Catalytic dehydration of fructose to HMF over sulfonic acid functionalized periodic mesoporous organosilicas: role of the acid density

  1. Home

abstract

Here, we reported the catalytic efficiency of sulfonic acid functionalized periodic mesoporous organosilica (PMO) materials with crystal-like pore walls in the dehydration of fructose to HMF in water. We found that the proton loading, the localization of acid sites and the surface hydrophobicity played a crucial role in the PMO activity.

keywords

CHEMISORBED TRIETHYLPHOSPHINE OXIDE; P-31 MAS-NMR; IONIC LIQUIDS; SILICA; SBA-15; WATER; EFFICIENT; WALLS

subject category

Chemistry

authors

Bispo, C; Vigier, KD; Sardo, M; Bion, N; Mafra, L; Ferreira, P; Jerome, F

our authors

foto Cláudia Sofia dos Santos Bispo

Cláudia Sofia dos Santos Bispo

PhD Student
foto Luís Mafra

Luís Mafra

Principal Researcher
foto Mariana Isabel Coutinho Sardo

Mariana Isabel Coutinho Sardo

Auxiliary Researcher
foto Paula Celeste da Silva Ferreira

Paula Celeste da Silva Ferreira

Research Coordinator

Groups

1 - Inorganic Functional Nanomaterials and Organic-Inorganic Hybrids
2 - Multifunctional Ferroic Ceramics and Nanostructures

Projects

Design of acid-functionalised periodic mesoporous organosilica catalysts for reactions with/in water (PTDC/QUI-QUI/113678/2009)
Centre for Research in Ceramics and Composite Materials - CICECO (LA0011: 2013-2014) (PEst-C/CTM/LA0011/2013)

acknowledgements

Authors are grateful to the CNRS and the French Ministry of Research for financial support. We are grateful to the Fundacao para a Ciencia e a Tecnologia (FCT), Fundo Europeu de Desenvolvimento Regional (FEDER), QREN-COMPETE (PTDC/QUI-QUI/113678/2009), the European Union, and the Associate Laboratory CICECO (Pest-C/CTM/LA0011/2013) for continued support and funding.

Share this project:

Related Publications

Publication Details

type
Journal Article
year
2014
journal
CATALYSIS SCIENCE & TECHNOLOGY
volume
4
publisher
ROYAL SOC CHEMISTRY
issn
2044-4753
issue
8
digital object identifier
10.1039/c4cy00137k
web of science article identifier
WOS:000339551400005

Journal Metrics (JCR 2019)

Journal Impact Factor
5.721
Journal Impact Factor (5 yrs)
5.863
category normalized journal percentile
74.528

Citations

Social Interaction

We use cookies for marketing activities and to offer you a better experience. By clicking “Accept Cookies” you agree with our cookie policy. Read about how we use cookies by clicking "Privacy and Cookie Policy".


Privacy and Cookie Policy

Personal data

CICECO-Aveiro Institute of Materials respects your privacy, ensuring confidentiality of personal data you share with the institution through this way, not collecting any personal information about you without your consent, under the terms required by General Data Protection Regulations (RGPD).

The data collected in forms are intended exclusively for processing user requests and will not be used for any other purpose, always safeguarding their confidentiality, under the terms of the protection conferred by the aforementioned regulation.

The collection and processing of data is the responsibility of CICECO and its storage is properly protected, only authorized CICECO employees can access the information within the scope of their functions, always being clear in the respective collection forms the purposes for which they are intended. The remaining issues to be considered in this matter will be handled by the University of Aveiro in accordance with the regime established by the GDPR.

Cookies policy

Cookies are small files with alphanumeric information that are stored on your computer's hard drive by your browser and are intended to improve the user experience and enhance website navigation.

Collection and use of technical information

The cookies used on CICECO are anonymous, and no information about our users that allows their personal identification is stored in them.

The technical information recorded consists of:

  • iP (Internet Protocol) address of the visitor;
  • the type of internet browser used by the website visitor and the respective operating system used;
  • the date and time of the consultation;
  • the pages visited on the site and the documents downloaded
  • The technical information collected is used for statistical purposes only.

Cookies used

Session cookies

These cookies are used to record user preferences, such as the language in which websites are displayed or to maintain authenticated user sessions, and are automatically deleted when the browser is closed.

Persistent cookies

These cookies store information that is needed between sessions. For example, a persistent cookie is set to record that you have been made aware of the cookie policy so that the message regarding this policy is not shown again the next time you visit the website. This cookie remains on the computer until it reaches its expiry date or is deleted by the user.

Data protection

The present privacy policy covers the Information System of the University of Aveiro (SIUA), governed by the General Data Protection Regulations (RGPD) Regulation (EU) No. 2016/679, of April 27th, 2016.

Data Protection Officer

The University of Aveiro has a Data Protection Officer (DPO), who ensures compliance of the processing of personal data with the legislation in force, and is available through the following email address epd@ua.pt.

Close