA; Rocha, J; Marques, FMB
2003, CATALYSIS COMMUNICATIONS, 4, 9, 477-483.

Novel microporous lanthanide silicates with tobermorite-like structure

Ferreira, A; Ananias, D; Carlos, LD; Morais, CM; Rocha, J
2003, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 125, 47, 14573-14579.

Oxidation of dry methane on the surface of oxygen ion-conducting membranes

Yaremchenko, AA; Valente, AA; Kharton, VV; Tsipis, EV; Frade, JR; Naumovich, EN; Rocha, J; Marques, FMB
2003, CATALYSIS LETTERS, 91, 3-4, 169-174.

Ordered benzene-silica hybrids with molecular-scale periodicity in the walls and different mesopore sizes

Bion, N; Ferreira, P; Valente, A; Goncalves, IS; Rocha, J
2003, JOURNAL OF MATERIALS CHEMISTRY, 13, 8, 1910-1913.

catena-[1,3-diammoniopropane di-mu(2)-hydroxo-di-mu(4)-phosphato-trioxotrivanadium dihydrate]: a redetermination at 180 (2) K

Paz, FAA; Shi, FN; Trindade, T; Rocha, J; Klinowski, J
2003, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 59, M179-M182.

Novel nuclear magnetic resonance techniques for the study of quadrupolar nuclei in clays and other layered materials

Rocha, J; Morais, CM; Fernandez, C
2003, CLAY MINERALS, 38, 3, 259-278.

Epoxidation of olefins catalyzed by molybdenum-siloxane compounds

Abrantes, M; Valente, AA; Pillinger, M; Goncalves, IS; Rocha, J; Romao, CC
2002, INORGANIC CHEMISTRY COMMUNICATIONS, 5, 12, 1069-1072.

The organosolv fractionation of cork components

Cordeiro, N; Neto, CP; Rocha, J; Belgacem, MN; Gandini, A
2002, HOLZFORSCHUNG, 56, 2, 135-142.

Lignin degradation in oxygen delignification catalysed by [PMo7V5O40](8-) polyanion. Part I. Study on wood lignin

Evtuguin, DV; Neto, CP; Rocha, J
2000, HOLZFORSCHUNG, 54, 4, 381-389.

Very high-resolution H-1 MAS NMR of a natural polymeric material

Gil, AM; Lopes, MH; Neto, CP; Rocha, J
1999, SOLID STATE NUCLEAR MAGNETIC RESONANCE, 15, 1, 59-67.

Oxidative delignification in the presence of molybdovanadophosphate heteropolyanions: mechanism and kinetic studies

Evtuguin, DV; Neto, CP; Rocha, J; de Jesus, JDP
1998, APPLIED CATALYSIS A-GENERAL, 167, 1, 123-139.

A C-13 solid state nuclear magnetic resonance spectroscopic study of cork cell wall structure: The effect of suberin removal

Gil, AM; Lopes, M; Rocha, J; Neto, CP
1997, INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 20, 4, 293-305.

The reaction of boric acid with wood in a polystyrene matrix (vol 62, pg 501, 1996)

Wang, YX; Simonsen, J; Neto, CP; Rocha, J; Rials, TG; Hart, E
1996, JOURNAL OF APPLIED POLYMER SCIENCE, 62, 11, 1977-1977.

The reaction of boric acid with wood in a polystyrene matrix

Wang, YX; Simonsen, J; Neto, CP; Rocha, J; Rials, TG; Hart, E
1996, JOURNAL OF APPLIED POLYMER SCIENCE, 62, 3, 501-508.

C-13 SOLID-STATE NUCLEAR-MAGNETIC-RESONANCE AND FOURIER-TRANSFORM INFRARED STUDIES OF THE THERMAL-DECOMPOSITION OF CORK

NETO, CP; ROCHA, J; GIL, A; CORDEIRO, N; ESCULCAS, AP; ROCHA, S; DELGADILLO, I; DEJESUS, JDP; CORREIA, AJF
1995, SOLID STATE NUCLEAR MAGNETIC RESONANCE, 4, 3, 143-151.

Characterisation of pharmaceutical solids combining NMR, X-ray diffraction and computer modelling

In María Angeles Canales (Eds.), Biophysical Techniques in Drug Discovery
Mariana Sardo, Inês Martins, Chiara Vladiskovic, M.Teresa Duarte, João Rocha, Norberto Masciocchi and Luís Mafra
2018, 120-169, Royal Society of Chemistry.
ISBN: 978-1-78262-733-3

Nanotecnologias e nanoética

In Maria do Céu Patrão Neves (Eds.), Ética Aplicada: Novas Tecnologias
João Rocha
2018, 87-122, Edições 70, Almedina.
ISBN: 978-972-44-2131-5

Solid-state NMR applications in the structural elucidation of small molecules

In Cid, M-M and Bravo, J. (Eds.), Structure Elucidation in Organic Chemistry: The Search for the Right Tools
Sardo, M., Rocha, J. and Mafra, L.
2015, Wiley-VCH.
ISBN: 978-3-527-33336-3

N-(Phosphonomethyl)iminodiacetic Acid in the Construction of Coordination Polymers

Metal Phosphonate Chemistry: From Synthesis to Applications
Paz FAA, Rocha J
2012, London, Royal Society of Chemistry.
ISBN: 978-1-84973-356-4

Layered Titanosilicates

In M. F. Brigatti and A. Mottana (Eds.), Layered mineral structures and their Application in Advanced Technologies
Lin Z, Paz FAA, Rocha J
2011, New York, European Mineralogical Union and the Mineralogical Society of Great Britain & Ireland.
ISBN: 978-0-903056-27-4

Crystallization of microporous titanosilicate membranes from clear solutions.

In R Xu, Z Giao, J Chen and W Yan (Eds.), From Zeolites to Porous MOFs - The 40th Anniversary of International Zeolite Conferences. Studies in Surface Science and Catalysis
Lin Z, Rocha J
2007, 170, 493-498, Amstesdam, Elsevier.
ISBN: 978-0444531858

29Si MAS NMR and raman spectroscopy studies of synthetic microporous (Zr, Hf)-umbite

In Čejka J, Žilková N, Nachtigall P (Eds.), Studies in Surface Science and Catalysis
Lin Z, Rocha J
2005, 158 , 861-868, Prague, Czech Republic.
ISBN: 978-0-444-51670-1

Microporous mixed octahedral-pentahedral tetrahedral framework oxides

In Giovanni Ferraris, Stefano Merlino (Eds.), Reviews in Mineralogy & Geochemistry - Micro- and Mesoporous Mineral Phases
Lin Z , Rocha J
2005, 57, 173-201, Mineralogical Society of America, Geochemical Society .
ISBN: 978-0-939950-69-0

Preparation of titanosilicate ETS-10 and vanadosilicate AM-6 membranes

In Čejka J, Žilková N, Nachtigall P (Eds.), Studies in Surface Science and Catalysis
Tiscornia I, Lin Z, Rocha J, Téllez C, Coronas J
2005, 158 A, 423-430.
ISBN: 978-0-444-51670-1

Progress in multiple-quantum magic-angle spinning NMR spectroscopy

In Klinowski J (Eds.), New techniques in solid-state nmr-topics in current chemistry
Rocha J, Morais CM, Fernandez C
2005, 246, 141-194, Springer.
ISBN: 978-3540221685

Progress in Multiple-Quantum Magic-Angle Spinning NMR Spectroscopy

Topics in Current Chemistry
Rocha J, Morais CM
2004, 246, 141-194, Berlin,Heidelberg , Springer-Verlag.
ISBN: 978-3-540-71426-2

Powder Processes conditioning for thermal spraying

J. Mesquita-Guimarães, E. Garcia, P. Miranzo, M. I. Osendi
.

Patentes

Materiais híbridos nanomagnete-porfirina, processo para a sua síntese e respetiva aplicação em formulações para desinfeção de águas

Materials Nacional

Cavaleiro, José ; Tome, Augusto ; Tome, João ; Rocha, João; Lin, Zhi; Carvalho, Carla ; Costa, Liliana ; Alves, Eliana ; Cunha, Maria ; Faustino, Maria ; Neves, Maria ; Rainho, José;

A presente invenção diz respeito à síntese de novos materiais híbridos nanomagnete-porfirina de fórmula geral (I) e à sua utilização para fotoinativar microrganismos presentes em águas contaminadas. O processo utilizado para a s...

Utilização de um metilfosfonato de alumínio microporoso cristalino para a purificação do cloreto de vinilo

Processes Nacional

Rocha, João; Coutinho, João ; Freitas, Francisco; Valente, Anabela ; Lin, Zhi

A presente invenção diz respeito à separação de cloreto de etilo e cloreto de vinilo por absorção utilizando um metilfosfato de alumínio microporoso cristalino como absorvente.A capacidade de absorção do metilfosfona...

João Rocha

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Últimas Notícias

João Rocha coordena painel de avaliação de bolsas ERC

João Mano distinguido com Prémio Investigador UA

Nova Rede de RMN junta sete centros de investigação europeus e um americano

João Rocha no evento "Ciência em Portugal: um diagnóstico"

João Rocha distinguido com Prémio Ferreira da Silva 2016

Perfil biográfico

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Grupo de Investigação

Projectos

Publicações seleccionadas

PALESTRAS SELECCIONADAS 2015-2019 (DE UM TOTAL DE Ca. 40)

Projectos

Agentes de Contraste Vectorizados para Imagem por Ressonância Magnética (IRM) e Cintigrafia Nuclear (ACV) (POCTI/QUI/47005/2002)

Coordenador LocalFundação para a Ciência e a Tecnologia

CAPACITAR O CICECO PARA INTERNACIONALIZAR A I&DT EM MATERIAIS E INCREMENTAR A COMPETITIVIDADE NACIONAL (CENTRO-07-0962-FEDER-002003 #1)

CoordenadorOther National

CAPACITAR O CICECO PARA INTERNACIONALIZAR A I&DT EM MATERIAIS E INCREMENTAR A COMPETITIVIDADE NACIONAL (CENTRO-07-0962-FEDER-002003 #2)

CoordenadorUA

Centro de Investigação em Materiais Cerâmicos e Compósitos - CICECO (LA0011: 2002-2010) (UI CICECO (UI 600/02) + POCI/LA11/2005)

CoordenadorFundação para a Ciência e a Tecnologia

Centro de Investigação em Materiais Cerâmicos e Compósitos - CICECO (LA0011: 2011-2012) (PEst-C/CTM/LA0011/2011)

CoordenadorFundação para a Ciência e a Tecnologia

Centro de Investigação em Materiais Cerâmicos e Compósitos - CICECO (LA0011: 2013-2014) (PEst-C/CTM/LA0011/2013)

CoordenadorFundação para a Ciência e a Tecnologia - R&D Unit Pluriannual funding

Centro de Investigação em Materiais Cerâmicos e Compósitos - CICECO - INCENTIVO (INCENTIVO/CTM/LA0011/2014)

CoordenadorFundação para a Ciência e a Tecnologia - R&D Unit Pluriannual funding

Centro de Investigação em Materiais Cerâmicos e Compósitos - CICECO - INCENTIVO 2013 (INCENTIVO/CTM/LA0011/2013)

CoordenadorFundação para a Ciência e a Tecnologia - R&D Unit Pluriannual funding

CICECO – Instituto de Materiais de Aveiro (UID/CTM/50011/2013)

CoordenadorFundação para a Ciência e a Tecnologia - R&D Unit Pluriannual funding

CICECO – Instituto de Materiais de Aveiro (UIDP/50011/2020)

CoordenadorFundação para a Ciência e a Tecnologia

CICECO – Instituto de Materiais de Aveiro (UIDB/50011/2020)

CoordenadorFundação para a Ciência e a Tecnologia

CICECO – Instituto de Materiais de Aveiro (UID/CTM/50011/2019)

CoordenadorFundação para a Ciência e a Tecnologia - R&D Unit Pluriannual funding

CICECO – Instituto de Materiais de Aveiro (UID/CTM/50011/2013)

CoordenadorFundação para a Ciência e a Tecnologia - R&D Unit Pluriannual funding

Controlo da escala de tamanho através de "Chimie Douce": de materiais funcionais inorgânicos a hìbridos orgânicos-inorgânicos (POCTI/CTM/46780/2002)

CoordenadorFundação para a Ciência e a Tecnologia

Dadores de gasotransmissores NO e H2S terapêuticos baseados em materiais nanoporosos (PTDC/MED-QUI/28721/2017)

Coordenador LocalFundação para a Ciência e a Tecnologia

De Matérias primas baratas para novos materiais vitreos luminescentes (InLumGlass)

Coordenador LocalFundação para a Ciência e a Tecnologia

EJD-FUNMAT - European Joint Doctorate in Functional Materials Research (EJD-FUNMAT)

ParticipanteEuropean Comission

ENERMATaa (ENERMATaa)

Coordenador LocalEuropean Comission

Especies de CO2 formadas a superficie de materiais porosos para aplicacoes ambientais caracterizadas por RMN de polarizacao nuclear dinamica (GAS2MAT-DNPSENS)

ParticipanteFundação para a Ciência e a Tecnologia

Fotossensibilizadores imobilizados como novos materiais no tratamento de águas (POCI/CTM/58183/2004)

ParticipanteFundação para a Ciência e a Tecnologia

Functionalised Advanced Materials and Engineering of Hybrids and Ceramics - FAME (FAME)

Coordenador LocalEuropean Comission

Imobilização de arilióxidos de terras raras e actinídeos Activação de pequenas moléculas (CO2,CH4,C2H6) (POCTI/QUI/42919/2001)

Coordenador LocalFundação para a Ciência e a Tecnologia

Luminescent Metal Organic Frameworks for anti-counterfeiting and logic computing (LUMIMOF)

CoordenadorEuropean Comission

Materiais para medicina regenerativa (CENTRO-07-0924-FEDER-002030)

CoordenadorOther National

Melhorar o Laboratório Central de Difracção de Raios - X da Universidade de Aveiro (REEQ/183/QUI/2005)

CoordenadorFundação para a Ciência e a Tecnologia

MNAA - Centres of excellence in materials for the economic development of the Atlantic Area (MNAA - MATERIALS NETWORK FOR THE ATLANTIC AREA)

Coordenador LocalOther International

Multiferróicos híbridos orgânico-inorgânicos foto-responsivos: Na senda da eletrónica multifuncional (PTDC/CTM-CTM/4044/2020)

ParticipanteFundação para a Ciência e a Tecnologia

Nanogotas de Água em Materiais Microporosos e Híbridos Orgânicos-Inorgânicos (PTDC/QUI/65805/2006)

CoordenadorFundação para a Ciência e a Tecnologia

Nanopartículas integrando aquecedores e termómetros: aplicações ao movimento Browniano e em hipertermia (nanoHYperTHerm)

ParticipanteFundação para a Ciência e a Tecnologia

Nanotubos e silicates microporosos de terras raras, fotoluminescentes (PTDC/CTM/73243/2006)

CoordenadorFundação para a Ciência e a Tecnologia