resumo
A rapid, mild and high-yield microwave synthesis of 1D isotypical [Ln(H(4)bmt)(H(5)bmt)(H2O)(2)]center dot 3H(2)O coordination polymers is presented. The La3+-based material is highly active as a heterogeneous catalyst in the methanolysis of styrene oxide at nearly room temperature. Eu3+- and Tb3+-doped materials are very effective UV-to-visible light converters.
palavras-chave
METAL-ORGANIC FRAMEWORKS; FUNCTIONALITY; LUMINESCENCE; COMPLEXES; DESIGN; TEMPERATURE; SEPARATION; NUMBER; IONS; SIZE
categoria
Chemistry
autores
Vilela, SMF; Firmino, ADG; Mendes, RF; Fernandes, JA; Ananias, D; Valente, AA; Ott, H; Carlos, LD; Rocha, J; Tome, JPC; Paz, FAA
nossos autores
Ana Daniela Gonçalves Firmino
Investigador
Anabela Tavares Aguiar Valente
Investigador Principal
Duarte Ananias Marques
Investigador Auxiliar
Filipe Alexandre Almeida Paz
Investigador Principal
João Rocha
Diretor
José Alberto Pires Fernandes
Bolseiro de pós-Doutoramento
Luís António Ferreira Martins Dias Carlos
Professor Catedrático
Ricardo Faria Mendes
Investigador
Sérgio Manuel Felipe Vilela
Bolseiro de pós-DoutoramentoGrupos
1 - Nanomateriais inorgânicos funcionais e híbridos orgânico-inorgânico
4 - biorrefinarias, materiais de origem biológica e reciclagem
Projectos
Nano-sized Functional Metal-Organic Frameworks Based on Lanthanide Polyphosphonates (PTDC/QUI-QUI/098098/2008)
Centre for Research in Ceramics and Composite Materials - CICECO (LA0011: 2011-2012) (PEst-C/CTM/LA0011/2011)
agradecimentos
We thank FCT, the European Union, QREN, FEDER, COMPETE and CICECO (PEst-C/CTM/LA0011/2011). We further wish to thank FCT for the R&D project PTDC/QUI-QUI/098098/2008 (FCOMP-01-0124-FEDER-010785), the PhD grants no. SFRH/BD/66371/2009 (to SMFV), SFRH/BD/84495/2012 (to ADGF), SFRH/BD/84231/2012 (to RFM), and the post-doctoral grant SFRH/BPD/63736/2009 (to JAF).