resumo
This study focuses on constrained sintering of BaLa4Ti4O15 (BLT) thick films on Pt foils and BLT rigid substrates. The densification of BLT films is only retarded in comparison with their bulk counterpart, but, and in opposition to other constrained systems investigated until now, grain growth is favored in constrained BLT films. An additional degree of constraint is provided by using a rigid BLT substrate instead of a compliant platinum foil, which induces even larger coarsening. These observations point to the possible effect of mechanical stress developing during constrained sintering on the microstructure development.
palavras-chave
MICROWAVE DIELECTRIC-PROPERTIES; CRYSTAL-STRUCTURE; GRAIN-GROWTH; HOMOLOGOUS SERIES; QUALITY FACTOR; ALUMINA; DEFORMATION; DIFFUSION; LAMINATE
categoria
Materials Science
autores
Amaral, L; Jamin, C; Senos, AMR; Vilarinho, PM; Guillon, O
nossos autores
Ana Maria de Oliveira e Rocha Senos
Professor associado
Paula Maria Lousada Silveirinha Vilarinho
Vice-DiretorGrupos
2 - nanoestruturas e cerâmicos ferróicos multifuncionais
3 - materiais de carbono, compósitos e revestimentos funcionais
agradecimentos
This work was supported by the Portuguese Foundation for Science and Technology, under grant no. SFRH/BD/40927/2007 and by the DAAD/GRICES Bilateral Action no. 0811978.