Martyn Pillinger

Investigador Principal

Perfil biográfico

Qualificacões académicas

1994: PhD Química no grupo do Professor John Evans, Universidade de Southampton, Inglaterra - "EXAFS studies of polyoxometalates and polyoxometalate-anion-pillared layered double hydroxides"
1990: BSc Química (Classe 1), Universidade de Southampton, Inglaterra

Actividades anteriores

2008-2015: Investigador Auxiliar no CICECO
2007-2008: Investigador Auxiliar no Instituto de Engenharia Electrónica e Telemática de Aveiro, Aveiro, Portugal
2002-2007: Investigador Auxiliar no CICECO
1999-2002: Investigador pós-doutoramento no grupo do Prof. Dr. João Rocha, Departamento de Química, Universidade de Aveiro (UA), Portugal (bolsas da UA e FCT)
1996-1999: Investigador pós-doutoramento no grupo do Prof. Alan Dyer, Chemistry Division, Science Research Institute, Universidade de Salford, Inglaterra (EU Framework 4 Nuclear Fission Safety Program - Partitioning Experiments and Waste Minimisation - "Waste Volume Minimisation Using Highly Selective Inorganic Ion Exchange Materials")
1994-1995: Investigador pós-doutoramento no grupo do Prof. Dr. Carlos C. Romão, Instituto de Tecnologia Química e Biológica, Oeiras, Portugal (TMR Programme - Selective Processes and Catalysis Involving Small Molecules - "Syntheses and Chemistry of Organotransition Metal Oxides")

Interesses científicos

LDH + ferrocenecarboxylate anionsMartyn’s research mainly involves the synthesis and chemistry of inorganic/organometallic hybrid and composite materials with interesting photofunctional, biofunctional and/or catalytic properties. A recurring theme has been organometallic inclusion and intercalation chemistry employing, for example, ordered mesoporous materials, cyclodextrins and layered double hydroxides as hosts (some examples are given on this page). To fully understand these systems it has been crucial to use multiple analysis techniques, e.g. X-ray absorption spectroscopy and powder X-ray diffraction. These studies have been and continue to be performed in close collaboration with colleagues at CICECO and other Portuguese institutions. Other collaborative research interests include the synthesis and characterization of molecular and hybrid molybdenum oxide-based catalysts for oxidation reactions, and solid acid catalysts for biomass conversion.

Ln complexes immobilized in MCM-41

Grupo de Investigação

Present

Investigadores de pós-doutoramento: Margarida Antunes (bolsa FCT, co-orientação com a Dr.ª Anabela A. Valente), Ana Catarina Costa Gomes Alves (bolsa FCT, co-orientação com a Dr.ª Isabel S. Gonçalves).

Previous

Estudantes de Doutoramento: Ana Sofia Vagueiro de Sousa Dias (2007, co-orientação com a Dr.ª Anabela A. Valente), Bernardo Ramos Batista Monteiro (2009, co-orientação com a Dr.ª Isabel S. Gonçalves), Maria Margarida Feitor Pintão Moreno Antunes (2012, co-orientação com a Dr.ª Anabela A. Valente).
Estudantes de Mestrado: Joana Leão Candeias (2012, co-orientação com a Dr.ª Anabela A. Valente), Joana Helena Aguiar de Almeida Pinho Abrantes (2014, co-orientação com a Dr.ª Anabela A. Valente), Clara Isabel Ribeiro Magalhães (2015, co-orientação com a Dr.ª Isabel S. Gonçalves).
Investigadores de pós-doutoramento: Ana Sofia Madureira Bruno (2009-2015, co-orientação com a Dr.ª Anabela A. Valente), Sérgio Nuno Martins Lima (2005-2012, co-orientação com a Dr.ª Anabela A. Valente), Sandra Maria Nunes Gago (2006-2010), Ana Catarina Costa Gomes (2010, co-orientação com a Dr.ª Isabel S. Gonçalves), Carlos Granadeiro (2016-2018, co-orientação com a Dr.ª Salete S. Balula (Universidade de Porto)).

Principais colaboradores

Aveiro (CICECO): Isabel S. Gonçalves, Anabela A. Valente, Patrícia Neves, Ana Luísa Costa, Filipe A. Almeida Paz.
Portugal: Carlos C. Romão (ITQB), André D. Lopes (Universidade do Algarve), Prof. Sérgio Seixas de Melo (Universidade de Coimbra), Salete Balula and Luís Cunha Silva (Universidade de Porto).
Alan Dyer (Universidade de Salford, UK).
Fritz E. Kühn (TU Munich).

Projectos financiados

Investigador responsável do projeto SASCOT "Sistemas ativados por estímulos para a terapia com monóxido de carbono" (CENTRO-01-0145-FEDER-028031; 1/5/2018-30/4/2021).

pocentro_pt2020_feder_bom_500px.jpg

Participante no projeto HyLight "Desenvolvimento Inteligente de Emissores de Luz Branca Energeticamente Eficientes Baseados em Híbridos Orgânicos-Inorgânicos" (Instituição Proponente = Universidade de Coimbra; POCI-01-0145-FEDER-031625; 1/7/2018-30/6/2021).
Participante no projeto BiOle_AcidOxCat "Conversao catalitica de olefinas derivadas da biomassa" (Instituição Proponente = Universidade de Aveiro; POCI-01-0145-FEDER-030075; 26/7/2018-25/7/2021).

modelos_barras_fundos_v04_3logos_feder_500px.jpg

PTDC/QEQ-SUP/1906/2012 (participante; instituição proponente = Universidade de Aveiro): Catalisadores de metaloceno modificados por contentores moleculares.
PTDC/EQU-EQU/121677/2010 (participante; instituição proponente = Instituto de Ciências e Tecnologias Agrárias e Agro-Alimentares - Porto): Dessulfurização do gasóleo por processos heterogéneos de oxidação catalítica sustentáveis
CICECO-funded project (1/3/10-28/2/11, investigador responsável): Metal carbonyl intercalated anion exchangers as drug delivery systems
PTDC/QUI/71198/2006 (participante): Ansa-bridged Organorhenium(VII) oxides and their application as homogeneous and heterogeneous catalysts
POCI/CTM/58507/2004 (investigador responsável): Argilas aniónicas multifuncionais
POCI/QUI/56109/2004 (participante): New oxometal compounds with tailored catalytic properties
POCI/QUI/56112/2004 (participante): Conversão catalítica de sacarídeos em aldeídos furânicos
POCTI/QUI/37990/2001 (participante): Tailored oxomolybdenum catalysts
POCTI/QUI/32889/99 (participante): Heterogenisation of photochemically and catalytically active transition metal complexes on mesoporous oxides

Publicações seleccionadas

223 publicações em revistas internacionais com arbitragem científica, w-index 9, h-index 46

Top three cited papers (12/03/2019):

(195 citações) Octahedral Bipyridine and Bipyrimidine Dioxomolybdenum(VI) Complexes: Characterization, Application in Catalytic Epoxidation, and Density Functional Mechanistic Study, F. E. Kühn, M. Groarke, É. Bencze, E. Herdtweck, A. Prazeres, A. M. Santos, M. J. Calhorda, C. C. Romão, I. S. Gonçalves, A. D. Lopes, M. Pillinger, Chem. Eur. J., 2002, 8, 2370. Link

(226 citações) Dehydration of xylose into furfural over micro-mesoporous sulfonic acid catalysts, A.S. Dias, M. Pillinger, A.A. Valente, J. Catal., 2005, 229, 414. Link

(168 citações) Conversion of mono/di/polysaccharides into furan compounds using 1-alkyl-3-methylimidazolium ionic liquids, S. Lima, P. Neves, M. M. Antunes, M. Pillinger, N. Ignatyev, A. A. Valente, Appl. Catal. A: Gen., 2009, 363, 93-99. Link

Layered double hydroxides

LDH+IC+HS1) An Indigo Carmine-Based Hybrid Nanocomposite with Supramolecular Control of Dye Aggregation and Photobehavior, A.L. Costa, A.C. Gomes, M. Pillinger, I.S. Gonçalves, J.S. Seixas de Melo, Chem. Eur. J., 2015, DOI: 10.1002/chem.201501344. Link

Tune into the blues: Zn-Al layered double hydroxides (LDHs) containing solely indigo carmine (IC) or 1-hexanesulfonate (HS) anions, or a mixture of the two with different HS/IC molar ratios, were prepared by the direct synthesis method. For the LDH containing solely IC anions, the dye molecules assembled within the interlayer galleries to form a J-type stacking arrangement. Through a comprehensive electronic spectral and photophysical study it was shown that incorporation of IC within the LDH decreased the level of aggregation, and that further addition of HS induced the appearance of isolated IC units within the LDH galleries. The indigo carmine-based nanocomposites constitute a step-forward in the design of hybrid materials with tunable properties.


2) Controlling the Fluorescence Behavior of 1-Pyrenesulfonate by Cointercalation with a Surfactant in a Layered Double Hydroxide, A.L. Costa, A.C. Gomes, M. Pillinger, I.S. Gonçalves, J.S. Seixas de Melo, Langmuir, 2015, 31, 4769. Link
PS/HS cointercalated LDH (Ref. 1)
3) Intercalation of a Molybdenum η3-Allyl Dicarbonyl Complex in a Layered Double Hydroxide and Catalytic Performance in Olefin Epoxidation, A. C. Gomes, S. M. Bruno, C. A. Gamelas, A. A. Valente, M. Abrantes, I. S. Gonçalves, C. C. Romão, M. Pillinger, Dalton Trans, 2013, 42, 8231. Link

4) Intercalation of a Molybdenum(0)-Tetracarbonyl-Bipyridine Complex in a Layered Double Hydroxide, A. C. Gomes, S. M. Bruno, A. A. Valente, I. S. Gonçalves, M. Pillinger, J. Organomet. Chem., 2013, 744, 53. Link
Intercalated LDHs (refs. 2 and 3)5) Preparation and photophysical characterisation of Zn-Al layered double hydroxides intercalated by anionic pyrene derivatives, S. Gago, T. Costa, J. Seixas de Melo, I. S. Gonçalves, M. Pillinger, J. Mater. Chem., 2008, 18, 894. Link

6) Investigation of layered double hydroxides intercalated by oxomolybdenum catecholate complexes, B. Monteiro, S. Gago, F. A. Almeida Paz, R. Bilsborrow, I. S. Gonçalves, M. Pillinger, Inorg. Chem., 2008, 47, 8674. Link
Intercalated LDHs (refs. 4 and 5)7) Immobilization of Oxomolybdenum Species in a Layered Double Hydroxide Pillared by 2,2'-Bipyridine-5,5'-Dicarboxylate Anions, S. Gago, M. Pillinger, A. A. Valente, T. M. Santos, J. Rocha, I. S. Gonçalves, Inorg. Chem., 2004, 43, 5422. Link

8) Immobilization of Lanthanide Ions in a Pillared Layered Double Hydroxide, S. Gago, M. Pillinger, R. A. Sá Ferreira, L. D. Carlos, T. M. Santos, I. S. Gonçalves, Chem. Mater., 2005, 17, 5803. Link
Intercalated LDH (ref. 7)Outras publicações

1) Desulfurization of model diesel by extraction/oxidation using a zinc-substituted polyoxometalate as catalyst under homogeneous and heterogeneous (MIL-101(Cr) encapsulated) conditions, D. Julião, A.C. Gomes, M. Pillinger, L. Cunha-Silva, B. de Castro, I.S. Gonçalves, S.S. Balula, Fuel Processing Technology, 2015, 131, 78. Link

2) Investigation of a dichlorodioxomolybdenum(VI)-pyrazolylpyridine complex and a hybrid derivative as catalysts in olefin epoxidation, T.R. Amarante, P. Neves, F.A.A. Paz, A.A. Valente, M. Pillinger, I.S. Gonçalves, Dalton Trans., 2014, 43, 6059. Link

3) Hydrothermal Synthesis, Crystal Structure and Catalytic Potential of a One-Dimensional Molybdenum Oxide/Bipyridinedicarboxylate Hybrid, T. R. Amarante, P. Neves, A. A. Valente, F. A. A. Paz, A. N. Fitch, M. Pillinger, I. S. Gonçalves, Inorg. Chem., 2013, 52, 4618. Link

4) Catalytic Cyclodehydration of Xylose to Furfural in the Presence of Zeolite H-Beta and a Micro/Mesoporous Beta/TUD-1 Composite Material, S. Lima, M. M. Antunes, A. Fernandes, M. Pillinger, M. F. Ribeiro, A. A. Valente, Appl. Catal. A: Gen., 2010, 388, 141. Link

5) Grafting of molecularly ordered mesoporous phenylene-silica with molybdenum carbonyl complexes: Efficient heterogeneous catalysts for the epoxidation of olefins, A. C. Coelho, S. S. Balula, S. M. Bruno, J. C. Alonso, N. Bion, P. Ferreira, M. Pillinger, A. A. Valente, J. Rocha, I. S. Gonçalves, Adv. Synth. Catal., 2010, 352, 1759. Link

6) Investigation of molybdenum tetracarbonyl complexes as precursors to MoVI catalysts for the epoxidation of olefins, T. R. Amarante, P. Neves, A. C. Coelho, S. Gago, A. A. Valente, F. A. A. Paz, M. Pillinger, I. S. Gonçalves, Organometallics, 2010, 29, 883. Link

7) Influence of Cyclodextrins on Catalytic Olefin Epoxidation with Metal Carbonyl Compounds. Crystal Structure of the TRIMEB Complex with CpFe(CO)2Cl, S. S. Balula, A. C. Coelho, S. S. Braga, A. Hazell, A. A. Valente, M. Pillinger, J. D. Seixas, C. C. Romão, I. S. Gonçalves, Organometallics, 2007, 26, 6857. Link

8) Immobilisation of rhodium acetonitrile complexes in ordered mesoporous silica, M. Pillinger, C. D. Nunes, P. D. Vaz, A. A. Valente, I. S. Gonçalves, P. J. A. Ribeiro-Claro, J. Rocha, L. D. Carlos, F. E. Kühn, Phys. Chem. Chem. Phys., 2002, 4, 3098. Link

9) Sorption behaviour of radionuclides on crystalline synthetic tunnel manganese oxides, A. Dyer, M. Pillinger, J. A. Newton, R. Harjula, T. Möller, S. Amin, Chem. Mater., 2000, 12, 3798. Link

10) Ion exchange of caesium and strontium on a titanosilicate analogue of the mineral pharmacosiderite, A. Dyer, M. Pillinger, S. Amin, J. Mater. Chem., 1999, 9, 2481. Link

Projectos

Argilas aniónicas multifuncionais (POCI/CTM/58507/2004)

CoordenadorFundação para a Ciência e a Tecnologia
Hidróxidos duplos lamelares Intercalação Sistemas hóspede-hospedeiro Catálise heterogénea

Catalisadores de metaloceno modificados por contentores moleculares (PTDC/QEQ-SUP/1906/2012)

ParticipanteFundação para a Ciência e a Tecnologia
Metalocenos Química hóspede-hospedeiro Contentores moleculares Transformações orgânicas

Conversao catalitica de olefinas derivadas da biomassa (BiOle_AcidOxCat)

ParticipanteFundação para a Ciência e a Tecnologia

Conversão catalítica de sacarídeos em aldeídos furânicos (POCI/QUI/56112/2004)

ParticipanteFundação para a Ciência e a Tecnologia
sacarídeos furfural catálise heterogénea ácidos sólidos

Desenvolvimento Inteligente de Emissores de Luz Branca Energeticamente Eficientes Baseados em Hibridos Organicos-Inorganicos (HyLight)

ParticipanteFundação para a Ciência e a Tecnologia

Dessulfurização do gasóleo por processos heterogéneos de oxidação catalítica sustentáveis (PTDC/EQU-EQU/121677/2010)

ParticipanteFundação para a Ciência e a Tecnologia
Desulfurization Heterogeneous catalysis Sulfoxidation Green oxidants

Novos compostos oxometálicos com propriedades catlíticas melhoradas (POCI/QUI/56109/2004)

ParticipanteFundação para a Ciência e a Tecnologia
Complexos oxometálicos Híbridos orgânicos-inorgânicos Mecanismos reaccionais Catálise oxidativa

Óxidos de organorénio (VII) com ligandos-ansa e as suas aplicações como catalisadores homogéneos e heterogéneos (PTDC/QUI/71198/2006)

ParticipanteFundação para a Ciência e a Tecnologia
catálise quiralidade rénio novos materiais

Sistemas ativados por estímulos para a terapia com monóxido de carbono (SASCOT)

ParticipanteFundação para a Ciência e a Tecnologia

Publicações

Intercalation of (eta(5)-Pentamethylcyclopentadienyl)trioxomolybdenum(VI) in a Layered Double Hydroxide

Gomes, AC; Neves, P; Gago, S; Valente, AA; Goncalves, IS; Pillinger, M
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 25, 2408-2416.
ISBN: 1099-0682

A sustainable peroxophosphomolybdate/H2O2 system for the oxidative removal of organosulfur compounds from simulated and real high-sulfur diesels

Juliao, D; Gomes, AC; Cunha-Silva, L; Valenca, R; Ribeiro, JC; Pillinger, M; de Castro, B; Goncalves, IS; Balula, SS
2020, APPLIED CATALYSIS A-GENERAL, 589.
ISBN: 1873-3875

Desulfurization of model and real fuels by extraction and oxidation processes using an indenylmolybdenum tricarbonyl pre-catalyst

Juliao, D; Gomes, AC; Pillinger, M; Valenca, R; Ribeiro, JC; Goncalves, IS; Balula, SS
2020, APPLIED ORGANOMETALLIC CHEMISTRY, 34, 4.
ISBN: 1099-0739

Evaluation of the supramolecular interaction of Congo red with cucurbiturils using mass spectrometry and spectroscopic methods

Costa, AL; Gomes, AC; Lopes, AD; Da Silva, JP; Pillinger, M; Goncalves, IS; de Melo, JSS
2020, NEW JOURNAL OF CHEMISTRY, 44, 6, 2587-2596.
ISBN: 1369-9261

One-Pot Intercalation Strategy for the Encapsulation of a CO-Releasing Organometallic Molecule in a Layered Double Hydroxide

Calhau, IB; Gomes, AC; Bruno, SM; Coelho, AC; Magalhaes, CIR; Romao, CC; Valente, AA; Goncalves, IS; Pillinger, M
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 28, 2726-2736.
ISBN: 1099-0682

Optimized preparation and regeneration of MFI type base catalysts for d-glucose isomerization in water

Antunes, MM; Fernandes, A; Falcao, D; Pillinger, M; Ribeiro, F; Valente, AA
2020, CATALYSIS SCIENCE & TECHNOLOGY, 10, 10, 3232-3246.
ISBN: 2044-4761

Deep oxidative desulfurization of diesel fuels using homogeneous and SBA-15-supported peroxophosphotungstate catalysts

Juliao, D; Mirante, F; Ribeiro, SO; Gomes, AC; Valenca, R; Ribeiro, JC; Pillinger, M; de Castro, B; Goncalves, IS; Balula, SS
2019, FUEL, 241, 616-624.
ISBN: 1873-7153

One-pot hydrogen production and cascade reaction of furfural to bioproducts over bimetallic Pd-Ni TUD-1 type mesoporous catalysts (vol 237, pg 521, 2018)

Antunes, MM; Lima, S; Fernandes, A; Ribeiro, MF; Chadwick, D; Hellgardt, K; Pillinger, M; Valente, AA
2019, APPLIED CATALYSIS B-ENVIRONMENTAL, 243, 801-801.
ISBN: 1873-3883

Mesoporous nanosilica-supported polyoxomolybdate as catalysts for sustainable desulfurization

Mirante, F; Gomes, N; Branco, LC; Cunha-Silva, L; Almeida, PL; Pillinger, M; Gago, S; Granadeiro, CM; Balula, SS
2019, MICROPOROUS AND MESOPOROUS MATERIALS, 275, 163-171.
ISBN: 1873-3093

A Comparative Study of Molybdenum Carbonyl and Oxomolybdenum Derivatives Bearing 1,2,3-Triazole or 1,2,4-Triazole in Catalytic Olefin Epoxidation

Nogueira, LS; Neves, P; Gomes, AC; Amarante, TA; Paz, FAA; Valente, AA; Goncalves, IS; Pillinger, M
2019, MOLECULES, 24, 1.

Efficient Isomerization of alpha-Pinene Oxide to Campholenic Aldehyde Promoted by a Mixed-Ring Analogue of Molybdenocene

Bruno, SM; Valente, AA; Pillinger, M; Arnelse, J; Romao, CC; Goncalves, IS
2019, ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 7, 16, 13639-13645.

A hydrogen-bonded assembly of cucurbit[6]uril and [MoO2Cl2(H2O)(2)] with catalytic efficacy for the one-pot conversion of olefins to alkoxy products

Nogueira, LS; Antunes, MM; Gomes, AC; Cunha-Silva, L; Pillinger, M; Lopes, AD; Valente, AA; Goncalves, IS
2019, DALTON TRANSACTIONS, 48, 30, 11508-11519.
ISBN: 1477-9234

Dichlorodioxomolybdenum(VI) complexes bearing oxygen-donor ligands as catalysts for oxidative desulfurization of simulated and real diesel

Juliao, D; Gomes, AC; Cunha-Silva, L; Pillinger, M; Lopes, AD; Valenca, R; Ribeiro, JC; Goncalves, IS; Balula, SS
2019, CATALYSIS COMMUNICATIONS, 128.
ISBN: 1873-3905

A Molybdenum Trioxide Hybrid Decorated by 3-(1,2,4-Triazol-4-yl)adamantane-1-carboxylic Acid: A Promising Reaction-Induced Self-Separating (RISS) Catalyst

Lysenko, AB; Senchyk, GA; Domasevitch, KV; Henfling, S; Erhart, O; Krautscheid, H; Neves, P; Valente, AA; Pillinger, M; Goncalves, IS
2019, INORGANIC CHEMISTRY, 58, 24, 16424-16433.
ISBN: 1520-510X

Performance of chiral tetracarbonylmolybdenum pyrindanyl amine complexes in catalytic olefin epoxidation

Neves, P; Nogueira, LS; Valente, AA; Pillinger, M; Goncalves, IS; Sampaio-Dias, IE; Sousa, CAD; Rizzo-Aguiar, F; Rodriguez-Borges, JE
2018, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 858, 29-36.

Acid-catalyzed epoxide alcoholysis in the presence of indenyl molybdenum carbonyl complexes

Bruno, SM; Goncalves, IS; Pillinger, M; Romao, CC; Valente, AA
2018, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 855, 12-17.

Interactions and Supramolecular Organization of Sulfonated Indigo and Thioindigo Dyes in Layered Hydroxide Hosts

Costa, AL; Gomes, AC; Pereira, RC; Pillinger, M; Goncalves, IS; Pineiro, M; de Melo, JSS
2018, LANGMUIR, 34, 1, 453-464.

[MoO3(2,2'-bipy)](n) catalyzed oxidation of amines and sulfides

Tosi, I; Vurchio, C; Abrantes, M; Goncalves, IS; Pillinger, M; Cavani, F; Cordero, FM; Brandi, A
2018, CATALYSIS COMMUNICATIONS, 103, 60-64.

Desulfurization of liquid fuels by extraction and sulfoxidation using H2O2 and [CpMo(CO)(3)R] as catalysts

Juliao, D; Gomes, AC; Pillinger, M; Valenca, R; Ribeiro, JC; Goncalves, IS; Balula, SS
2018, APPLIED CATALYSIS B-ENVIRONMENTAL, 230, 177-183.

Molybdenum(0) tricarbonyl and tetracarbonyl complexes with a cationic pyrazolylpyridine ligand: synthesis, crystal structures and catalytic performance in olefin epoxidation

Nogueira, LS; Neves, P; Gomes, AC; Lavrador, P; Cunha-Silva, L; Valente, AA; Goncalves, IS; Pillinger, M
2018, RSC ADVANCES, 8, 29, 16294-16302.

An Organotin Vanadate with Sodalite Topology and Catalytic Versatility in Oxidative Transformations

Gomes, AC; Antunes, MM; Abrantes, M; Valente, AA; Paz, FAA; Goncalves, IS; Pillinger, M
2018, CHEMCATCHEM, 10, 16, 3481-3489.

Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts

Granadeiro, CM; Ferreira, PMC; Juliao, D; Ribeiro, LA; Valenca, R; Ribeiro, JC; Goncalves, IS; de Castro, B; Pillinger, M; Cunha-Silva, L; Balula, SS
2018, ENERGIES, 11, 7.

High-yield synthesis and catalytic response of chainlike hybrid materials of the [(MoO3)(m)(2,2 '-bipyridine)(n)] family

Bruno, SM; Nogueira, LS; Gomes, AC; Valente, AA; Goncalves, IS; Pillinger, M
2018, NEW JOURNAL OF CHEMISTRY, 42, 20, 16483-16492.

One-pot hydrogen production and cascade reaction of furfural to bioproducts over bimetallic Pd-Ni TUD-1 type mesoporous catalysts

Antunes, MM; Lima, S; Fernandes, A; Ribeiro, MF; Chadwick, D; Hellgardt, K; Pillinger, M; Valente, AA
2018, APPLIED CATALYSIS B-ENVIRONMENTAL, 237, 521-537.

A Linear Trinuclear Oxidodiperoxido-molybdenum(VI) Complex with Single Triazole Bridges: Catalytic Activity in Epoxidation, Alcoholysis, and Acetalization Reactions

Antunes, MM; Amarante, TR; Valente, AA; Paz, FAA; Goncalves, IS; Pillinger, M
2018, CHEMCATCHEM, 10, 13, 2782-2791.

TUD-1 type aluminosilicate acid catalysts for 1-butene oligomerisation

Silva, AF; Fernandes, A; Antunes, MM; Neves, P; Rocha, SM; Ribeiro, MF; Pillinger, M; Ribeiro, J; Silva, CM; Valente, AA
2017, FUEL, 209, 371-382.

Insights into the Photophysics and Supramolecular Organization of Congo Red in Solution and the Solid State

Costa, AL; Gomes, AC; Pillinger, M; Goncalves, IS; Pina, J; de Melo, JSS
2017, CHEMPHYSCHEM, 18, 5, 564-575.

Ferrocene and ferrocenium inclusion compounds with cucurbiturils: a study of metal atom dynamics probed by Mossbauer spectroscopy

Magalhaes, CIR; Gomes, AC; Lopes, AD; Goncalves, IS; Pillinger, M; Jin, E; Kim, I; Ko, YH; Kim, K; Nowik, I; Herber, RH
2017, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 19, 32, 21548-21555.
ISBN: 1463-9084

Performance of a tetracarbonylmolybdenum(0) pyrazolylpyridine (pre) catalyst in olefin epoxidation and epoxide alcoholysis

Nogueira, LS; Neves, P; Gomes, AC; Valente, AA; Pillinger, M; Goncalves, IS
2017, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 846, 185-192.
ISBN: 1872-8561

MFI Acid Catalysts with Different Crystal Sizes and Porosity for the Conversion of Furanic Compounds in Alcohol Media

Antunes, MM; Lima, S; Fernandes, A; Magalhaes, AL; Neves, P; Silva, CM; Ribeiro, MF; Chadwick, D; Hellgardt, K; Pillinger, M; Valente, AA
2017, CHEMCATCHEM, 9, 14, 2747-2759.
ISBN: 1867-3899

Synthesis, structure and catalytic olefin epoxidation activity of a dinuclear oxo-bridged oxodiperoxomolybdenum(VI) complex containing coordinated 4,4 '-bipyridinium

Neves, P; Gomes, AC; Paz, FAA; Valente, AA; Goncalves, IS; Pillinger, M
2017, MOLECULAR CATALYSIS, 432, 104-114.

Behavior of Triazolylmolybdenum(VI) Oxide Hybrids as Oxidation Catalysts with Hydrogen Peroxide

Neves, P; Lysenko, AB; Gomes, AC; Pillinger, M; Goncalves, IS; Valente, AA
2017, CATALYSIS LETTERS, 147, 5, 1133-1143.
ISBN: 1572-879X

Chemistry and Catalytic Performance of Pyridyl-Benzimidazole Oxidomolybdenum(VI) Compounds in (Bio)Olefin Epoxidation

Neves, P; Nogueira, LS; Gomes, AC; Oliveira, TSM; Lopes, AD; Valente, AA; Goncalves, IS; Pillinger, M
2017, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 19, 2617-2627.
ISBN: 1099-0682

Integrated reduction and acid-catalysed conversion of furfural in alcohol medium using Zr,Al-containing ordered micro/mesoporous silicates

Antunes, MM; Lima, S; Neves, P; Magalhaes, AL; Fazio, E; Neri, F; Pereira, MT; Silva, AF; Silva, CM; Rocha, SM; Pillinger, M; Urakawa, A; Valente, AA
2016, APPLIED CATALYSIS B-ENVIRONMENTAL, 182, 485-503.

Solid-state study of the structure and host-guest chemistry of cucurbituril-ferrocene inclusion complexes

Gomes, AC; Magalhaes, CIR; Oliveira, TSM; Lopes, AD; Goncalves, IS; Pillinger, M
2016, DALTON TRANSACTIONS, 45, 42, 17042-17052.

A recyclable ionic liquid-oxomolybdenum(VI) catalytic system for the oxidative desulfurization of model and real diesel fuel

Juliao, D; Gomes, AC; Pillinger, M; Valenca, R; Ribeiro, JC; Goncalves, IS; Balula, SS
2016, DALTON TRANSACTIONS, 45, 38, 15242-15248.

Bulk and composite catalysts combining BEA topology and mesoporosity for the valorisation of furfural

Antunes, MM; Neves, P; Fernandes, A; Lima, S; Silva, AF; Ribeiro, MF; Silva, CM; Pillinger, M; Valente, AA
2016, CATALYSIS SCIENCE & TECHNOLOGY, 6, 21, 7812-7829.

Catalytic alcoholysis of epoxides using metal-free cucurbituril-based solids

Bruno, SM; Gomes, AC; Oliveira, TSM; Antunes, MM; Lopes, AD; Valente, AA; Goncalves, IS; Pillinger, M
2016, ORGANIC & BIOMOLECULAR CHEMISTRY, 14, 16, 3873-3877.

Catalytic Application of an Octamolybdate Salt (H(3)biim)(4)[beta-Mo8O26] in Olefin Epoxidation (H(2)biim=2,2'-biimidazole)

Neves, P; Amarante, TR; Valente, AA; Pillinger, M; Goncalves, IS
2016, CATALYSIS LETTERS, 146, 4, 841-850.

Metal oxide-triazole hybrids as heterogeneous or reaction-induced self-separating catalysts

Amarante, TR; Neves, P; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2016, JOURNAL OF CATALYSIS, 340, 354-367.

Oxidomolybdenum complexes for acid catalysis using alcohols as solvents and reactants

Gomes, AC; Neves, P; Cunha-Silva, L; Valente, AA; Goncalves, IS; Pillinger, M
2016, CATALYSIS SCIENCE & TECHNOLOGY, 6, 13, 5207-5218.

Zinc-Substituted Polyoxotungstate@amino-MIL-101(Al) - An Efficient Catalyst for the Sustainable Desulfurization of Model and Real Diesels

Juliao, D; Gomes, AC; Pillinger, M; Valenca, R; Ribeiro, JC; de Castro, B; Goncalves, IS; Cunha Silva, L; Balula, SS
2016, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 32, 5114-5122.

Crystal structure and temperature-dependent luminescence of a heterotetranuclear sodium-europium(III) beta-diketonate complex

Bruno, SM; Ananias, D; Paz, FAA; Pillinger, M; Valente, AA; Carlos, LD; Goncalves, IS
2015, DALTON TRANSACTIONS, 44, 2, 488-492.

Ring-opening of epoxides promoted by organomolybdenum complexes of the type [eta(5)-C5H4R)mo(CO)(2)(773-C3H5)] and [(eta(5)-C5H5) Mo(CO)(3)(CH2R)]

Bruno, SM; Gomes, AC; Abrantes, M; Valente, AA; Pillinger, M; Goncalves, IS
2015, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 799-800, 179-183.

One-pot conversion of furfural to useful bio-products in the presence of a Sn,Al-containing zeolite beta catalyst prepared via post-synthesis routes

Antunes, MM; Lima, S; Neves, P; Magalhaes, AL; Fazio, E; Fernandes, A; Neri, F; Silva, CM; Rocha, SM; Eiro, MFR; Pillinger, M; Urakawa, A; Valente, AA
2015, JOURNAL OF CATALYSIS, 329, 522-537.

An Indigo Carmine-Based Hybrid Nanocomposite with Supramolecular Control of Dye Aggregation and Photobehavior

Costa, AL; Gomes, AC; Pillinger, M; Goncalves, IS; de Melo, JSS
2015, CHEMISTRY-A EUROPEAN JOURNAL, 21, 34, 12069-12078.

Crystal Structure and Catalytic Behavior in Olefin Epoxidation of a One-Dimensional Tungsten Oxide/Bipyridine Hybrid

Amarante, TR; Antunes, MM; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2015, INORGANIC CHEMISTRY, 54, 20, 9690-9703.

Incorporation of a dioxomolybdenum(VI) complex in a Zr-IV-based Metal-Organic Framework and its application in catalytic olefin epoxidation

Neves, P; Gomes, AC; Amarante, TR; Paz, FAA; Pillinger, M; Goncalves, IS; Valente, AA
2015, MICROPOROUS AND MESOPOROUS MATERIALS, 202, 106-114.

Catalytic isomerisation of alpha-pinene oxide in the presence of ETS-10 supported ferrocenium ions

Bruno, SM; Gomes, AC; Coelho, AC; Brandao, P; Valente, AA; Pillinger, M; Goncalves, IS
2015, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 791, 66-71.

Dichlorodioxomolybdenum(VI) complexes bearing oxygen-donor ligands as olefin epoxidation catalysts

Oliveira, TSM; Gomes, AC; Lopes, AD; Lourenco, JP; Paz, FAA; Pillinger, M; Goncalves, IS
2015, DALTON TRANSACTIONS, 44, 31, 14139-14148.

Desulfurization of model diesel by extraction/oxidation using a zinc-substituted polyoxometalate as catalyst under homogeneous and heterogeneous (MIL-101 (Cr) encapsulated) conditions

Juliao, D; Gomes, AC; Pillinger, M; Cunha-Silva, L; de Castro, B; Goncalves, IS; Balula, SS
2015, FUEL PROCESSING TECHNOLOGY, 131, 78-86.

Promotion of phosphoester hydrolysis by the Zr-IV-based metal-organic framework UiO-67

Nunes, P; Gomes, AC; Pillinger, M; Goncalves, IS; Abrantes, M
2015, MICROPOROUS AND MESOPOROUS MATERIALS, 208, 21-29.

Controlling the Fluorescence Behavior of 1-Pyrenesulfonate by Cointercalation with a Surfactant in a Layered Double Hydroxide

Costa, AL; Gomes, AC; Pillinger, M; Goncalves, IS; de Melo, JSS
2015, LANGMUIR, 31, 16, 4769-4778.

Use of Organomolybdenum Compounds for Promoted Hydrolysis of Phosphoester Bonds in Aqueous Media

Gomes, AC; Gamelas, CA; Fernandes, JA; Paz, FAA; Nunes, P; Pillinger, M; Goncalves, IS; Romao, CC; Abrantes, M
2014, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 23, 3681-3689.

Crystal Structure and Spectroscopic Studies of a Dimeric Europium( III) similar to- Diketonate Complex Containing [ 3-( 2-Pyridyl)-1-pyrazolyl] acetate

Coelho, AC; Gomes, AC; Fernandes, JA; Paz, FAA; Braga, SS; Rino, L; Pereira, L; Pillinger, M; Goncalves, IS
2014, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 8, 1284-1288.

Catalytic olefin epoxidation with a carboxylic acid-functionalized cyclopentadienyl molybdenum tricarbonyl complex

Gomes, AC; Bruno, SM; Abrantes, M; Magalhaes, CIR; Goncalves, IS; Valente, AA; Pillinger, M
2014, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 760, 205-211.

Post-synthetic modification of crystal-like periodic mesoporous phenylene-silica with ferrocenyl groups

Gomes, AC; Lourenco, MAO; Bruno, SM; Ferreira, P; Valente, AA; Pillinger, M; Goncalves, IS
2014, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 751, 501-507.

Solid acids with SO3H groups and tunable surface properties: versatile catalysts for biomass conversion

Russo, PA; Antunes, MM; Neves, P; Wiper, PV; Fazio, E; Neri, F; Barreca, F; Mafra, L; Pillinger, M; Pinna, N; Valente, AA
2014, JOURNAL OF MATERIALS CHEMISTRY A, 2, 30, 11813-11824.

Sulfonated Graphene Oxide as Effective Catalyst for Conversion of 5-( Hydroxymethyl)-2-furfural into Biofuels

Antunes, MM; Russo, PA; Wiper, PV; Veiga, JM; Pillinger, M; Mafra, L; Evtuguin, DV; Pinna, N; Valente, AA
2014, CHEMSUSCHEM, 7, 3, 804-812.

Mesoporous carbon-silica solid acid catalysts for producing useful bio-products within the sugar-platform of biorefineries

Russo, PA; Antunes, MM; Neves, P; Wiper, PV; Fazio, E; Neri, F; Barreca, F; Mafra, L; Pillinger, M; Pinna, N; Valente, AA
2014, GREEN CHEMISTRY, 16, 9, 4292-4305.

Mesoporous zirconia-based mixed oxides as versatile acid catalysts for producing bio-additives from furfuryl alcohol and glycerol

Neves, P; Russo, PA; Fernandes, A; Antunes, MM; Farinha, J; Pillinger, M; Ribeiro, MF; Castanheiro, JE; Valente, AA
2014, APPLIED CATALYSIS A-GENERAL, 487, 148-157.

Application of an indenyl molybdenum dicarbonyl complex in the isomerisation of alpha-pinene oxide to campholenic aldehyde

Bruno, SM; Gomes, AC; Gamelas, CA; Abrantes, M; Oliveira, MC; Valente, AA; Paz, FAA; Pillinger, M; Romao, CC; Goncalves, IS
2014, NEW JOURNAL OF CHEMISTRY, 38, 7, 3172-3180.

Synthesis, Structural Elucidation, and Catalytic Properties in Olefin Epoxidation of the Polymeric Hybrid Material [Mo3O9(2-[3(5)-Pyrazolyl]pyridine)](n)

Amarante, TR; Neves, P; Gomes, AC; Nolasco, MM; Ribeiro-Claro, P; Coelho, AC; Valente, AA; Paz, FAA; Smeets, S; McCusker, LB; Pillinger, M; Goncalves, IS
2014, INORGANIC CHEMISTRY, 53, 5, 2652-2665.

Investigation of a dichlorodioxomolybdenum(VI)-pyrazolylpyridine complex and a hybrid derivative as catalysts in olefin epoxidation

Amarante, TR; Neves, P; Paz, FAA; Valente, AA; Pillinger, M; Goncalves, IS
2014, DALTON TRANSACTIONS, 43, 16, 6059-6069.

Synthesis, Characterisation and Antiproliferative Studies of Allyl(dicarbonyl)(cyclopentadienyl)molybdenum Complexes and Cyclodextrin Inclusion Compounds

Braga, SS; Mokal, V; Paz, FAA; Pillinger, M; Branco, AF; Sardao, VA; Diogo, CV; Oliveira, PJ; Marques, MPM; Romao, CC; Goncalves, IS
2014, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 29, 5034-5045.

Promotion of phosphoester hydrolysis by MoO2Cl2L (L bipyridine derivatives, H2O, no ligand), MoO2(CH3)(2)L (L bipyridine derivatives) and related inorganice-organic hybrids in aqueous media

Gomes, AC; Pillinger, M; Nunes, P; Goncalves, IS; Abrantes, M
2014, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 760, 42-47.

Isomerization of alpha-pinene oxide in the presence of methyltrioxorhenium(VII)

Bruno, SM; Pillinger, M; Kuhn, FE; Goncalves, IS; Valente, AA
2013, CATALYSIS COMMUNICATIONS, 35, 40-44.

Bis(pyrazolyl)methanetetracarbonyl-molybdenum(0) as precursor to a molybdenum(VI) catalyst for olefin epoxidation

Figueiredo, S; Gomes, AC; Fernandes, JA; Paz, FAA; Lopes, AD; Lourenco, JP; Pillinger, M; Goncalves, IS
2013, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 723, 56-64.

Use of MoO2Cl2(DMF)(2) as a precursor for molybdate promoted hydrolysis of phosphoester bonds

Tome, CM; Oliveira, MC; Pillinger, M; Goncalves, IS; Abrantes, M
2013, DALTON TRANSACTIONS, 42, 11, 3901-3907.

A dinuclear oxo-bridged molybdenum(VI) complex containing a bidentate pyrazolylpyridine ligand: Structure, characterization and catalytic performance for olefin epoxidation

Amarante, TR; Gomes, AC; Neves, P; Paz, FAA; Valente, AA; Pillinger, M; Goncalves, IS
2013, INORGANIC CHEMISTRY COMMUNICATIONS, 32, 59-63.

Synthesis and characterization of CpMo(CO)(3)(CH2-pC(6)H(4)-CO2CH3) and its inclusion compounds with methylated cyclodextrins. Applications in olefin epoxidation catalysis

Gomes, AC; Bruno, SM; Tome, C; Valente, AA; Pillinger, M; Abrantes, M; Goncalves, IS
2013, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 730, 116-122.

Hydrothermal Synthesis, Crystal Structure, and Catalytic Potential of a One-Dimensional Molybdenum Oxide/Bipyridinedicarboxylate Hybrid

Amarante, TR; Neves, P; Valente, AA; Paz, FAA; Fitch, AN; Pillinger, M; Goncalves, IS
2013, INORGANIC CHEMISTRY, 52, 8, 4618-4628.

Tris(pyrazolyl)methane molybdenum tricarbonyl complexes as catalyst precursors for olefin epoxidation

Gomes, AC; Neves, P; Figueiredo, S; Fernandes, JA; Valente, AA; Paz, FAA; Pillinger, M; Lopes, AD; Goncalves, IS
2013, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 370, 64-74.

Aqueous phase reactions of pentoses in the presence of nanocrystalline zeolite beta: Identification of by-products and kinetic modelling

Ferreira, LR; Lima, S; Neves, P; Antunes, MM; Rocha, SM; Pillinger, M; Portugal, I; Valente, AA
2013, CHEMICAL ENGINEERING JOURNAL, 215, 772-783.

Intercalation of a molybdenum eta(3)-allyl dicarbonyl complex in a layered double hydroxide and catalytic performance in olefin epoxidation

Gomes, AC; Bruno, SM; Gamelas, CA; Valente, AA; Abrantes, M; Goncalves, IS; Romao, CC; Pillinger, M
2013, DALTON TRANSACTIONS, 42, 23, 8231-8240.

Microwave-assisted coating of carbon nanostructures with titanium dioxide for the catalytic dehydration of D-xylose into furfural

Russo, PA; Lima, S; Rebuttini, V; Pillinger, M; Willinger, MG; Pinna, N; Valente, AA
2013, RSC ADVANCES, 3, 8, 2595-2603.

Conversion of furfuryl alcohol to ethyl levulinate using porous aluminosilicate acid catalysts

Neves, P; Lima, S; Pillinger, M; Rocha, SM; Rocha, J; Valente, AA
2013, CATALYSIS TODAY, 218, 76-84.

Production of biomass-derived furanic ethers and levulinate esters using heterogeneous acid catalysts

Neves, P; Antunes, MM; Russo, PA; Abrantes, JP; Lima, S; Fernandes, A; Pillinger, M; Rocha, SM; Ribeiro, MF; Valente, AA
2013, GREEN CHEMISTRY, 15, 12, 3367-3376.

Preparation of crystal-like periodic mesoporous phenylene-silica derivatized with ferrocene and its use as a catalyst for the oxidation of styrene

Gomes, AC; Ferreira, MJ; Bruno, SM; Bion, N; Ferreira, P; Valente, AA; Pillinger, M; Rocha, J; Goncalves, IS
2013, DALTON TRANSACTIONS, 42, 40, 14612-14620.

Catalytic oxidative desulfurization systems based on Keggin phosphotungstate and metal-organic framework MIL-101

Ribeiro, S; Barbosa, ADS; Gomes, AC; Pillinger, M; Goncalves, IS; Cunha-Silva, L; Balula, SS
2013, FUEL PROCESSING TECHNOLOGY, 116, 350-357.

Intercalation of a molybdenum(0)-tetracarbonyl-bipyridine complex in a layered double hydroxide

Gomes, AC; Bruno, SM; Valente, AA; Goncalves, IS; Pillinger, M
2013, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 744, 53-59.

Molybdenum(II) Diiodo-Tricarbonyl Complexes Containing Nitrogen Donor Ligands as Catalyst Precursors for the Epoxidation of Methyl Oleate

Gamelas, CA; Neves, P; Gomes, AC; Valente, AA; Romao, CC; Goncalves, IS; Pillinger, M
2012, CATALYSIS LETTERS, 142, 10, 1218-1224.

Aqueous-phase dehydration of xylose to furfural in the presence of MCM-22 and ITQ-2 solid acid catalysts

Antunes, MM; Lima, S; Fernandes, A; Pillinger, M; Ribeiro, MF; Valente, AA
2012, APPLIED CATALYSIS A-GENERAL, 417, 243-252.

Isomerisation of alpha-pinene oxide in the presence of indenyl allyl dicarbonyl molybdenum(II) and tungsten(II) complexes

Bruno, SM; Gamelas, CA; Gomes, AC; Valente, AA; Pillinger, M; Romao, CC; Goncalves, IS
2012, CATALYSIS COMMUNICATIONS, 23, 58-61.

Catalytic dehydration of D-xylose to 2-furfuraldehyde in the presence of Zr-(W,Al) mixed oxides. Tracing by-products using two-dimensional gas chromatography-time-of-flight mass spectrometry

Antunes, MM; Lima, S; Fernandes, A; Candeias, J; Pillinger, M; Rocha, SM; Ribeiro, MF; Valente, AA
2012, CATALYSIS TODAY, 195, 1, 127-135.

Epoxidation of olefins using a dichlorodioxomolybdenum(VI)-pyridylimine complex as catalyst

Balula, SS; Bruno, SM; Gomes, AC; Valente, AA; Pillinger, M; Goncalves, IS; Macquarrie, DJ; Clark, JH
2012, INORGANICA CHIMICA ACTA, 387, 234-239.

A dinuclear oxomolybdenum(VI) complex, [Mo2O6(4,4 '-di-tert-butyl-2,2 '-bipyridine)(2)], displaying the {MoO2(mu-O)(2)MoO2}(0) core, and its use as a catalyst in olefin epoxidation

Amarante, TR; Neves, P; Paz, FAA; Pillinger, M; Valente, AA; Goncalves, IS
2012, INORGANIC CHEMISTRY COMMUNICATIONS, 20, 147-152.

An Octanuclear Molybdenum(VI) Complex Containing Coordinative ly Bound 4,4 '-di-tert-Butyl-2,2 '-Bipyridine, [Mo8O22(OH)(4)(di-tBu-bipy)(4)]: Synthesis, Structure, and Catalytic Epoxidation of Bio-Derived Olefins

Amarante, TR; Neves, P; Tome, C; Abrantes, M; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2012, INORGANIC CHEMISTRY, 51, 6, 3666-3676.

Synthesis, Structural Elucidation, and Application of a Pyrazolylpyridine-Molybdenum Oxide Composite as a Heterogeneous Catalyst for Olefin Epoxidation

Figueiredo, S; Gomes, AC; Neves, P; Amarante, TR; Paz, FAA; Soares, R; Lopes, AD; Valente, AA; Pillinger, M; Goncalves, IS
2012, INORGANIC CHEMISTRY, 51, 15, 8629-8635.

Molybdenum(VI) catalysts obtained from eta(3)-allyl dicarbonyl precursors: Synthesis, characterization and catalytic performance in cyclooctene epoxidation

Gamelas, CA; Gomes, AC; Bruno, SM; Paz, FAA; Valente, AA; Pillinger, M; Romao, CC; Goncalves, IS
2012, DALTON TRANSACTIONS, 41, 12, 3474-3484.

A novel dinuclear MoVI complex with tris(3,5-dimethyl-1H-pyrazol-1-yl)methane

Gago, S; Gomes, AC; Cunha-Silva, L; Pillinger, M; Goncalves, IS; Paz, FAA
2012, ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 68, M73-M75.

Coupling of Nanoporous Chromium, Aluminium-Containing Silicates with an Ionic Liquid for the Transformation of Glucose into 5-(Hydroxymethyl)-2-furaldehyde

Antunes, MM; Lima, S; Pillinger, M; Valente, AA
2012, MOLECULES, 17, 4, 3690-3707.

Ionic Liquids as Tools for the Acid-Catalyzed Hydrolysis/Dehydration of Saccharides to Furanic Aldehydes

Lima, S; Antunes, MM; Pillinger, M; Valente, AA
2011, CHEMCATCHEM, 3, 11, 1686-1706.

Structural Studies and Cytotoxicity of Trimethyl(ferrocenylmethyl)ammonium Iodide Encapsulated in beta-Cyclodextrin

Bruno, SM; Fernandes, JA; Marques, J; Neto, SC; Ribeiro-Claro, PJ; Pillinger, M; Paz, FAA; Marques, MPM; Braga, SS; Goncalves, IS
2011, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 32, 4955-4963.

Oxidation of Ethylbenzene in the Presence of an MCM-41-Supported or Ionic Liquid-Standing Bischlorocopper(II) Complex

Gago, S; Bruno, SM; Queiros, DC; Valente, AA; Goncalves, IS; Pillinger, M
2011, CATALYSIS LETTERS, 141, 7, 1009-1017.

Heterogeneous oxidation catalysts formed in situ from molybdenum tetracarbonyl complexes and tert-butyl hydroperoxide

Neves, P; Amarante, TR; Gomes, AC; Coelho, AC; Gago, S; Pillinger, M; Goncalves, IS; Silva, CM; Valente, AA
2011, APPLIED CATALYSIS A-GENERAL, 395, 1-2, 71-77.

Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor

Abrantes, M; Bruno, SM; Tome, C; Pillinger, M; Goncalves, IS; Valente, AA
2011, CATALYSIS COMMUNICATIONS, 15, 1, 64-67.

Epoxidation of cyclooctene using soluble or MCM-41-supported molybdenum tetracarbonyl-pyridylimine complexes as catalyst precursors

Gomes, AC; Bruno, SM; Gago, S; Lopes, RP; Machado, DA; Carminatti, AP; Valente, AA; Pillinger, M; Goncalves, IS
2011, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 696, 22, 3543-3550.

Molybdenum oxide/bipyridine hybrid material {[MoO3(bipy)][MoO3(H2O)]}(n) as catalyst for the oxidation of secondary amines to nitrones

Abrantes, M; Goncalves, IS; Pillinger, M; Vurchio, C; Cordero, FM; Brandi, A
2011, TETRAHEDRON LETTERS, 52, 52, 7079-7082.

Chemistry and Catalytic Activity of Molybdenum(VI)-Pyrazolylpyridine Complexes in Olefin Epoxidation. Crystal Structures of Monomeric Dioxo, Dioxo-mu-oxo, and Oxodiperoxo Derivatives

Coelho, AC; Nolasco, M; Balula, SS; Antunes, MM; Pereira, CCL; Paz, FAA; Valente, AA; Pillinger, M; Ribeiro-Claro, P; Klinowski, J; Goncalves, IS
2011, INORGANIC CHEMISTRY, 50, 2, 525-538.

Synthesis and Catalytic Properties of Molybdenum(VI) Complexes with Tris(3,5-dimethyl-1-pyrazolyl)methane

Neves, P; Gago, S; Balula, SS; Lopes, AD; Valente, AA; Cunha-Silva, L; Paz, FAA; Pillinger, M; Rocha, J; Silva, CM; Goncalves, IS
2011, INORGANIC CHEMISTRY, 50, 8, 3490-3500.

Grafting of Molecularly Ordered Mesoporous Phenylene-Silica with Molybdenum Carbonyl Complexes: Efficient Heterogeneous Catalysts for the Epoxidation of Olefins

Coelho, AC; Balula, SS; Bruno, SM; Alonso, JC; Bion, N; Ferreira, P; Pillinger, M; Valente, AA; Rocha, J; Goncalves, IS
2010, ADVANCED SYNTHESIS & CATALYSIS, 352, 10, 1759-1769.

Dehydration of Xylose into Furfural in the Presence of Crystalline Microporous Silicoaluminophosphates

Lima, S; Fernandes, A; Antunes, MM; Pillinger, M; Ribeiro, F; Valente, AA
2010, CATALYSIS LETTERS, 135, 1-2, 41-47.

Catalytic olefin epoxidation with cationic molybdenum(VI) cis-dioxo complexes and ionic liquids

Gago, S; Balula, SS; Figueiredo, S; Lopes, AD; Valente, AA; Pillinger, M; Goncalves, IS
2010, APPLIED CATALYSIS A-GENERAL, 372, 1, 67-72.

Catalytic cyclodehydration of xylose to furfural in the presence of zeolite H-Beta and a micro/mesoporous Beta/TUD-1 composite material

Lima, S; Antunes, MM; Fernandes, A; Pillinger, M; Ribeiro, MF; Valente, AA
2010, APPLIED CATALYSIS A-GENERAL, 388, 1-2, 141-148.

Cyclopentadienyl molybdenum dicarbonyl eta(3)-allyl complexes as catalyst precursors for olefin epoxidation. Crystal structures of Cp ' Mo(CO)(2)(eta(3)-C3H5) (Cp ' = eta(5)-C5H4Me, eta(5)-C5Me5)

Neves, P; Pereira, CCL; Paz, FAA; Gago, S; Pillinger, M; Silva, CM; Valente, AA; Romao, CC; Goncalves, IS
2010, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 695, 21, 2311-2319.

Microwave-assisted molybdenum-catalysed epoxidation of olefins

Abrantes, M; Neves, P; Antunes, MM; Gago, S; Paz, FAA; Rodrigues, AE; Pillinger, M; Goncalves, IS; Silva, CM; Valente, AA
2010, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 320, 1-2, 19-26.

Complexation of crystal-like mesoporous phenylene-silica with Cr(CO)(3) and catalytic performance in the oxidation of cyclooctene

Coelho, AC; Balula, SS; Antunes, MM; Gerganova, TI; Bion, N; Ferreira, P; Pillinger, M; Valente, AA; Rocha, J; Goncalves, IS
2010, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 332, 1-2, 13-18.

Crystal and supramolecular structures of dioxomolybdenum(VI) and dioxotungsten(VI) complexes of dihydroxybenzoic acids

Monteiro, B; Cunha-Silva, L; Gago, S; Klinowski, J; Paz, FAA; Rocha, J; Goncalves, IS; Pillinger, M
2010, POLYHEDRON, 29, 2, 719-730.

Synthesis, Structure, and Catalytic Performance in Cyclooctene Epoxidation of a Molybdenum Oxide/Bipyridine Hybrid Material: {[MoO3(bipy)][MoO3(H2O)]}n

Abrantes, M; Amarante, TR; Antunes, MM; Gago, S; Paz, FAA; Margiolaki, I; Rodrigues, AE; Pillinger, M; Valente, AA; Goncalves, IS
2010, INORGANIC CHEMISTRY, 49, 15, 6865-6873.

Picosecond Dynamics of Dimer Formation in a Pyrene Labeled Polymer

Costa, T; de Melo, JSS; Castro, CS; Gago, S; Pillinger, M; Goncalves, IS
2010, JOURNAL OF PHYSICAL CHEMISTRY B, 114, 39, 12439-12447.

Investigation of Molybdenum Tetracarbonyl Complexes As Precursors to Mo-VI Catalysts for the Epoxidation of Olefins

Amarante, TR; Neves, P; Coelho, AC; Gago, S; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2010, ORGANOMETALLICS, 29, 4, 883-892.

Tetrapyridinium mu-oxido-di-mu-sulfato-bis[chloridodioxidomolybdate(VI)]

Fernandes, JA; Gomes, AC; Figueiredo, S; Gago, S; Lopes, AD; Pillinger, M; Ribeiro-Claro, PJA; Goncalves, IS; Paz, FAA
2010, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 66, M1005-U1354.

Acid-Catalysed Conversion of Saccharides into Furanic Aldehydes in the Presence of Three-Dimensional Mesoporous Al-TUD-1

Lima, S; Antunes, MM; Fernandes, A; Pillinger, M; Ribeiro, MF; Valente, AA
2010, MOLECULES, 15, 6, 3863-3877.

Synthesis and Catalytic Properties in Olefin Epoxidation of Octahedral Dichloridodioxidomolybdenum(VI) Complexes Bearing N,N-Dialkylamide Ligands: Crystal Structure of [Mo2O4(mu(2)-O)Cl-2(dmf)(4)]

Gago, S; Neves, P; Monteiro, B; Pessego, M; Lopes, AD; Valente, AA; Paz, FAA; Pillinger, M; Moreira, J; Silva, CM; Goncalves, IS
2009, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 29-30, 4528-4537.

Catalytic Epoxidation and Sulfoxidation Activity of a Dioxomolybdenum(VI) Complex Bearing a Chiral Tetradentate Oxazoline Ligand

Neves, P; Gago, S; Pereira, CCL; Figueiredo, S; Lemos, A; Lopes, AD; Goncalves, IS; Pillinger, M; Silva, CM; Valente, AA
2009, CATALYSIS LETTERS, 132, 1-2, 94-103.

Effect of an Ionic Liquid on the Catalytic Performance of Thiocyanatodioxomolybdenum(VI) Complexes for the Oxidation of Cyclooctene and Benzyl Alcohol

Monteiro, B; Gago, S; Neves, P; Valente, AA; Goncalves, IS; Pereira, CCL; Silva, CM; Pillinger, M
2009, CATALYSIS LETTERS, 129, 3-4, 350-357.

Conversion of mono/di/polysaccharides into furan compounds using 1-alkyl-3-methylimidazolium ionic liquids

Lima, S; Neves, P; Antunes, MM; Pillinger, M; Ignatyev, N; Valente, AA
2009, APPLIED CATALYSIS A-GENERAL, 363, 1-2, 93-99.

Amino acid-functionalized cyclopentadienyl molybdenum tricarbonyl complex and its use in catalytic olefin epoxidation

Abrantes, M; Paz, FAA; Valente, AA; Pereira, CCL; Gago, S; Rodrigues, AE; Klinowski, J; Pillinger, M; Goncalves, IS
2009, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 694, 12, 1826-1833.

Comparison of liquid-phase olefin epoxidation catalysed by dichlorobis-(dimethylformamide)dioxomolybdenum(VI) in homogeneous phase and grafted onto MCM-41

Monteiro, B; Balula, SS; Gago, S; Grosso, C; Figueiredo, S; Lopes, AD; Valente, AA; Pillinger, M; Lourenco, JP; Goncalves, IS
2009, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 297, 2, 110-117.

Liquid-phase oxidation catalysed by copper(II) immobilised in a pillared layered double hydroxide

Monteiro, B; Gago, S; Balula, SS; Valente, AA; Goncalves, IS; Pillinger, M
2009, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 312, 1-2, 23-30.

Structural and Photoluminescence Studies of a Europium(III) Tetrakis (beta-diketonate) Complex with Tetrabutylammonium, Imidazolium, Pyridinium and Silica-Supported Imidazolium Counterions

Bruno, SM; Ferreira, RAS; Paz, FAA; Carlos, LD; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2009, INORGANIC CHEMISTRY, 48, 11, 4882-4895.

Multi-functional rare-earth hybrid layered networks: photoluminescence and catalysis studies

Cunha-Silva, L; Lima, S; Ananias, D; Silva, P; Mafra, L; Carlos, LD; Pillinger, M; Valente, AA; Paz, FAA; Rocha, J
2009, JOURNAL OF MATERIALS CHEMISTRY, 19, 17, 2618-2632.

Heterometallic complexes involving iron(II) and rhenium(VII) centers connected by mu-oxido bridges

Goncalves, IS; Lopes, AD; Amarante, TR; Paz, FAA; Silva, NJO; Pillinger, M; Gago, S; Palacio, F; Kuhn, FE; Romao, CC
2009, DALTON TRANSACTIONS, 46, 10199-10207.

Microwave-Assisted Synthesis and Crystal Structure of Oxo(diperoxo)(4,4 '-di-tert-butyl-2,2 '-bipyridine)-molybdenum(VI)

Amarante, TR; Paz, FAA; Gago, S; Goncalves, IS; Pillinger, M; Rodrigues, AE; Abrantes, M
2009, MOLECULES, 14, 9, 3610-3620.

MCM-41 derivatised with pyridyl groups and its use as a support for luminescent europium(III) complexes

Bruno, SM; Coelho, AC; Ferreira, RAS; Carlos, LD; Pillinger, M; Valente, AA; Ribeiro-Claro, P; Goncalves, IS
2008, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 24, 3786-3795.

Isomerization of D-glucose to D-fructose over metallosilicate solid bases

Lima, S; Dias, AS; Lin, Z; Brandao, P; Ferreira, P; Pillinger, M; Rocha, J; Calvino-Casilda, V; Valente, AA
2008, APPLIED CATALYSIS A-GENERAL, 339, 1, 21-27.

Dehydration of D-xylose into furfural catalysed by solid acids derived from the layered zeolite Nu-6(1)

Lima, S; Pillinger, M; Valente, AA
2008, CATALYSIS COMMUNICATIONS, 9, 11-12, 2144-2148.

Synthesis, characterization and antitumor activity of 1,2-disubstituted ferrocenes and cyclodextrin inclusion complexes

Petrovski, Z; de Matos, MRPN; Braga, SS; Pereira, CCL; Matos, ML; Goncalves, IS; Pillinger, M; Alves, PM; Romao, CC
2008, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 693, 4, 675-684.

Synthesis, characterisation and luminescence properties of MCM-41 impregnated with an Eu3+ beta-diketonate complex

Bruno, SM; Ferreira, RAS; Carlos, LD; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2008, MICROPOROUS AND MESOPOROUS MATERIALS, 113, 1-3, 453-462.

Investigation of layered double hydroxides intercalated by oxomolybdenum catecholate complexes

Monteiro, B; Gago, S; Paz, FAA; Bilsborrow, R; Goncalves, IS; Pillinger, M
2008, INORGANIC CHEMISTRY, 47, 19, 8674-8686.

Complex formation between heptakis(2,6-di-O-methyl)-beta-cyclodextrin and cyclopentadienyl molybdenum(II) dicarbonyl complexes: Structural studies and cytotoxicity evaluations

Pereira, CCL; Diogo, CV; Burgeiro, A; Oliveira, PJ; Marques, MPM; Braga, SS; Paz, FAA; Pillinger, M; Goncalves, IS
2008, ORGANOMETALLICS, 27, 19, 4948-4956.

Preparation and photophysical characterisation of Zn-Allayered double hydroxides intercalated by anionic pyrene derivatives

Gago, S; Costa, T; de Melo, JS; Goncalves, IS; Pillinger, M
2008, JOURNAL OF MATERIALS CHEMISTRY, 18, 8, 894-904.

1-hydroxy-1,1,3,3,3-pentaphenyldisiloxane, [Si2O(OH)(Ph)(5)], at 100 K

Coelho, AC; Amarante, TR; Klinowski, J; Goncalves, IS; Paz, FAA
2008, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 64, O237-U4707.

Cyclodextrin encapsulation of biomimetic organometallic cancer drug candidates

Braga, SS; Paz, FAA; Mokal, V; Pillinger, M; Marques, MPM; Romao, CC; Goncalves, IS
2007, DRUGS OF THE FUTURE, 32, 101-101.

Characterization of a chiral menthyldimethyltin molybdate and its use as an olefin epoxidation catalyst

Abrantes, M; Valente, AA; Pillinger, M; Romao, CC; Goncalves, IS
2007, CATALYSIS LETTERS, 114, 1-2, 103-109.

Modified versions of sulfated zirconia as catalysts for the conversion of xylose to furfural

Dias, AS; Lima, S; Pillinger, M; Valente, AA
2007, CATALYSIS LETTERS, 114, 3-4, 151-160.

Structural and catalytic studies of a trimethyltin vanadate coordination polymer

Abrantes, M; Balula, MS; Valente, AA; Paz, FAA; Pillinger, M; Romao, CC; Rocha, J; Goncalves, IS
2007, JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 17, 1, 215-222.

Metatungstate and tungstoniobate-containing LDHs: Preparation, characterisation and activity in epoxidation of cyclooctene

Carriazo, D; Lima, S; Martin, C; Pillinger, M; Valente, AA; Rives, V
2007, JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 68, 10, 1872-1880.

New chloro and triphenylsiloxy derivatives of dioxomolybdenum(VI) chelated with pyrazolylpyridine ligands: Catalytic applications in olefin epoxidation

Bruno, SM; Pereira, CCL; Balula, MS; Nolasco, M; Valente, AA; Hazell, A; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2007, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 261, 1, 79-87.

Synthesis and catalytic properties in olefin epoxidation of dioxomolybdenurn(VI) complexes bearing a bidentate or tetradentate salen-type ligand

Bruno, SM; Balula, SS; Valente, AA; Paz, FAA; Pillinger, M; Sousa, C; Klinowski, J; Freire, C; Ribeiro-Claro, P; Goncalves, IS
2007, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 270, 1-2, 185-194.

A highly efficient dioxo(mu-oxo)molybdenum(VI) dimer catalyst for olefin epoxidation

Pereira, CCL; Balula, SS; Paz, FAA; Valente, AA; Pillinger, M; Klinowski, J; Goncalves, IS
2007, INORGANIC CHEMISTRY, 46, 21, 8508-8510.

A combined theoretical-experimental study of the inclusion of niobocene dichloride in native and permethylated beta-cyclodextrins

Pereira, CCL; Nolasco, M; Braga, SS; Almeida Paz, FA; Ribeiro-Claro, P; Pillinger, M; Goncalves, IS
2007, ORGANOMETALLICS, 26, 17, 4220-4228.

Influence of cyclodextrins on catalytic olefin epoxidation with metal-carbonyl compounds. Crystal structure of the TRIMEB complex with CpFe(CO)(2)Cl

Balula, SS; Coelho, AC; Braga, SS; Hazell, A; Valente, AA; Pillinger, M; Seixas, JD; Romao, CC; Goncalves, IS
2007, ORGANOMETALLICS, 26, 27, 6857-6863.

Redetermination of dipotassium mu-oxo-bis[aqua(oxalato-kappa O-2,O ') dioxomolybdate(VI)] at 150 K

Cunha-Silva, L; Monteiro, B; Pillinger, M; Goncalves, IS; Rocha, J; Paz, FAA
2007, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 63, M376-M378.

Structural studies of beta-cyclodextrin and permethylated beta-cyclodextrin inclusion compounds of cyclopentadienyl metal carbonyl complexes

Braga, SS; Paz, FAA; Pillinger, M; Seixas, JD; Romao, CC; Goncalves, IS
2006, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 8, 1662-1669.

Structural studies of [CpMoL2(CO)(2)](+) (L = NCMe, L-2 =,2,2 '-biimidazole) complexes and their inclusion compounds with cyclodextrins

Pereira, CCL; Braga, SS; Paz, FAA; Pillinger, M; Klinowski, J; Goncalves, IS
2006, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 21, 4278-4288.

Liquid-phase dehydration of D-xylose over microporous and mesoporous niobium silicates

Dias, AS; Lima, S; Brandao, P; Pillinger, M; Rocha, J; Valente, AA
2006, CATALYSIS LETTERS, 108, 3-4, 179-186.

Modification of the luminescence properties of an Europium(III) tris(beta-diketonate) complex by inclusion in gamma-cyclodextrin and 2,3,6-trimethyl-gamma-cyclodextrin

Fernandes, JA; Braga, SS; Ferreira, RAS; Pillinger, M; Carlos, LD; Ribeiro-Claro, P; Goncalves, IS
2006, JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 55, 3-4, 329-333.

Acidic cesium salts of 12-tungstophosphoric acid as catalysts for the dehydration of xylose into furfural

Dias, AS; Lima, S; Pillinger, M; Valente, AA
2006, CARBOHYDRATE RESEARCH, 341, 18, 2946-2953.

Dioxomolybdenum(VI) modified mesoporous materials for the catalytic epoxidation of olefins

Bruno, SM; Fernandes, JA; Martins, LS; Goncalves, IS; Pillinger, M; Ribeiro-Claro, P; Rocha, J; Valente, AA
2006, CATALYSIS TODAY, 114, 2-3, 263-271.

beta-cyclodextrin and permethylated beta-cyclodextrin inclusion compounds of a cyclopentadienyl molybdenum tricarbonyl complex and their use as cyclooctene epoxidation catalyst precursors

Braga, SS; Gago, S; Seixas, JD; Valente, AA; Pillinger, M; Santos, TM; Goncalves, IS; Romao, CC
2006, INORGANICA CHIMICA ACTA, 359, 15, 4757-4764.

Exfoliated titanate, niobate and titanoniobate nanosheets as solid acid catalysts for the liquid-phase dehydration of D-xylose into furfural

Dias, AS; Lima, S; Carriazo, D; Rives, V; Pillinger, M; Valente, AA
2006, JOURNAL OF CATALYSIS, 244, 2, 230-237.

Synthesis and characterization of layered double hydroxides intercalated by an oxomolybdenum complex

Gago, S; Dias, AS; Monteiro, B; Pillinger, M; Valente, AA; Santos, TM; Goncalves, IS
2006, JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 67, 5-6, 1011-1015.

Immobilisation of methyltrioxorhenium on functionalised MCM-41

Gago, S; Fernandes, JA; Abrantes, M; Kuhn, FE; Ribeiro-Claro, P; Pillinger, M; Santos, TM; Goncalves, IS
2006, MICROPOROUS AND MESOPOROUS MATERIALS, 89, 1-3, 284-290.

Mesoporous silica-supported 12-tungstophosphoric acid catalysts for the liquid phase dehydration of D-xylose

Dias, AS; Pillinger, M; Valente, AA
2006, MICROPOROUS AND MESOPOROUS MATERIALS, 94, 1-3, 214-225.

Molybdenum(VI) oxides bearing 1,4,7-triazacyclononane and 1,1,1-tris(aminomethyl)ethane ligands: Synthesis and catalytic applications

Petrovski, Z; Valente, AA; Pillinger, M; Dias, AS; Rodrigues, SS; Romao, CC; Goncalves, IS
2006, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 249, 1-2, 166-171.

Synthesis and catalytic properties in olefin epoxidation of chiral oxazoline dioxomolybdenum(VI) complexes

Bruno, SM; Monteiro, B; Balula, MS; Pedro, FM; Abrantes, M; Valente, AA; Pillinger, M; Ribeiro-Claro, P; Kuhn, FE; Goncalves, IS
2006, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 260, 1-2, 11-18.

beta-Cyclodextrin inclusion of europium(III) tris(beta-diketonate)-bipyridine

Fernandes, JA; Braga, SS; Pillinger, M; Ferreira, RAS; Carlos, LD; Hazell, A; Ribeiro-Claro, P; Goncalves, IS
2006, POLYHEDRON, 25, 6, 1471-1476.

Catalytic properties of the dioxomolybdenum siloxide MoO2(OSiPh3)(2) and its 2,2 '-bipyridine adduct MoO2(OSiPh3)(2)(bpy)

Bruno, SM; Monteiro, B; Balula, MS; Lourenco, C; Valente, AA; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2006, MOLECULES, 11, 4, 298-308.

Synthesis and structure of a sodium complex of an aromatic beta-diketone and pyrazolylpyridine

Coelho, AC; Paz, FAA; Klinowski, J; Pillinger, M; Goncalves, IS
2006, MOLECULES, 11, 7, 528-538.

Microwave assisted synthesis of molybdenum and tungsten tetracarbonyl complexes with a pyrazolylpyridine ligand. Crystal structure of cis-[Mo(CO)4{ethyl[3-(2-pyridyl)-1-pyrazolyl]acetate}]

Coelho, AC; Paz, FAA; Klinowski, J; Pillinger, M; Goncalves, IS
2006, MOLECULES, 11, 12, 940-952.

Luminescent polyoxotungstoeuropate anion-pillared layered double hydroxides

Sousa, FL; Pillinger, M; Ferreira, RAS; Granadeiro, CM; Cavaleiro, AMV; Rocha, J; Carlos, LD; Trindade, T; Nogueira, HIS
2006, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 4, 726-734.

Kinetics of cyclooctene epoxidation with tert-butyl hydroperoxide in the presence of [MoO2X2L]-type catalysts (L = bidentate Lewis base)

Al-Ajlouni, A; Valente, AA; Nunes, CD; Pillinger, M; Santos, AM; Zhao, J; Romao, CC; Goncalves, IS; Kuhn, FE
2005, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 9, 1716-1723.

Experimental and theoretical study of the encapsulation of a linear oligo(ferrocenylsilane) trimer with beta-cyclodextrin

Fernandes, JA; Lima, S; Braga, SS; Pillinger, M; Rodriguez-Borges, JE; Ribeiro-Claro, P; Teixeira-Dias, JJC; Goncalves, IS
2005, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 23, 4729-4734.

CpMo(CO)(3)Cl as a precatalyst for the epoxidation of olefins

Valente, AA; Seixas, JD; Goncalves, IS; Abrantes, M; Pillinger, M; Romao, CC
2005, CATALYSIS LETTERS, 101, 1-2, 127-130.

Liquid phase dehydration Of D-xylose in the presence of Keggin-type heteropolyacids

Dias, AS; Pillinger, M; Valente, AA
2005, APPLIED CATALYSIS A-GENERAL, 285, 1-2, 126-131.

Synthesis and characterization of the inclusion compound of a ferrocenyldiimine dioxomolybdenum complex with heptakis-2,3,6-tri-O-methyl-beta-cyclodextrin

Petrovski, Z; Braga, SS; Santos, AM; Rodrigues, SS; Goncalves, IS; Pillinger, M; Kuhn, FE; Romao, CC
2005, INORGANICA CHIMICA ACTA, 358, 4, 981-988.

Dehydration of xylose into furfural over micro-mesoporous sulfonic acid catalysts

Dias, AS; Pillinger, M; Valente, AA
2005, JOURNAL OF CATALYSIS, 229, 2, 414-423.

Investigation of europium(III) and gadolinium(III) complexes with naphthoyltrifluoroacetone and bidentate heterocyclic amines

Fernandes, JA; Ferreira, RAS; Pillinger, M; Carlos, LD; Jepsen, J; Hazell, A; Ribeiro-Claro, P; Goncalves, IS
2005, JOURNAL OF LUMINESCENCE, 113, 1-2, 50-63.

Inclusion of molybdenocene dichloride (Cp2MoCl2) in 2-hydroxypropyl- and trimethyl-beta-cyclodextrin: Structural and biological properties

Braga, SS; Marques, MPM; Sousa, JB; Pillinger, M; Teixeira-Dias, JJC; Goncalves, IS
2005, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690, 12, 2905-2912.

Inclusion complex formation of diferrocenyldimethylsilane with beta-cyclodextrin

Fernandes, JA; Lima, S; Braga, SS; Ribeiro-Claro, P; Rodriguez-Borges, JE; Teixeira, C; Pillinger, M; Teixeira-Dias, JJC; Goncalves, IS
2005, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690, 21-22, 4801-4808.

Preparation and catalytic studies of bis(halogeno) dioxomolybdenum(VI)-diimine complexes

Petrovski, Z; Pillinger, M; Valente, AA; Goncalves, IS; Hazell, A; Romao, CC
2005, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 227, 1-2, 67-73.

Synthesis, characterization and catalytic studies of bis(chloro)dioxomolybdenum(VI)-chiral diimine complexes

Gago, S; Rodriguez-Borges, JE; Teixeira, C; Santos, AM; Zhao, J; Pillinger, M; Nunes, CD; Petrovski, Z; Santos, TM; Kuhn, FE; Romao, CC; Goncalves, IS
2005, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 236, 1-2, 1-6.

Organotin-oxomolybdate coordination polymers as catalysts for the epoxidation of cyclooctene

Abrantes, M; Valente, AA; Goncalves, IS; Pillinger, M; Romao, CC
2005, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 238, 1-2, 51-55.

Immobilization of lanthanide ions in a pillared layered double hydroxide

Gago, S; Pillinger, M; Ferreira, RAS; Carlos, LD; Santos, TM; Goncalves, IS
2005, CHEMISTRY OF MATERIALS, 17, 23, 5803-5809.

Highly luminescent tris(beta-diketonate)europium(III) complexes immobilized in a functionalized mesoporous silica

Gago, S; Fernandes, JA; Rainho, JP; Ferreira, RAS; Pillinger, M; Valente, AA; Santos, TM; Carlos, LD; Ribeiro-Claro, PJA; Goncalves, IS
2005, CHEMISTRY OF MATERIALS, 17, 20, 5077-5084.

Inclusion complexation of dimeric and trimeric oligo(ferrocenyldimethylsilanes) with gamma-cyclodextrin

Fernandes, JA; Lima, S; Braga, SS; Pillinger, M; Ribeiro-Claro, P; Rodriguez-Borges, JE; Lopes, AD; Teixeira-Dias, JJC; Goncalves, IS
2005, ORGANOMETALLICS, 24, 23, 5673-5677.

Synthesis of ferrocenyldiimine metal carbonyl complexes and an investigation of the Mo adduct encapsulated in cyclodextrin

Petrovski, Z; Braga, SS; Rodrigues, SS; Pereira, CCL; Goncalves, IS; Pillinger, M; Freire, C; Ramao, CC
2005, NEW JOURNAL OF CHEMISTRY, 29, 2, 347-354.

Zn-Al layered double hydroxide pillared by different dicarboxylate anions

Gago, S; Pillinger, M; Santos, TM; Goncalves, IS
2004, CERAMICS-SILIKATY, 48, 4, 155-158.

Synthesis and properties of Zn-Al layered double hydroxides containing ferrocenecarboxylate anions

Gago, S; Pillinger, M; Santos, TM; Rocha, J; Goncalves, IS
2004, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 7, 1389-1395.

Spectroscopic studies of europium(III) and gadolinium(III) tris-beta-diketonate complexes with diazabutadiene ligands

Fernandes, JA; Ferreira, RAS; Pillinger, M; Carlos, LD; Goncalves, IS; Ribeiro-Claro, PJA
2004, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 19, 3913-3919.

Incorporation of a (cyclopentadienyl)molybdenum oxo complex in MCM-41 and its use as a catalyst for olefin epoxidation

Abrantes, M; Gago, S; Valente, AA; Pillinger, M; Goncalves, IS; Santos, TM; Rocha, J; Romao, CC
2004, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 24, 4914-4920.

Synthesis and characterization of a manganese(II) acetonitrile complex supported on functionalized MCM-41

Gago, S; Zhang, YM; Santos, AM; Kohler, K; Kuhn, FE; Fernandes, JA; Pillinger, M; Valente, AA; Santos, TM; Ribeiro-Claro, PJA; Goncalves, IS
2004, MICROPOROUS AND MESOPOROUS MATERIALS, 76, 1-3, 131-136.

Epoxidation of cyclooctene catalyzed by dioxomolybdenum(VI) complexes in ionic liquids

Valente, AA; Petrovski, Z; Branco, LC; Afonso, CAM; Pillinger, M; Lopes, AD; Romao, CC; Nunes, CD; Goncalves, IS
2004, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 218, 1, 5-11.

Immobilization of oxomolybdenum species in a layered double hydroxide pillared by 2,2 '-bipyridine-5,5 '-dicarboxylate anions

Gago, S; Pillinger, M; Valente, AA; Santos, TM; Rocha, J; Goncalves, IS
2004, INORGANIC CHEMISTRY, 43, 17, 5422-5431.

Dichloro and dimethyl dioxomolybdenum(VI)-diazabutadiene complexes as catalysts for the epoxidation of olefins

Valente, AA; Moreira, J; Lopes, AD; Pillinger, M; Nunes, CD; Romao, CC; Kuhn, FE; Goncalves, IS
2004, NEW JOURNAL OF CHEMISTRY, 28, 2, 308-313.

Preparation and characterization of organotin - Oxomolybdate coordination polymers and their use in sulfoxidation catalysis

Abrantes, M; Valente, AA; Pillinger, M; Goncalves, IS; Rocha, J; Romao, CC
2003, CHEMISTRY-A EUROPEAN JOURNAL, 9, 12, 2685-+.

Molecular structure - Activity relationships for the oxidation of organic compounds using mesoporous silica catalysts derivatised with bis(halogeno)dioxomolybdenum(VI) complexes

Nunes, CD; Valente, AA; Pillinger, M; Rocha, J; Goncalves, IS
2003, CHEMISTRY-A EUROPEAN JOURNAL, 9, 18, 4380-4390.

Dioxomolybdenum(VI)-modified mesoporous MCM-41 and MCM-48 materials for the catalytic epoxidation of olefins

Nunes, CD; Pillinger, M; Valente, AA; Rocha, J; Lopes, AD; Goncalves, IS
2003, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 21, 3870-3877.

Bimetallic transition metal-ruthenium(II) complexes containing bridging bipyrimidine ligands

Nunes, CD; Pillinger, M; Hazell, A; Jepsen, J; Santos, TM; Madureira, J; Lopes, AD; Goncalves, IS
2003, POLYHEDRON, 22, 20, 2799-2807.

Preparation and catalytic properties of a new dioxomolybdenum(VI) complex covalently anchored to mesoporous MCM-48

Nunes, CD; Pillinger, M; Valente, AA; Lopes, AD; Goncalves, IS
2003, INORGANIC CHEMISTRY COMMUNICATIONS, 6, 9, 1228-1233.

Interactions of omeprazole and precursors with beta-cyclodextrin host molecules

Braga, SS; Ribeiro-Claro, P; Pillinger, M; Goncalves, IS; Fernandes, AC; Pereira, F; Romao, CC; Correia, PB; Teixeira-Dias, JJC
2003, JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 47, 1-2, 47-52.

Encapsulation of sodium nimesulide and precursors in beta-cyclodextrin

Braga, SS; Ribeiro-Claro, P; Pillinger, M; Goncalves, IS; Pereira, F; Fernandes, AC; Romao, CC; Correia, PB; Teixeira-Dias, JJC
2003, ORGANIC & BIOMOLECULAR CHEMISTRY, 1, 5, 873-878.

Epoxidation of olefins catalyzed by molybdenum-siloxane compounds

Abrantes, M; Valente, AA; Pillinger, M; Goncalves, IS; Rocha, J; Romao, CC
2002, INORGANIC CHEMISTRY COMMUNICATIONS, 5, 12, 1069-1072.

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