Projects
European network of FURan based chemicals and materials FOR a Sustainable development (FUR4Sustain)
CoordinatorEuropean Comission
Modern society relies on a huge quantity of polymeric materials. However, today, these materials are still almost exclusively based on fossil-resources and evolution to a more sustainable model of development is required. In this perspective, biomass and, in particular carbohydrates from, for example, low value bioma...Rational design of a thermostable esterase for the production of highvalue bioplastics for biomedical applications (ThermoEst)
Local CoordinatorFundação para a Ciência e a Tecnologia
This project is focused on the design of customized thermostable enzymes to produce highvaluebiopolymers for biomedicalapplications.We are living a new industrial production paradigm era, where biocatalysis is becoming increasingly competitive and replacingtraditional chemical synthesis. Nowadays, ...Publications
Asymmetric Monomer, Amorphous Polymer? Structure-Property Relationships in 2,4-FDCA and 2,4-PEF
Nolasco, MM; Araujo, CF; Thiyagarajan, S; Rudic, S; Vaz, PD; Silvestre, AJD; Ribeiro-Claro, PJA; Sousa, AF
2020, MACROMOLECULES, 53, 4, 1380-1387.
ISBN:
1520-5835
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Enzymatic Synthesis of Poly(caprolactone): A QM/MM Study
Pedro R. Figueiredo, Beatriz C. Almeida, Daniel F. A. R. Dourado, Andreia F. Sousa, Armando J. D. Silvestre and Alexandra T. P. Carvalho
2020, ChemCatChem, 12, 19, 4845-4852.
ISBN:
1867-3899
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A Perspective on PEF Synthesis, Properties, and End-Life
Loos, K; Zhang, RY; Pereira, I; Agostinho, B; Hu, H; Maniar, D; Sbirrazzuoli, N; Silvestre, AJD; Guigo, N; Sousa, AF
2020, FRONTIERS IN CHEMISTRY, 8.
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Co-Polymers based on Poly(1,4-butylene 2,5-furandicarboxylate) and Poly(propylene oxide) with Tuneable Thermal Properties: Synthesis and Characterization
Matos, M; Sousa, AF; Mendonca, PV; Silvestre, AJD
2019, MATERIALS, 12, 2.
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Cinnamic acid derivatives as promising building blocks for advanced polymers: synthesis, properties and applications
Fonseca, AC; Lima, MS; Sousa, AF; Silvestre, AJ; Coelho, JFJ; Serra, AC
2019, POLYMER CHEMISTRY, 10, 14, 1696-1723.
ISBN:
1759-9962
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Highly transparent films of new copolyesters derived from terephthalic and 2,4-furandicarboxylic acids
Zaidi, S; Thiyagarajan, S; Bougarech, A; Sebti, F; Abid, S; Majdi, A; Silvestre, AJD; Sousa, AF
2019, POLYMER CHEMISTRY, 10, 39, 5324-5332.
ISBN:
1759-9962
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Replacing Di(2-ethylhexyl) Terephthalate by Di(2-ethylhexyl) 2,5-Furandicarboxylate for PVC Plasticization: Synthesis, Materials Preparation and Characterization
Matos, M; Cordeiro, RA; Faneca, H; Coelho, JFJ; Silvestre, AJD; Sousa, AF
2019, MATERIALS, 12, 14.
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Inside PEF: Chain Conformation and Dynamics in Crystalline and Amorphous Domains
Araujo, CF; Nolasco, MM; Ribeiro-Claro, PJA; Rudic, S; Silvestre, AJD; Vaz, PD; Sousa, AF
2018, MACROMOLECULES, 51, 9, 3515-3526.
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Tailored design of renewable copolymers based on poly(1,4-butylene 2,5-furandicarboxylate) and poly(ethylene glycol) with refined thermal properties
Sousa, AF; Guigo, N; Pozycka, M; Delgado, M; Soares, J; Mendonca, PV; Coelho, JFJ; Sbirrazzuoli, N; Silvestre, AJD
2018, POLYMER CHEMISTRY, 9, 6, 722-731.
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Furanoate-Based Nanocomposites: A Case Study Using Poly(Butylene 2,5-Furanoate) and Poly(Butylene 2,5-Furanoate)-co-(Butylene Diglycolate) and Bacterial Cellulose
Matos, M; Sousa, AF; Silva, NHCS; Freire, CSR; Andrade, M; Mendes, A; Silvestre, AJD
2018, POLYMERS, 10, 8.
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Bio-based poly(butylene 2,5-furandicarboxylate)-b-poly(ethylene glycol) copolymers with adjustable degradation rate and mechanical properties: Synthesis and echaracterization
Hu, H; Zhang, RY; Sousa, A; Long, Y; Ying, WB; Wang, JG; Zhu, J
2018, EUROPEAN POLYMER JOURNAL, 106, 42-52.
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Improving the Thermal Properties of Poly(2,5-furandicarboxylate)s Using Cyclohexylene Moieties: A Comparative Study
Matos, M; Sousa, AF; Silvestre, AJD
2017, MACROMOLECULAR CHEMISTRY AND PHYSICS, 218, 5.
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Increasing the Bile Acid Sequestration Performance of Cationic Hydrogels by Using an Advanced/Controlled Polymerization Technique
Mendonca, PV; Matos, A; Sousa, AF; Serra, AC; Simoes, S; Coelho, JFJ
2017, PHARMACEUTICAL RESEARCH, 34, 9, 1934-1943.
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Thermosetting AESO-bacterial cellulose nanocomposite foams with tailored mechanical properties obtained by Pickering emulsion templating
Sousa, AF; Ferreira, S; Lopez, A; Borges, I; Pinto, RJB; Silvestre, AJD; Freire, CSR
2017, POLYMER, 118, 127-134.
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Poly(1,20-eicosanediyl 2,5-furandicarboxylate), a biodegradable polyester from renewable resources
Soares, MJ; Dannecker, PK; Vilela, C; Bastos, J; Meier, MAR; Sousa, AF
2017, EUROPEAN POLYMER JOURNAL, 90, 301-311.
ISBN:
1873-1945
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New unsaturated copolyesters based on 2,5-furandicarboxylic acid and their crosslinked derivatives
Sousa, AF; Fonseca, AC; Serra, AC; Freire, CSR; Silvestre, AJD; Coelho, JFJ
2016, POLYMER CHEMISTRY, 7, 5, 1049-1058.
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Renewable-based poly((ether)ester)s from 2,5-furandicarboxylic acid
Sousa, AF; Coelho, JFJ; Silvestre, AJD
2016, POLYMER, 98, 129-135.
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Unravelling the distinct crystallinity and thermal properties of suberin compounds from Quercus suber and Betula pendula outer barks
Sousa, AF; Gandini, A; Caetano, A; Maria, TMR; Freire, CSR; Neto, CP; Silvestre, AJD
2016, INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 93, 686-694.
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Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: a tribute to furan excellency
Sousa, AF; Vilela, C; Fonseca, AC; Matos, M; Freire, CSR; Gruter, GJM; Coelhob, JFJ; Silvestre, AJD
2015, POLYMER CHEMISTRY, 6, 33, 5961-5983.
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Erratum: Biobased polyesters and other polymers from 2,5-furandicarboxylic acid: A tribute to furan excellency
AF Sousa*, C Vilela, AC Fonseca, M Matos, CSR Freire, G-JM Gruter, JFJ Coelho, AJD Silvestre
2015, Polymer Chemistry, 6, 33, 6096-6096.
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One-pot synthesis of biofoams from castor oil and cellulose microfibers for energy absorption impact materials
Sousa, AF; Matos, M; Pinto, RJB; Freire, CSR; Silvestre, AJD
2014, CELLULOSE, 21, 3, 1723-1733.
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Unveiling the dual role of the cholinium hexanoate ionic liquid as solvent and catalyst in suberin depolymerisation
Ferreira, R; Garcia, H; Sousa, AF; Guerreiro, M; Duarte, FJS; Freire, CSR; Calhorda, MJ; Silvestre, AJD; Kunz, W; Rebelo, LPN; Pereira, CS
2014, RSC ADVANCES, 4, 6, 2993-3002.
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Ex Situ Reconstitution of the Plant Biopolyester Suberin as a Film
Garcia, H; Ferreira, R; Martins, C; Sousa, AF; Freire, CSR; Silvestre, AJD; Kunz, W; Rebelo, LPN; Pereira, CS
2014, BIOMACROMOLECULES, 15, 5, 1806-1813.
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A New Generation of Furanic Copolyesters with Enhanced Degradability: Poly(ethylene 2,5-furandicarboxylate)-co-poly(lactic acid) Copolyesters
Matos, M; Sousa, AF; Fonseca, AC; Freire, CSR; Coelho, JFJ; Silvestre, AJD
2014, MACROMOLECULAR CHEMISTRY AND PHYSICS, 215, 22, 2175-2184.
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The quest for sustainable polyesters - insights into the future
Vilela, C; Sousa, AF; Fonseca, AC; Serra, AC; Coelho, JFJ; Freire, CSR; Silvestre, AJD
2014, POLYMER CHEMISTRY, 5, 9, 3119-3141.
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Phenolic composition and antioxidant activity of industrial cork by-products
Santos, SAO; Villaverde, JJ; Sousa, AF; Coelho, JFJ; Neto, CP; Silvestre, AJD
2013, INDUSTRIAL CROPS AND PRODUCTS, 47, 262-269.
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Novel sustainable composites prepared from cork residues and biopolymers
Vilela, C; Sousa, AF; Freire, CSR; Silvestre, AJD; Neto, CP
2013, BIOMASS & BIOENERGY, 55, 148-155.
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New copolyesters derived from terephthalic and 2,5-furandicarboxylic acids: A step forward in the development of biobased polyesters
Sousa, AF; Matos, M; Freire, CSR; Silvestre, AJD; Coelho, JFJ
2013, POLYMER, 54, 2, 513-519.
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Isolation of suberin from birch outer bark and cork using ionic liquids: A new source of macromonomers
Ferreira, R; Garcia, H; Sousa, AF; Freire, CSR; Silvestre, AJD; Rebelo, LPN; Pereira, CS
2013, INDUSTRIAL CROPS AND PRODUCTS, 44, 520-527.
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Microwave assisted extraction of betulin from birch outer bark
Ferreira, R; Garcia, H; Sousa, AF; Freire, CSR; Silvestre, AJD; Kunz, W; Rebelo, LPN; Pereira, CS
2013, RSC ADVANCES, 3, 44, 21285-21288.
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Suberin isolation from cork using ionic liquids: characterisation of ensuing products
Ferreira, R; Garcia, H; Sousa, AF; Petkovic, M; Lamosa, P; Freire, CSR; Silvestre, AJD; Rebelo, LPN; Pereira, CS
2012, NEW JOURNAL OF CHEMISTRY, 36, 10, 2014-2024.
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Synthesis of aliphatic suberin-like polyesters by ecofriendly catalytic systems
Sousa, AF; Silvestre, AJD; Gandini, A; Neto, CP
2012, HIGH PERFORMANCE POLYMERS, 24, 1, 4-8.
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Novel Suberin-Based Biopolyesters: From Synthesis to Properties
Sousa, AF; Gandini, A; Silvestre, AJD; Neto, CP; Pinto, JJCC; Eckerman, C; Holmbom, B
2011, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 49, 10, 2281-2291.
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Determination of the Hydroxy and Carboxylic Acid Groups in Natural Complex Mixtures of Hydroxy Fatty Acids by H-1 Nuclear Magnetic Resonance Spectroscopy
Sousa, AF; Gandini, A; Silvestre, AJD; Neto, CP
2009, APPLIED SPECTROSCOPY, 63, 8, 873-878.
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The Furan Counterpart of Poly(ethylene terephthalate): An Alternative Material Based on Renewable Resources
Gandini, A; Silvestre, AJD; Neto, CP; Sousa, AF; Gomes, M
2009, JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 47, 1, 295-298.
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Quercus suber and Betula pendula outer barks as renewable sources of oleochemicals: A comparative study
Pinto, PCRO; Sousa, AR; Silvestre, AJD; Neto, CP; Gandini, A; Eckerman, C; Holmbom, B
2009, INDUSTRIAL CROPS AND PRODUCTS, 29, 1, 126-132.
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Synthesis and Characterization of Novel Biopolyesters from Suberin and Model Comonomers
Sousa, AF; Gandini, A; Silvestre, AJD; Neto, CP
2008, CHEMSUSCHEM, 1, 12, 1020-1025.
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Triterpenic and other lipophilic components from industrial cork byproducts
Sousa, AF; Pinto, PCRO; Silvestre, AJD; Neto, CP
2006, JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 54, 18, 6888-6893.
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Improving regioselectivity in the rhodium catalyzed hydroformylation of protoporphyrin-IX and chlorophyll a derivatives
AF Peixoto, MM Pereira*, AF Sousa, AAC Pais, MGMPS Neves, AMS Silva, JAS Cavaleiro
2005, Elsevier, 235, 1-2, 185-193.
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Polymer distribution in connected spherical domains
AF Sousa*, AACC Pais and P Linse
2005, The Journal of Chemical Physics, 122, 21, 214902.
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Infrared spectroscopy and the characterization of terfenadine crystallized from solvents
MLP Leitão*, J Canotilho, AF Sousa, AACC Pais, AT Sousa and JS Redinha
2003, Journal of Thermal Analysis and Calorimetry volume, 73, 3, 763-774.
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Molecular dynamics simulation of the terfenadine monomer and dimer, including solvent effects
AF Sousa, J Canotilho, AACC PAis, MLP Leitão and JS Redinha
2003, Molecular Physics, 101, 6, 871-879.
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Solvation of alkane and alcohol molecules. energy contributions
AACC Pais*, AF Sousa, ME Eusébio and JS Redinha
2001, Physical Chemistry Chemical Physics, 3, 18, 4001-4009.
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Polyethylene Terephthalate: Copolyesters, Composites, and Renewable Alternatives

In P. M. Visakh Mong Liang (Eds.), Poly(ethylene Terephthalate) Based Blends, Composites and Nanocomposites.
Andreia F. Sousa, Carla Vilela, Marina Matos, Carmen S.R. Freire, Armando J.D. Silvestre, Jorge F.J. Coelho
2015, 111-139, Elsevier Science Ltd.
ISBN:
9780323313063
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Polyethylene Terephthalate: Copolyesters, Composites, and Renewable Alternatives

In Visakh P.M., Mong Liang (Eds.), POLY(ETHYLENE TEREPHTHALATE) BASED BLENDS, COMPOSITES AND NANOCOMPOSITES
Andreia F. Sousa, Carla Vilela, Marina Matos, Carmen S.R. Freire, Armando J.D. Silvestre, Jorge F.J. Coelho
2015, Elsevier Inc..
ISBN:
978-0-323-31306-3
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