resumo
Novel chiral halogen and chalcogen bonding receptors exhibit different selectivities for stereo- and geometric dicarboxylate isomers compared to a hydrogen bonding analogue. The unique geometric and electronic properties of the chalcogen bonding receptor facilitate the diagnostic fluorescence sensing of geometric dicarboxylate isomer guest species.
palavras-chave
ANION RECOGNITION; ASPARTATE; DINUCLEAR; GLUTAMATE; ACIDS
categoria
Chemistry
autores
Lim, JYC; Marques, I; Felix, V; Beer, PD
nossos autores
Igor Oliveira Marques
Investigador
Vítor Félix
Professor Associado com AgregaçãoProjectos
Anion transmembrane transport promoted by drug-like molecules: building a library of anion carriers inspired in Ataluren (PTC124) (PTDC/QEQ-SUP/4283/2014)
CICECO - Aveiro Institute of Materials (UID/CTM/50011/2013)
agradecimentos
J. Y. C. L. acknowledges the Agency for Science, Technology and Research (A*STAR), Singapore, for postgraduate research funding. The theoretical studies were supported by projects P2020-PTDC/QEQ-SUP/4283/2014 and CICECO - Aveiro Institute of Materials (UID/CTM/50011/2013), financed by National Funds through the FCT/MEC and, when applicable, co-financed by QREN-FEDER through COMPETE, under the PT2020 Partnership Agreement.