Transposition of chirality from diphosphonate metal-organic framework precursors onto porous lanthanide pyrophosphates

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abstract

Chiral porous inorganic materials, lanthanide pyrophosphates, were prepared from chiral porous metal-organic framework precursors, which upon thermal decomposition transpose their chirality and porosity onto the inorganic framework. It is argued that this synthesis concept may be extended to other chiral porous inorganic solids.

keywords

SPONTANEOUS RESOLUTION; SOLIDS; ZEOLITE

subject category

Chemistry

authors

Shi, FN; Paz, FAA; Ribeiro-Claro, P; Rocha, J

our authors

foto Fa-Nian Shi

Fa-Nian Shi

Researcher
foto Filipe Alexandre Almeida Paz

Filipe Alexandre Almeida Paz

Principal Researcher
foto João Rocha

João Rocha

Director
foto Paulo Jorge Almeida Ribeiro Claro

Paulo Jorge Almeida Ribeiro Claro

Associate Professor with Aggregation

Groups

1 - Inorganic Functional Nanomaterials and Organic-Inorganic Hybrids
6 - Computer Simulation and Multiscale Modeling

Projects

Centre for Research in Ceramics and Composite Materials - CICECO (LA0011: 2013-2014) (PEst-C/CTM/LA0011/2013)
Nano-sized Functional Metal-Organic Frameworks Based on Lanthanide Polyphosphonates (PTDC/QUI-QUI/098098/2008)
Novel smart multi-functional Transition metal-Rare earth-Organic- Frameworks (TROFs) toward tunable magnetic and luminescent properties (PTDC/CTM-NAN/119994/2010)

acknowledgements

We thank Fundacao para a Ciencia e a Tecnologia (FCT), FEDER, QREN, COMPETE (PEst-C/CTM/LA0011/2013). F.-N. SHI acknowledges FCT for the Ciencia 2007 program and the project PTDC/CTM-NAN/119994/2010. F. A. A. P. also wishes to thank FCT for financial support through the R&D project PTDC/QUI-QUI/098098/2008. Drs Moises Pinto and Sergio Santos are acknowledged for, respectively, providing the gas adsorption data and some structure ab initio calculations.

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Publication Details

type
Journal Article
year
2013
journal
CHEMICAL COMMUNICATIONS
volume
49
publisher
ROYAL SOC CHEMISTRY
issn
1359-7345
issue
99
digital object identifier
10.1039/c3cc46503a
web of science article identifier
WOS:000327446200018

Journal Metrics (JCR 2019)

Journal Impact Factor
5.996
Journal Impact Factor (5 yrs)
5.818
category normalized journal percentile
81.073

Citations

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