resumo
A new heterodinuclear [Zn(L)Dy](3+) complex, with L being a compartmental Schiff base ligand, exhibits the characteristic Dy3+ luminescence associated with a single-ion field induced slow relaxation of the magnetisation. This complex may be considered as one of the rare examples of a bifunctional luminescent single-ion magnet.
palavras-chave
MOLECULE MAGNET; FIELD; ANISOTROPY; BEHAVIOR; COMPLEX
categoria
Chemistry
autores
Long, J; Vallat, R; Ferreira, RAS; Carlos, LD; Paz, FAA; Guari, Y; Larionova, J
nossos autores
Projectos
Centre for Research in Ceramics and Composite Materials - CICECO (LA0011: 2011-2012) (PEst-C/CTM/LA0011/2011)
Functionalised Advanced Materials and Engineering of Hybrids and Ceramics - FAME (FAME)
agradecimentos
The authors are grateful to UM2, CNRS, PAC ICGM, FCT Portugal (R&D project No. PDTC/QUI-QUI/098098/2008 - FCOMP-01-0124-FEDER-010785), CICECO (PEst-C/CTM/LA0011/2011) and NoE FAME for financial support.