resumo
The very dense (d = 4.359 g cm(-3)) three dimensional (3D) hybrid heterometallic framework Bi3O2Cu(OH)(pdc)(2) (pdc(3-):3,5-pyrazoledicarboxylate), 1, features a 2D inorganic subnetwork representing an unprecedented topological type, and is an effective catalyst for the diastereoselective synthesis of E-alpha,beta-unsaturated ketones.
palavras-chave
COORDINATION POLYMERS; HYDROTHERMAL SYNTHESIS; BISMUTH SUBSALICYLATE; MOLECULAR PRECURSORS; CRYSTAL-STRUCTURE; SALICYLATE; COMPLEXES; ION
categoria
Chemistry; Crystallography
autores
Shi, FN; Silva, AR; Yang, TH; Rocha, J
nossos autores
Ana Rosa Silva
Investigador Principal
Fa-Nian Shi
Investigador
João Rocha
Diretor
Tinghai Yang
Bolseiro de pós-DoutoramentoProjectos
Centre for Research in Ceramics and Composite Materials - CICECO (LA0011: 2011-2012) (PEst-C/CTM/LA0011/2011)
Novel smart multi-functional Transition metal-Rare earth-Organic- Frameworks (TROFs) toward tunable magnetic and luminescent properties (PTDC/CTM-NAN/119994/2010)
agradecimentos
We thank FCT, FEDER, QREN, COMPETE, (PEst-C/CTM/LA0011/2011), Rede Nacional de RMN, and grant SFRH/BPD/74582/2010, F.-N. SHI and Ana acknowledge FCT for Ciencia 2007, 2008 program and project PTDC/CTM-NAN/119994/2010.