Isabel Maria de Sousa Gonçalves

Professor associado

Perfil biográfico

A Isabel é Professora Associada do Departamento de Química da Universidade de Aveiro. Em 1996 doutorou-se no IST com uma dissertação sobre a síntese e a flexibilidade estrutural e electrónica de alguns metalocenos (Mo, W) com anéis mistos, sob a orientação do Prof. Carlos Romão. A Isabel publicou (ou tem aceites para publicação) ca. 265 artigos do SCI e 15 patentes. Participa com regularidade na arbitragem de artigos científicos (referee) de revistas da especialidade, nomeadamente: Angewandte Chemie; Chemistry - A European Journal; European Journal of Inorganic Chemistry; Organometallics; New Journal of Chemistry; Advanced Synthesis & Calalysis; Journal of Molecular Catalysis A: Chemical Nos tempos livres a Isabel gosta de estar com a família, os amigos e o Sócrates (Labrador completamente louco!). Quando anda mais desiludida com a ciência ainda consegue dedicar algum tempo à pintura.

Interesses científicos

Os interesses de investigação da Isabel incluem: 

* Novos sistemas catalíticos baseados em óxidos de molibdénio
* Interacções entre ciclodextrinas e diferentes classes de compostos; em particular sistemas orgânicos ou organometálicos com interesse farmacêutico

* Materiais híbridos orgânicos-inorgânicos: síntese e caracterização das propriedades catalíticas, ópticas ou magnéticas
* Extensão de alguns conceitos da química dos óxidos inorgânicos ou organometálicos à ciência dos materiais 
* Complexos polinucleares com centros metálicos em diferentes estados de oxidação 
* Propriedades catalíticas de complexos bimetálicos com ligações metal-metal estabilizados por moléculas de solvent.

Grupo de Investigação

Presentemente, o seu grupo inclui: 

Pós-Docs: Ana Catarina Gomes
Doutorandos: Cátia Tomé, Sónia Figueiredo

Doutorados no grupo: Carla D. Nunes (Dezembro 2003), José Alberto Fernandes (Janeiro 2006), Sandra Gago (Março 2006),  Bernardo Monteiro (Março 2009),  Sofia Bruno (Abril 2009), Ana Catarina Coelho (Outubro 2010), Tatiana Amarante (Dezembro 2013).

Pós-Docs anteriores: Susana S. Braga, Paula Ferreira, Cláudia Lage Pereira, Salete Balula e João Pina

Principais colaboradores

Portugal:

Aveiro - Profs João Rocha, Paulo Ribeiro Claro, Teresa M. Santos, Luís Carlos; – Dr´s Martyn Pillinger, Anabela A. Valente, Filipe A. Almeida Paz, Rute A. Sá Ferreira e Paula Ferreira. 

Lisboa – Profs Carlos Romão (ITQB) e  Maria J. Calhorda (FC)

Algarve – Prof André Lopes (UAlg) 

Porto - José Enrique Borges (UP) 

Coimbra - Prof. Sérgio Seixas de Melo (UC) 

Prof. Dr. K. Köhler, Dr. Fritz E. Kühn e Dr. Eberhardt Herdtweck TUM, Germany.
Prof. Dr. Alan Hazell, University of Aarhus, Denmark 
Prof. Dr. James H. Clark, University of York, UK 

Indústria: colaboração formal entre a Universidade de Aveiro (CICECO – Isabel S. Gonçalves) e a Alfama (Empresa dedicada à investigação e desenvolvimento de produtos farmacêuticos).

Actividade pedagógica

A Isabel leccionou as aulas teóricas (T), teórico-práticas (TP) e práticas (P) das seguintes disciplinas: 

Química I (T, TP e P) 
Química II (T, TP e P) 
Laboratórios de Química Inorgânica (P) 
Química Básica (T e TP) 
Elementos de Química Física (TP´s)
Química Geral (T e P)

Projectos financiados

Investigadora responsável: Novos compostos oxometálicos com propriedades catalíticas melhoradas. FCT(POCTI/QUI/56109/2004). Estudos de EXAFS em catalisadores bimetálicos imobilizados em materiais mesoporosos. ESRF GRENOBLE, France (2003). Imobilização de complexos estabilizados por moléculas de solvente em materiais mesoporosos e suas aplicações em polimerização. Acções Integradas Luso-Alemãs com a Universidade Técnica de Munique (Prof. Dr. Fritz E. Kühn; 2002-2003). Estudos de EXAFS em oxocomplexos de molibdénio. ESRF GRENOBLE, France (2002). Novos sistemas catalíticos baseados em óxidos de molibdénio. FCT (POCTI/QUI/37990/2001). Estudos de EXAFS em sílicas mesoporosas derivatisadas com dioxocomplexos de molibdénio(VI). ESRF GRENOBLE, France (2001). Estudos de EXAFS em sílicas mesoporosas derivatisadas com catalisadores bimetálicos. ESRF GRENOBLE, France (2000). Catalisadores bimetálicos estabilizados por moléculas de solvente. Síntese e aplicações catalíticas. Acções Integradas Luso-Alemãs com a Universidade Técnica de Munique (Prof. Dr. Klaus Koehler; 1999-2000), Nº A-15/99. Investigadora: Argilas aniónicas multifuncionais. FCT (POCI/CTM/58507/2004). Materiais mesoporos híbridos orgânicos-inorgânicos. FCT (POCI/CTM/55648/2004). Síntese de silicatos luminescentes utilizando complexos de lantanídeos como agentes directores de estrutura. FCT (POCI/CTM/58863/2004). Controlo da escala de tamanho através de “Chemie Douce”: de materiais funcionais inorgânicos a híbridos orgânicos-inorgânicos. FCT (POCTI/CTM/46780/2002). Estudos de XAFS em materiais híbridos orgânicos-inorgânico mesoporosos. ESRF GRENOBLE, France (2003). Heterogeneização de complexos de metais de transição com actividade catalítica ou fotoquímica em óxidos mesoporosos. FCT (POCTI/QUI/32889/99). Participação: "European Madame Curie Training Site" (Advanced Ceramic Materials: Synthesis and Structure). Projectos Europeus: “FAME - Functionalised Advanced Materials Engineering of hybrids and ceramics”, Excelence Network, EU, 2004.

Publicações seleccionadas

Alguns trabalhos seleccionados:

Patentes
“Method for treating a mammal by administration of a compound having the ability to release CO, compounds having the ability to release CO and pharmaceutical compositions thereof” W. Haas, C. C. Romão, B. Royo, A. C. Fernandes, I. S. Gonçalves. WO 03/066067 A2, 14 August 2003. 

“Method for treating a mammal by administration of a compound having the ability to release CO, compounds having the ability to release CO and pharmaceutical compositions thereof” W. Haas, C. C. Romão, B. Royo, A. C. Fernandes, I. S. Gonçalves. US 2004/00667261 A1, 8 April 2004. 

“Method for treating a mammal by administration of a compound having the ability to release CO” C. C. Romão, S. S. Rodrigues, J. D. Seixas, A. R. M. Pina, B. Royo, A. C. Fernandes, I. S. Gonçalves. (Ref. Number: 290814.125WO, 3 Janeiro 2007). 

Artigos
“Mixed-ring and indenyl analogues of molybdenocene and tungstenocene: preparation and characterization” J. R. Ascenso, C. G. de Azevedo, I. S. Gonçalves, E. Herdtweck, D. S. Moreno, M. Pessanha, C. C. Romão. Organometallics 14 (1995) 3901-3919.

“Ligand dependence of the indenyl ring slippage in [(eta5-Ind)MoL2(CO)2]0,+ complexes: experimental and theoretical studies” M. J. Calhorda, C. A. Gamelas, I. S. Gonçalves, E. Herdtweck, C. C. Romão, L. F. Veiros. Organometallics 17 (1998) 2597-2611. 

“Modification of beta-cyclodextrin with ferrocenyl groups by ring opening of an encapsulated [1]ferrocenophane” P. Ferreira, I. S. Gonçalves, M. Pillinger, J. Rocha, P. Santos, J. Teixeira-Dias. Organometallics 19 (2000) 1455-1457.

“Mesoporous silicas modified with dioxomolybdenum(VI) complexes: synthesis and catalysis” P. Ferreira, I. S. Gonçalves, F. E. Kühn, A. D. Lopes, M. A. Martins, M. Pillinger, A. Pina, J. Rocha, C. C. Romão, A. M. Santos, T. M. Santos, A. A. Valente. Eur. J. Inorg. Chem. (2000) 2263-2270.

“Monomer-dimer equilibria in oxo/imido complexes of heptavalent rhenium: theoretical and spectroscopic investigations” P. Gisdakis, N. Rösch, E. Bencze, J. Mink, I. S. Gonçalves, F. E. Kühn. Eur. J. Inorg. Chem. (2001) 981-991.

“Synthesis and characterisation of a RuII([14]aneS4) complex immobilized in MCM–41-type mesoporous silica” M. Pillinger, I. S. Gonçalves, A. D. Lopes, J. Madureira, P. Ferreira, A. A. Valente, T. M. Santos, J. Rocha, J. F. S. Menezes, L. D. Carlos, J. Chem. Soc., Dalton Trans. (2001) 1628-1633. 

“Interactions of cationic and neutral molybdenum complexes with beta-cyclodextrin host molecules” S. Lima, I. S. Gonçalves, P. Claro, M. Pillinger, A. D. Lopes, P. Ferreira, J. J. C. Teixeira-Dias, J. Rocha, C. C. Romão. Organometallics 20 (2001) 2191-2197.

“Stepwise hapticity changes in sequential one-electron redox reactions of indenyl-molybdenum complexes: combined electrochemical, ESR, X-Ray and theoretical studies" M. E. Stoll, P. Belanzoni, M. J. Calhorda, M. G.B. Drew, V. Félix, W. E. Geiger, C. A. Gamelas, I. S. Gonçalves, C. C. Romão, L. F. Veiros. J. Am. Chem. Soc. 123 (2001) 10595-10606.

“Mesoporous silica grafted with multiply bonded dimolybdenum cations: XAFS analysis and catalytic activity in cyclopentadiene polymerization” M. Pillinger, I. S. Gonçalves, A. D. Lopes, P. Ferreira, J. Rocha, G. Zhang, M. Schäfer, O. Nuyken, F. E. Kühn. Phys. Chem. Chem. Phys. 4 (2002) 696-702.

“New insights in the reaction of t-butylhydroperoxide with dichloro- and dimethyl(dioxo)molybdenum(VI)” M. Groarke, I. S. Gonçalves, W. A. Herrmann, F. E. Kühn. J. Organomet. Chem. 649 (2002) 108-112. 

“Octahedral bipyridine and bipyrimidine dioxomolybdenum(VI) complexes: characterization, application in catalytic epoxidation, and density functional mechanistic study” F. E. Kühn, M. Groarke, É. Bencze, E. Herdtweck, A. Prazeres, A. M. Santos, M. J. Calhorda, C. C. Romão, I. S. Gonçalves, A. D. Lopes, M. Pillinger. Chem. Eur. J. 8 (2002) 2370-2383. 

“Organotin-oxometalate coordination polymers as catalysts for the epoxidation of olefins” M. Abrantes, A. A. Valente, M. Pillinger, I. S. Gonçalves, J. Rocha, C. C. Romão. J. Catal. 209 (2002) 237-244.

“Synthesis, characterization and luminescence of beta-cyclodextrin inclusion compounds containing europium(III) and gadolinium(III) tris(beta-diketonates)” S. S. Braga, R. A. Sá Ferreira, I. S. Gonçalves, M. Pillinger, J. Rocha, J. J. C. Teixeira-Dias, L. D. Carlos. J. Phys. Chem. B, 106 (2002) 11430-11437. 

“Solid state inclusion compound of S-ibuprofen in beta-cyclodextrin: structure and characterization” S. S. Braga, I. S. Gonçalves, E. Herdtweck, J. J. C. Teixeira-Dias. New J. Chem. 27 (2003) 597-601. 

“Preparation and characterization of organotin-oxomolybdate coordination polymers and their use in sulfoxidation catalysis” M. Abrantes, A. A. Valente, M. Pillinger, I. S. Gonçalves, J. Rocha, C. C. Romão. Chem. Eur. J. 9 (2003) 2685-2695. (artigo com frontispício) 

“Ordered benzene-silica hybrids with molecular-scale periodicity in the walls and different mesopore sizes” N. Bion, P. Ferreira, A. Valente, I. S. Gonçalves, J. Rocha. J. Mater. Chem. 13 (2003) 1910-1913. 

“Molecular structure-activity relationship for the oxidation of organic compounds using mesoporous silica catalysts derivatized with bis(halogeno)dioxomolybdenum(VI) complexes” C. D. Nunes, A. A. Valente, M. Pillinger, J. Rocha, I. S. Gonçalves. Chem. Eur. J. 9 (2003) 4380-4390. 

-“Dichloro and dimethyl dioxomolybdenum(VI)-diazobutadiene complexes as catalysts for the epoxidation of olefins” A. A. Valente, J. Moreira, A. D. Lopes, M. Pillinger, C. D. Nunes, C. C. Romão, F. E. Kühn, I. S. Gonçalves. New J. Chem. 28 (2004) 308-313. 

“Synthesis and properties of layered double hydroxides containing ferrocenecarboxylate anions” S. Gago, M. Pillinger, T. M. Santos, J. Rocha, I. S. Gonçalves. Eur. J. Inorg. Chem. (2004) 1389-1395. (Capa da revista – ISSUE 7/2004). 

“Immobilization of oxomolybdenum species in a layered double hydroxide pillared by 2,2’-bipyridine-5,5’-dicarboxylate anions” S. Gago, M. Pillinger, A. A. Valente, T. M. Santos, J. Rocha, I. S. Gonçalves. Inorg. Chem. 43 (2004) 5422-5431.

 “Spectroscopic studies of europium(III) and gadolinium(III) tris-beta-diketonate complexes with diazabutadiene ligands” J. A. Fernandes, R. A. Sá Ferreira, M. Pillinger, L. D. Carlos, I. S. Gonçalves, P. Ribeiro-Claro. Eur. J. Inorg. Chem. (2004) 3913-3919. 

“Incorporation of a (Cyclopentadienyl)molybdenum Oxo Complex in MCM-41 and its Use as a Catalyst for Olefin Epoxidation” M. Abrantes, S. Gago, A. A. Valente, M. Pillinger, I. S. Gonçalves, T. M. Santos, J. Rocha, C. C. Romão. Eur. J. Inorg. Chem. (2004) 4914-4920. 

“Catalytic Olefin Epoxidation with Cyclopentadienyl-Molybdenum Complexes in Room Temperature Ionic Liquids” F. E. Kühn, J. Zhao, M. Abrantes, W. Sun, C. A. M. Afonso, L. C. Branco, I. S. Gonçalves, M. Pillinger, C. C. Romão. Tetrahedron Lett., 46 (2005) 47-52. 

“Synthesis and reactivity of mixed-ring indenyl complexes of molybdenocene” I. S. Gonçalves, C. A. Gamelas, C. C. L. Pereira, C. C. Romão. J. Organomet. Chem. 690 (2005) 1718-1725. 

“Inclusion of molybdenocene dichloride (Cp2MoCl2) in 2-hydroxypropyl- and trimethyl-beta-cyclodextrin: structural and biological properties” S. S. Braga, M. P. M. Marques, J. B. Sousa, M. Pillinger, J. J. C. Teixeira-Dias, I. S. Gonçalves. J. Organomet. Chem. 690 (2005) 2905-2912. 

“Highly luminescent tris(beta-diketonate)europium(III) complexes immobilized in a functionalized mesoporous silica” S. Gago, J. A. Fernandes, J. P. Rainho, R. A. Sá Ferreira, M. Pillinger, A. A. Valente, T. M. Santos, L. D. Carlos, P. J. Ribeiro-Claro, I. S. Gonçalves. Chem. Mater. 17 (2005) 5077-5084. 

“Immobilization of lanthanide ions in a pillared layered double hydroxide” S. Gago, M. Pillinger, R. A. Sá Ferreira, L. D. Carlos, T. M. Santos, I. S. Gonçalves. Chem. Mater., 17 (2005) 5803-5809. 

“Inclusion complexation of dimeric and trimeric oligo(ferrocenyldimethylsilanes) with gamma-cyclodextrin” J. A. Fernandes, S. Lima, S. S. Braga, M. Pillinger, P. Ribeiro-Claro, J. E. Rodriguez-Borges, A. D. Lopes, J. J. C. Teixeira-Dias, I. S. Gonçalves. Organometallics, 24 (2005) 5673-5677. 

“Structural studies of beta-cyclodextrin and permethylated beta-cyclodextrin inclusion compounds of cyclopentadienyl metal carbonyl complexes” S. S. Braga, F. A. Almeida Paz, M. Pillinger, J. D. Seixas, C. C. Romão, I. S. Gonçalves. Eur. J. Inorg. Chem. (2006) 1662-1669. 

“Raman and infrared spectroscopic and theoretical studies of dinuclear rhenium and osmium complexes, M2(O2CCH3)4X2 (M=Re, Os; X = Cl, Br)” L. Hajba, J. Mink, F. E. Kühn, I. S. Gonçalves. Inorg. Chim. Acta, 359 (2006) 4741-4756.

“Luminescence properties of composites made of a europium(III) complex and electroluminescent polymers with different energy gaps” J. Morgado, A. Charas, J. A. Fernandes, I. S. Gonçalves, L. D. Carlos, L. Alcácer. J. Phys. D: Appl. Phys. 39 (2006) 3582-3587. 

“Structural studies of [CpMoL2(CO)2]+ (L = NCMe, L2 = 2,2-biimidazole) complexes and their inclusion compounds with cyclodextrins” C. C. P. Pereira, S. S. Braga, F. A. Almeida Paz, M. Pillinger, J. Klinowski, I. S. Gonçalves. Eur. J. Inorg. Chem., (2006) 4278-4288.

"A combined theoretical-experimental study of the inclusion of niobocene dichloride in native and permethylated b-cyclodextrins"  C. C. L. Pereira, M. Nolasco, S. S. Braga, F. A. A. Paz, P. Ribeiro-Claro, M. Pillinger, I. S. Gonçalves. Organometallics  26 (2007) 4220-4228.

"Preparation and photophysical characterization of Zn-Al layered double hydroxides intercalated by anionic pyrene derivatives" S. Gago, T. Costa, J. Seixas de Melo, I. S. Gonçalves, M. Pillinger. J. Mater. Chem. 18 (2008) 894-904.

"An investigation of layered double hydroxides intercalated by oxomolybdenum and oxotungsten catecholate complexes"  B. Monteiro, S. Gago, F. A. Almeida Paz, R. Bilsborrow, I. S. Gonçalves, M. Pillinger. Inorg. Chem. 47 (2008) 8674-8686.

"Structural and photoluminescence studies of a europium(III) tetrakis(b-diketonate) complex with tetrabutylammonium, imidazolium, pyridinium and silica-supported imidazolium counterions" S. M. Bruno, R. A. Sá Ferreira, F. A. Almeida Paz, L. D. Carlos, M. Pillinger, P. Ribeiro-Claro, I. S. Gonçalves. Inorg. Chem. 48 (2009) 4882–4895.

Projectos

Argilas aniónicas multifuncionais (POCI/CTM/58507/2004)

ParticipanteFundação para a Ciência e a Tecnologia
Hidróxidos duplos lamelares Intercalação Sistemas hóspede-hospedeiro Catálise heterogénea

Catalisadores de metaloceno modificados por contentores moleculares (PTDC/QEQ-SUP/1906/2012)

CoordenadorFundação para a Ciência e a Tecnologia
Metalocenos Química hóspede-hospedeiro Contentores moleculares Transformações orgânicas

Controlo da escala de tamanho através de "Chimie Douce": de materiais funcionais inorgânicos a hìbridos orgânicos-inorgânicos (POCTI/CTM/46780/2002)

ParticipanteFundação para a Ciência e a Tecnologia
Materiais Funcionais Inorgânicos Chimie Douce HÌbridos Orgânicos-Inorgânicos Luminescente

Conversao catalitica de olefinas derivadas da biomassa (BiOle_AcidOxCat)

ParticipanteFundação para a Ciência e a Tecnologia

Desenvolvimento Inteligente de Emissores de Luz Branca Energeticamente Eficientes Baseados em Hibridos Organicos-Inorganicos (HyLight)

Coordenador LocalFundação para a Ciência e a Tecnologia

Dessulfurização do gasóleo por processos heterogéneos de oxidação catalítica sustentáveis (PTDC/EQU-EQU/121677/2010)

Coordenador LocalFundação para a Ciência e a Tecnologia
Desulfurization Heterogeneous catalysis Sulfoxidation Green oxidants

Novos compostos oxometálicos com propriedades catlíticas melhoradas (POCI/QUI/56109/2004)

CoordenadorFundação para a Ciência e a Tecnologia
Complexos oxometálicos Híbridos orgânicos-inorgânicos Mecanismos reaccionais Catálise oxidativa

Óxidos de organorénio (VII) com ligandos-ansa e as suas aplicações como catalisadores homogéneos e heterogéneos (PTDC/QUI/71198/2006)

CoordenadorFundação para a Ciência e a Tecnologia
catálise quiralidade rénio novos materiais

Síntese de Silicatos Luminescentes Utilizando Complexos de Lantanideos como Agentes Directores de Estrutura (POCI/CTM/58863/2004)

ParticipanteFundação para a Ciência e a Tecnologia
Materias Funcionais Inorgânicos Luminescência Silicatos Microporosos Complexos de Lantanídeos

Sistemas ativados por estímulos para a terapia com monóxido de carbono (SASCOT)

ParticipanteFundação para a Ciência e a Tecnologia

Publicações

Intercalation of (eta(5)-Pentamethylcyclopentadienyl)trioxomolybdenum(VI) in a Layered Double Hydroxide

Gomes, AC; Neves, P; Gago, S; Valente, AA; Goncalves, IS; Pillinger, M
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 25, 2408-2416.
ISBN: 1099-0682

A sustainable peroxophosphomolybdate/H2O2 system for the oxidative removal of organosulfur compounds from simulated and real high-sulfur diesels

Juliao, D; Gomes, AC; Cunha-Silva, L; Valenca, R; Ribeiro, JC; Pillinger, M; de Castro, B; Goncalves, IS; Balula, SS
2020, APPLIED CATALYSIS A-GENERAL, 589.
ISBN: 1873-3875

Desulfurization and Denitrogenation Processes to Treat Diesel Using Mo(VI)-Bipyridine Catalysts

Juliao, D; Gomes, AC; Pillinger, M; Goncalves, IS; Balula, SS
2020, CHEMICAL ENGINEERING & TECHNOLOGY, 43, 9, 1774-1783.
ISBN: 1521-4125

Desulfurization of diesel by extraction coupled with Mo-catalyzed sulfoxidation in polyethylene glycol-based deep eutectic solvents

Juliao, D; Gomes, AC; Pillinger, M; Lopes, AD; Valenca, R; Ribeiro, JC; Goncalves, IS; Balula, SS
2020, JOURNAL OF MOLECULAR LIQUIDS, 309.
ISBN: 1873-3166

Desulfurization of model and real fuels by extraction and oxidation processes using an indenylmolybdenum tricarbonyl pre-catalyst

Juliao, D; Gomes, AC; Pillinger, M; Valenca, R; Ribeiro, JC; Goncalves, IS; Balula, SS
2020, APPLIED ORGANOMETALLIC CHEMISTRY, 34, 4.
ISBN: 1099-0739

Evaluation of the supramolecular interaction of Congo red with cucurbiturils using mass spectrometry and spectroscopic methods

Costa, AL; Gomes, AC; Lopes, AD; Da Silva, JP; Pillinger, M; Goncalves, IS; de Melo, JSS
2020, NEW JOURNAL OF CHEMISTRY, 44, 6, 2587-2596.
ISBN: 1369-9261

One-Pot Intercalation Strategy for the Encapsulation of a CO-Releasing Organometallic Molecule in a Layered Double Hydroxide

Calhau, IB; Gomes, AC; Bruno, SM; Coelho, AC; Magalhaes, CIR; Romao, CC; Valente, AA; Goncalves, IS; Pillinger, M
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 28, 2726-2736.
ISBN: 1099-0682

Oxidation of sulfides in aqueous media catalyzed by pyrazole-oxidoperoxido-molybdenum(VI) complexes

Bruno, SM; Amarante, TR; Paz, FAA; Pillinger, M; Valente, AA; Goncalves, IS
2020, INORGANICA CHIMICA ACTA, 511.
ISBN: 1873-3255

Deep oxidative desulfurization of diesel fuels using homogeneous and SBA-15-supported peroxophosphotungstate catalysts

Juliao, D; Mirante, F; Ribeiro, SO; Gomes, AC; Valenca, R; Ribeiro, JC; Pillinger, M; de Castro, B; Goncalves, IS; Balula, SS
2019, FUEL, 241, 616-624.
ISBN: 1873-7153

A Comparative Study of Molybdenum Carbonyl and Oxomolybdenum Derivatives Bearing 1,2,3-Triazole or 1,2,4-Triazole in Catalytic Olefin Epoxidation

Nogueira, LS; Neves, P; Gomes, AC; Amarante, TA; Paz, FAA; Valente, AA; Goncalves, IS; Pillinger, M
2019, MOLECULES, 24, 1.

Efficient Isomerization of alpha-Pinene Oxide to Campholenic Aldehyde Promoted by a Mixed-Ring Analogue of Molybdenocene

Bruno, SM; Valente, AA; Pillinger, M; Arnelse, J; Romao, CC; Goncalves, IS
2019, ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 7, 16, 13639-13645.

A hydrogen-bonded assembly of cucurbit[6]uril and [MoO2Cl2(H2O)(2)] with catalytic efficacy for the one-pot conversion of olefins to alkoxy products

Nogueira, LS; Antunes, MM; Gomes, AC; Cunha-Silva, L; Pillinger, M; Lopes, AD; Valente, AA; Goncalves, IS
2019, DALTON TRANSACTIONS, 48, 30, 11508-11519.
ISBN: 1477-9234

Dichlorodioxomolybdenum(VI) complexes bearing oxygen-donor ligands as catalysts for oxidative desulfurization of simulated and real diesel

Juliao, D; Gomes, AC; Cunha-Silva, L; Pillinger, M; Lopes, AD; Valenca, R; Ribeiro, JC; Goncalves, IS; Balula, SS
2019, CATALYSIS COMMUNICATIONS, 128.
ISBN: 1873-3905

A Molybdenum Trioxide Hybrid Decorated by 3-(1,2,4-Triazol-4-yl)adamantane-1-carboxylic Acid: A Promising Reaction-Induced Self-Separating (RISS) Catalyst

Lysenko, AB; Senchyk, GA; Domasevitch, KV; Henfling, S; Erhart, O; Krautscheid, H; Neves, P; Valente, AA; Pillinger, M; Goncalves, IS
2019, INORGANIC CHEMISTRY, 58, 24, 16424-16433.
ISBN: 1520-510X

Performance of chiral tetracarbonylmolybdenum pyrindanyl amine complexes in catalytic olefin epoxidation

Neves, P; Nogueira, LS; Valente, AA; Pillinger, M; Goncalves, IS; Sampaio-Dias, IE; Sousa, CAD; Rizzo-Aguiar, F; Rodriguez-Borges, JE
2018, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 858, 29-36.

Acid-catalyzed epoxide alcoholysis in the presence of indenyl molybdenum carbonyl complexes

Bruno, SM; Goncalves, IS; Pillinger, M; Romao, CC; Valente, AA
2018, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 855, 12-17.

Interactions and Supramolecular Organization of Sulfonated Indigo and Thioindigo Dyes in Layered Hydroxide Hosts

Costa, AL; Gomes, AC; Pereira, RC; Pillinger, M; Goncalves, IS; Pineiro, M; de Melo, JSS
2018, LANGMUIR, 34, 1, 453-464.

[MoO3(2,2'-bipy)](n) catalyzed oxidation of amines and sulfides

Tosi, I; Vurchio, C; Abrantes, M; Goncalves, IS; Pillinger, M; Cavani, F; Cordero, FM; Brandi, A
2018, CATALYSIS COMMUNICATIONS, 103, 60-64.

Desulfurization of liquid fuels by extraction and sulfoxidation using H2O2 and [CpMo(CO)(3)R] as catalysts

Juliao, D; Gomes, AC; Pillinger, M; Valenca, R; Ribeiro, JC; Goncalves, IS; Balula, SS
2018, APPLIED CATALYSIS B-ENVIRONMENTAL, 230, 177-183.

Molybdenum(0) tricarbonyl and tetracarbonyl complexes with a cationic pyrazolylpyridine ligand: synthesis, crystal structures and catalytic performance in olefin epoxidation

Nogueira, LS; Neves, P; Gomes, AC; Lavrador, P; Cunha-Silva, L; Valente, AA; Goncalves, IS; Pillinger, M
2018, RSC ADVANCES, 8, 29, 16294-16302.

An Organotin Vanadate with Sodalite Topology and Catalytic Versatility in Oxidative Transformations

Gomes, AC; Antunes, MM; Abrantes, M; Valente, AA; Paz, FAA; Goncalves, IS; Pillinger, M
2018, CHEMCATCHEM, 10, 16, 3481-3489.

Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts

Granadeiro, CM; Ferreira, PMC; Juliao, D; Ribeiro, LA; Valenca, R; Ribeiro, JC; Goncalves, IS; de Castro, B; Pillinger, M; Cunha-Silva, L; Balula, SS
2018, ENERGIES, 11, 7.

High-yield synthesis and catalytic response of chainlike hybrid materials of the [(MoO3)(m)(2,2 '-bipyridine)(n)] family

Bruno, SM; Nogueira, LS; Gomes, AC; Valente, AA; Goncalves, IS; Pillinger, M
2018, NEW JOURNAL OF CHEMISTRY, 42, 20, 16483-16492.

A Linear Trinuclear Oxidodiperoxido-molybdenum(VI) Complex with Single Triazole Bridges: Catalytic Activity in Epoxidation, Alcoholysis, and Acetalization Reactions

Antunes, MM; Amarante, TR; Valente, AA; Paz, FAA; Goncalves, IS; Pillinger, M
2018, CHEMCATCHEM, 10, 13, 2782-2791.

Insights into the Photophysics and Supramolecular Organization of Congo Red in Solution and the Solid State

Costa, AL; Gomes, AC; Pillinger, M; Goncalves, IS; Pina, J; de Melo, JSS
2017, CHEMPHYSCHEM, 18, 5, 564-575.

Ferrocene and ferrocenium inclusion compounds with cucurbiturils: a study of metal atom dynamics probed by Mossbauer spectroscopy

Magalhaes, CIR; Gomes, AC; Lopes, AD; Goncalves, IS; Pillinger, M; Jin, E; Kim, I; Ko, YH; Kim, K; Nowik, I; Herber, RH
2017, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 19, 32, 21548-21555.
ISBN: 1463-9084

Performance of a tetracarbonylmolybdenum(0) pyrazolylpyridine (pre) catalyst in olefin epoxidation and epoxide alcoholysis

Nogueira, LS; Neves, P; Gomes, AC; Valente, AA; Pillinger, M; Goncalves, IS
2017, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 846, 185-192.
ISBN: 1872-8561

Synthesis, structure and catalytic olefin epoxidation activity of a dinuclear oxo-bridged oxodiperoxomolybdenum(VI) complex containing coordinated 4,4 '-bipyridinium

Neves, P; Gomes, AC; Paz, FAA; Valente, AA; Goncalves, IS; Pillinger, M
2017, MOLECULAR CATALYSIS, 432, 104-114.

Behavior of Triazolylmolybdenum(VI) Oxide Hybrids as Oxidation Catalysts with Hydrogen Peroxide

Neves, P; Lysenko, AB; Gomes, AC; Pillinger, M; Goncalves, IS; Valente, AA
2017, CATALYSIS LETTERS, 147, 5, 1133-1143.
ISBN: 1572-879X

Triazolyl, Imidazolyl, and Carboxylic Acid Moieties in the Design of Molybdenum Trioxide Hybrids: Photophysical and Catalytic Behavior

Lysenko, AB; Senchyk, GA; Domasevitch, KV; Kobalz, M; Krautscheid, H; Cichos, J; Karbowiak, M; Neves, P; Valente, AA; Goncalves, IS
2017, INORGANIC CHEMISTRY, 56, 8, 4380-4394.
ISBN: 1520-510X

Chemistry and Catalytic Performance of Pyridyl-Benzimidazole Oxidomolybdenum(VI) Compounds in (Bio)Olefin Epoxidation

Neves, P; Nogueira, LS; Gomes, AC; Oliveira, TSM; Lopes, AD; Valente, AA; Goncalves, IS; Pillinger, M
2017, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 19, 2617-2627.
ISBN: 1099-0682

Solid-state study of the structure and host-guest chemistry of cucurbituril-ferrocene inclusion complexes

Gomes, AC; Magalhaes, CIR; Oliveira, TSM; Lopes, AD; Goncalves, IS; Pillinger, M
2016, DALTON TRANSACTIONS, 45, 42, 17042-17052.

A recyclable ionic liquid-oxomolybdenum(VI) catalytic system for the oxidative desulfurization of model and real diesel fuel

Juliao, D; Gomes, AC; Pillinger, M; Valenca, R; Ribeiro, JC; Goncalves, IS; Balula, SS
2016, DALTON TRANSACTIONS, 45, 38, 15242-15248.

Catalytic alcoholysis of epoxides using metal-free cucurbituril-based solids

Bruno, SM; Gomes, AC; Oliveira, TSM; Antunes, MM; Lopes, AD; Valente, AA; Goncalves, IS; Pillinger, M
2016, ORGANIC & BIOMOLECULAR CHEMISTRY, 14, 16, 3873-3877.

Catalytic Application of an Octamolybdate Salt (H(3)biim)(4)[beta-Mo8O26] in Olefin Epoxidation (H(2)biim=2,2'-biimidazole)

Neves, P; Amarante, TR; Valente, AA; Pillinger, M; Goncalves, IS
2016, CATALYSIS LETTERS, 146, 4, 841-850.

Crystal structure of an organic-inorganic supramolecular salt based on a 4,4 '-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a beta-octamolybdate anion

Amarante, TR; Goncalves, IS; Paz, FAA
2016, ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 72, 124-+.

Metal oxide-triazole hybrids as heterogeneous or reaction-induced self-separating catalysts

Amarante, TR; Neves, P; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2016, JOURNAL OF CATALYSIS, 340, 354-367.

Oxidomolybdenum complexes for acid catalysis using alcohols as solvents and reactants

Gomes, AC; Neves, P; Cunha-Silva, L; Valente, AA; Goncalves, IS; Pillinger, M
2016, CATALYSIS SCIENCE & TECHNOLOGY, 6, 13, 5207-5218.

Zinc-Substituted Polyoxotungstate@amino-MIL-101(Al) - An Efficient Catalyst for the Sustainable Desulfurization of Model and Real Diesels

Juliao, D; Gomes, AC; Pillinger, M; Valenca, R; Ribeiro, JC; de Castro, B; Goncalves, IS; Cunha Silva, L; Balula, SS
2016, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 32, 5114-5122.

Crystal structure and temperature-dependent luminescence of a heterotetranuclear sodium-europium(III) beta-diketonate complex

Bruno, SM; Ananias, D; Paz, FAA; Pillinger, M; Valente, AA; Carlos, LD; Goncalves, IS
2015, DALTON TRANSACTIONS, 44, 2, 488-492.

Ring-opening of epoxides promoted by organomolybdenum complexes of the type [eta(5)-C5H4R)mo(CO)(2)(773-C3H5)] and [(eta(5)-C5H5) Mo(CO)(3)(CH2R)]

Bruno, SM; Gomes, AC; Abrantes, M; Valente, AA; Pillinger, M; Goncalves, IS
2015, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 799-800, 179-183.

Redetermination of the crystal structure of 3,5-dimethylpyrazolium beta-octamolybdate tetrahydrate

Amarante, TR; Goncalves, IS; Paz, FAA
2015, ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 71, M244-+.

An Indigo Carmine-Based Hybrid Nanocomposite with Supramolecular Control of Dye Aggregation and Photobehavior

Costa, AL; Gomes, AC; Pillinger, M; Goncalves, IS; de Melo, JSS
2015, CHEMISTRY-A EUROPEAN JOURNAL, 21, 34, 12069-12078.

Crystal Structure and Catalytic Behavior in Olefin Epoxidation of a One-Dimensional Tungsten Oxide/Bipyridine Hybrid

Amarante, TR; Antunes, MM; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2015, INORGANIC CHEMISTRY, 54, 20, 9690-9703.

Synthesis and Structural Elucidation of Triazolylmolybdenum(VI) Oxide Hybrids and Their Behavior as Oxidation Catalysts

Lysenko, AB; Senchyk, GA; Domasevitch, KV; Hauser, J; Fuhrmann, D; Kobalz, M; Krautscheid, H; Neves, P; Valente, AA; Goncalves, IS
2015, INORGANIC CHEMISTRY, 54, 17, 8327-8338.

Incorporation of a dioxomolybdenum(VI) complex in a Zr-IV-based Metal-Organic Framework and its application in catalytic olefin epoxidation

Neves, P; Gomes, AC; Amarante, TR; Paz, FAA; Pillinger, M; Goncalves, IS; Valente, AA
2015, MICROPOROUS AND MESOPOROUS MATERIALS, 202, 106-114.

Catalytic isomerisation of alpha-pinene oxide in the presence of ETS-10 supported ferrocenium ions

Bruno, SM; Gomes, AC; Coelho, AC; Brandao, P; Valente, AA; Pillinger, M; Goncalves, IS
2015, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 791, 66-71.

Dichlorodioxomolybdenum(VI) complexes bearing oxygen-donor ligands as olefin epoxidation catalysts

Oliveira, TSM; Gomes, AC; Lopes, AD; Lourenco, JP; Paz, FAA; Pillinger, M; Goncalves, IS
2015, DALTON TRANSACTIONS, 44, 31, 14139-14148.

Comparing spectroscopic and electrochemical properties of complexes of type Cp'M(eta(3)-C3H5)(CO)(2) (Cp' = Cp, Ind, Flu): A complementary experimental and DFT study

Goncalves, IS; Veiros, LF; Gamelas, CA; Cabrita, C; Calhorda, MJ; Geraldes, CFGC; Green, J; Packham, E; Drew, MGB; Felix, V; Santos, AG; Romao, CC
2015, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 792, 154-166.

Desulfurization of model diesel by extraction/oxidation using a zinc-substituted polyoxometalate as catalyst under homogeneous and heterogeneous (MIL-101 (Cr) encapsulated) conditions

Juliao, D; Gomes, AC; Pillinger, M; Cunha-Silva, L; de Castro, B; Goncalves, IS; Balula, SS
2015, FUEL PROCESSING TECHNOLOGY, 131, 78-86.

Promotion of phosphoester hydrolysis by the Zr-IV-based metal-organic framework UiO-67

Nunes, P; Gomes, AC; Pillinger, M; Goncalves, IS; Abrantes, M
2015, MICROPOROUS AND MESOPOROUS MATERIALS, 208, 21-29.

Controlling the Fluorescence Behavior of 1-Pyrenesulfonate by Cointercalation with a Surfactant in a Layered Double Hydroxide

Costa, AL; Gomes, AC; Pillinger, M; Goncalves, IS; de Melo, JSS
2015, LANGMUIR, 31, 16, 4769-4778.

Use of Organomolybdenum Compounds for Promoted Hydrolysis of Phosphoester Bonds in Aqueous Media

Gomes, AC; Gamelas, CA; Fernandes, JA; Paz, FAA; Nunes, P; Pillinger, M; Goncalves, IS; Romao, CC; Abrantes, M
2014, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 23, 3681-3689.

Crystal Structure and Spectroscopic Studies of a Dimeric Europium( III) similar to- Diketonate Complex Containing [ 3-( 2-Pyridyl)-1-pyrazolyl] acetate

Coelho, AC; Gomes, AC; Fernandes, JA; Paz, FAA; Braga, SS; Rino, L; Pereira, L; Pillinger, M; Goncalves, IS
2014, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 8, 1284-1288.

Catalytic olefin epoxidation with a carboxylic acid-functionalized cyclopentadienyl molybdenum tricarbonyl complex

Gomes, AC; Bruno, SM; Abrantes, M; Magalhaes, CIR; Goncalves, IS; Valente, AA; Pillinger, M
2014, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 760, 205-211.

Post-synthetic modification of crystal-like periodic mesoporous phenylene-silica with ferrocenyl groups

Gomes, AC; Lourenco, MAO; Bruno, SM; Ferreira, P; Valente, AA; Pillinger, M; Goncalves, IS
2014, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 751, 501-507.

Application of an indenyl molybdenum dicarbonyl complex in the isomerisation of alpha-pinene oxide to campholenic aldehyde

Bruno, SM; Gomes, AC; Gamelas, CA; Abrantes, M; Oliveira, MC; Valente, AA; Paz, FAA; Pillinger, M; Romao, CC; Goncalves, IS
2014, NEW JOURNAL OF CHEMISTRY, 38, 7, 3172-3180.

Synthesis, Structural Elucidation, and Catalytic Properties in Olefin Epoxidation of the Polymeric Hybrid Material [Mo3O9(2-[3(5)-Pyrazolyl]pyridine)](n)

Amarante, TR; Neves, P; Gomes, AC; Nolasco, MM; Ribeiro-Claro, P; Coelho, AC; Valente, AA; Paz, FAA; Smeets, S; McCusker, LB; Pillinger, M; Goncalves, IS
2014, INORGANIC CHEMISTRY, 53, 5, 2652-2665.

Investigation of a dichlorodioxomolybdenum(VI)-pyrazolylpyridine complex and a hybrid derivative as catalysts in olefin epoxidation

Amarante, TR; Neves, P; Paz, FAA; Valente, AA; Pillinger, M; Goncalves, IS
2014, DALTON TRANSACTIONS, 43, 16, 6059-6069.

Synthesis, Characterisation and Antiproliferative Studies of Allyl(dicarbonyl)(cyclopentadienyl)molybdenum Complexes and Cyclodextrin Inclusion Compounds

Braga, SS; Mokal, V; Paz, FAA; Pillinger, M; Branco, AF; Sardao, VA; Diogo, CV; Oliveira, PJ; Marques, MPM; Romao, CC; Goncalves, IS
2014, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 29, 5034-5045.

Promotion of phosphoester hydrolysis by MoO2Cl2L (L bipyridine derivatives, H2O, no ligand), MoO2(CH3)(2)L (L bipyridine derivatives) and related inorganice-organic hybrids in aqueous media

Gomes, AC; Pillinger, M; Nunes, P; Goncalves, IS; Abrantes, M
2014, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 760, 42-47.

Triazolyl-Based Copper-Molybdate Hybrids: From Composition Space Diagram to Magnetism and Catalytic Performance

Senchyk, GA; Lysenko, AB; Babaryk, AA; Rusanov, EB; Krautscheid, H; Neves, P; Valente, AA; Goncalves, IS; Kramer, KW; Liu, SX; Decurtins, S; Domasevitch, KV
2014, INORGANIC CHEMISTRY, 53, 19, 10112-10121.

Isomerization of alpha-pinene oxide in the presence of methyltrioxorhenium(VII)

Bruno, SM; Pillinger, M; Kuhn, FE; Goncalves, IS; Valente, AA
2013, CATALYSIS COMMUNICATIONS, 35, 40-44.

Bis(pyrazolyl)methanetetracarbonyl-molybdenum(0) as precursor to a molybdenum(VI) catalyst for olefin epoxidation

Figueiredo, S; Gomes, AC; Fernandes, JA; Paz, FAA; Lopes, AD; Lourenco, JP; Pillinger, M; Goncalves, IS
2013, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 723, 56-64.

Use of MoO2Cl2(DMF)(2) as a precursor for molybdate promoted hydrolysis of phosphoester bonds

Tome, CM; Oliveira, MC; Pillinger, M; Goncalves, IS; Abrantes, M
2013, DALTON TRANSACTIONS, 42, 11, 3901-3907.

A dinuclear oxo-bridged molybdenum(VI) complex containing a bidentate pyrazolylpyridine ligand: Structure, characterization and catalytic performance for olefin epoxidation

Amarante, TR; Gomes, AC; Neves, P; Paz, FAA; Valente, AA; Pillinger, M; Goncalves, IS
2013, INORGANIC CHEMISTRY COMMUNICATIONS, 32, 59-63.

Synthesis and characterization of CpMo(CO)(3)(CH2-pC(6)H(4)-CO2CH3) and its inclusion compounds with methylated cyclodextrins. Applications in olefin epoxidation catalysis

Gomes, AC; Bruno, SM; Tome, C; Valente, AA; Pillinger, M; Abrantes, M; Goncalves, IS
2013, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 730, 116-122.

Hydrothermal Synthesis, Crystal Structure, and Catalytic Potential of a One-Dimensional Molybdenum Oxide/Bipyridinedicarboxylate Hybrid

Amarante, TR; Neves, P; Valente, AA; Paz, FAA; Fitch, AN; Pillinger, M; Goncalves, IS
2013, INORGANIC CHEMISTRY, 52, 8, 4618-4628.

Tris(pyrazolyl)methane molybdenum tricarbonyl complexes as catalyst precursors for olefin epoxidation

Gomes, AC; Neves, P; Figueiredo, S; Fernandes, JA; Valente, AA; Paz, FAA; Pillinger, M; Lopes, AD; Goncalves, IS
2013, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 370, 64-74.

Intercalation of a molybdenum eta(3)-allyl dicarbonyl complex in a layered double hydroxide and catalytic performance in olefin epoxidation

Gomes, AC; Bruno, SM; Gamelas, CA; Valente, AA; Abrantes, M; Goncalves, IS; Romao, CC; Pillinger, M
2013, DALTON TRANSACTIONS, 42, 23, 8231-8240.

Preparation of crystal-like periodic mesoporous phenylene-silica derivatized with ferrocene and its use as a catalyst for the oxidation of styrene

Gomes, AC; Ferreira, MJ; Bruno, SM; Bion, N; Ferreira, P; Valente, AA; Pillinger, M; Rocha, J; Goncalves, IS
2013, DALTON TRANSACTIONS, 42, 40, 14612-14620.

Catalytic oxidative desulfurization systems based on Keggin phosphotungstate and metal-organic framework MIL-101

Ribeiro, S; Barbosa, ADS; Gomes, AC; Pillinger, M; Goncalves, IS; Cunha-Silva, L; Balula, SS
2013, FUEL PROCESSING TECHNOLOGY, 116, 350-357.

Intercalation of a molybdenum(0)-tetracarbonyl-bipyridine complex in a layered double hydroxide

Gomes, AC; Bruno, SM; Valente, AA; Goncalves, IS; Pillinger, M
2013, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 744, 53-59.

Molybdenum(II) Diiodo-Tricarbonyl Complexes Containing Nitrogen Donor Ligands as Catalyst Precursors for the Epoxidation of Methyl Oleate

Gamelas, CA; Neves, P; Gomes, AC; Valente, AA; Romao, CC; Goncalves, IS; Pillinger, M
2012, CATALYSIS LETTERS, 142, 10, 1218-1224.

Isomerisation of alpha-pinene oxide in the presence of indenyl allyl dicarbonyl molybdenum(II) and tungsten(II) complexes

Bruno, SM; Gamelas, CA; Gomes, AC; Valente, AA; Pillinger, M; Romao, CC; Goncalves, IS
2012, CATALYSIS COMMUNICATIONS, 23, 58-61.

Epoxidation of olefins using a dichlorodioxomolybdenum(VI)-pyridylimine complex as catalyst

Balula, SS; Bruno, SM; Gomes, AC; Valente, AA; Pillinger, M; Goncalves, IS; Macquarrie, DJ; Clark, JH
2012, INORGANICA CHIMICA ACTA, 387, 234-239.

A dinuclear oxomolybdenum(VI) complex, [Mo2O6(4,4 '-di-tert-butyl-2,2 '-bipyridine)(2)], displaying the {MoO2(mu-O)(2)MoO2}(0) core, and its use as a catalyst in olefin epoxidation

Amarante, TR; Neves, P; Paz, FAA; Pillinger, M; Valente, AA; Goncalves, IS
2012, INORGANIC CHEMISTRY COMMUNICATIONS, 20, 147-152.

An Octanuclear Molybdenum(VI) Complex Containing Coordinative ly Bound 4,4 '-di-tert-Butyl-2,2 '-Bipyridine, [Mo8O22(OH)(4)(di-tBu-bipy)(4)]: Synthesis, Structure, and Catalytic Epoxidation of Bio-Derived Olefins

Amarante, TR; Neves, P; Tome, C; Abrantes, M; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2012, INORGANIC CHEMISTRY, 51, 6, 3666-3676.

Synthesis, Structural Elucidation, and Application of a Pyrazolylpyridine-Molybdenum Oxide Composite as a Heterogeneous Catalyst for Olefin Epoxidation

Figueiredo, S; Gomes, AC; Neves, P; Amarante, TR; Paz, FAA; Soares, R; Lopes, AD; Valente, AA; Pillinger, M; Goncalves, IS
2012, INORGANIC CHEMISTRY, 51, 15, 8629-8635.

Molybdenum(VI) catalysts obtained from eta(3)-allyl dicarbonyl precursors: Synthesis, characterization and catalytic performance in cyclooctene epoxidation

Gamelas, CA; Gomes, AC; Bruno, SM; Paz, FAA; Valente, AA; Pillinger, M; Romao, CC; Goncalves, IS
2012, DALTON TRANSACTIONS, 41, 12, 3474-3484.

A novel dinuclear MoVI complex with tris(3,5-dimethyl-1H-pyrazol-1-yl)methane

Gago, S; Gomes, AC; Cunha-Silva, L; Pillinger, M; Goncalves, IS; Paz, FAA
2012, ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 68, M73-M75.

[(E )-1-(Naphthalen-2-yl)ethylidene](naphthalen-1- ylmethyl)amine

Sofia M. Bruno, José A. Fernandes, Isabel S. Gonçalves, Filipe A. Almeida Paz
2012, ACTA CRYSTALLOGRAPHICA SECTION E, E68.

Structural Studies and Cytotoxicity of Trimethyl(ferrocenylmethyl)ammonium Iodide Encapsulated in beta-Cyclodextrin

Bruno, SM; Fernandes, JA; Marques, J; Neto, SC; Ribeiro-Claro, PJ; Pillinger, M; Paz, FAA; Marques, MPM; Braga, SS; Goncalves, IS
2011, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 32, 4955-4963.

Oxidation of Ethylbenzene in the Presence of an MCM-41-Supported or Ionic Liquid-Standing Bischlorocopper(II) Complex

Gago, S; Bruno, SM; Queiros, DC; Valente, AA; Goncalves, IS; Pillinger, M
2011, CATALYSIS LETTERS, 141, 7, 1009-1017.

Heterogeneous oxidation catalysts formed in situ from molybdenum tetracarbonyl complexes and tert-butyl hydroperoxide

Neves, P; Amarante, TR; Gomes, AC; Coelho, AC; Gago, S; Pillinger, M; Goncalves, IS; Silva, CM; Valente, AA
2011, APPLIED CATALYSIS A-GENERAL, 395, 1-2, 71-77.

Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor

Abrantes, M; Bruno, SM; Tome, C; Pillinger, M; Goncalves, IS; Valente, AA
2011, CATALYSIS COMMUNICATIONS, 15, 1, 64-67.

Epoxidation of cyclooctene using soluble or MCM-41-supported molybdenum tetracarbonyl-pyridylimine complexes as catalyst precursors

Gomes, AC; Bruno, SM; Gago, S; Lopes, RP; Machado, DA; Carminatti, AP; Valente, AA; Pillinger, M; Goncalves, IS
2011, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 696, 22, 3543-3550.

Molybdenum oxide/bipyridine hybrid material {[MoO3(bipy)][MoO3(H2O)]}(n) as catalyst for the oxidation of secondary amines to nitrones

Abrantes, M; Goncalves, IS; Pillinger, M; Vurchio, C; Cordero, FM; Brandi, A
2011, TETRAHEDRON LETTERS, 52, 52, 7079-7082.

Chemistry and Catalytic Activity of Molybdenum(VI)-Pyrazolylpyridine Complexes in Olefin Epoxidation. Crystal Structures of Monomeric Dioxo, Dioxo-mu-oxo, and Oxodiperoxo Derivatives

Coelho, AC; Nolasco, M; Balula, SS; Antunes, MM; Pereira, CCL; Paz, FAA; Valente, AA; Pillinger, M; Ribeiro-Claro, P; Klinowski, J; Goncalves, IS
2011, INORGANIC CHEMISTRY, 50, 2, 525-538.

Synthesis and Catalytic Properties of Molybdenum(VI) Complexes with Tris(3,5-dimethyl-1-pyrazolyl)methane

Neves, P; Gago, S; Balula, SS; Lopes, AD; Valente, AA; Cunha-Silva, L; Paz, FAA; Pillinger, M; Rocha, J; Silva, CM; Goncalves, IS
2011, INORGANIC CHEMISTRY, 50, 8, 3490-3500.

4,4 '-Di-tert-butyl-2,2 '-dipyridinium dichloride

Amarante, TR; Goncalves, IS; Paz, FAA
2011, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 67, O1903-U1807.

mu-Oxido-bis[chlorido(4,4 '-di-tert-butyl-2,2 '-bipyridine-kappa N-2,N ')dioxidomolybdenum(VI)] 0.2-hydrate

Gomes, AC; Fernandes, JA; Gamelas, CA; Goncalves, IS; Paz, FAA
2011, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 67, M1738-U901.

Propylammonium 4,4,4-trifluoro-1-(naphthalen-2-yl)butane-1,3-dionate

Fernandes, JA; Bruno, SM; Goncalves, IS; Paz, FAA
2011, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 67, O3384-U938.

Tris(4,4 '-di-tert-butyl-2,2 '-bipyridine-kappa N-2,N ')molybdenum(II) mu(6)-oxido-dodeca-mu(2)-oxido-hexaoxidohexamolybdate(VI) acetonitrile tetrasolvate

Amarante, TR; Fernandes, JA; Goncalves, IS; Paz, FAA
2011, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 67, M1828-U988.

Grafting of Molecularly Ordered Mesoporous Phenylene-Silica with Molybdenum Carbonyl Complexes: Efficient Heterogeneous Catalysts for the Epoxidation of Olefins

Coelho, AC; Balula, SS; Bruno, SM; Alonso, JC; Bion, N; Ferreira, P; Pillinger, M; Valente, AA; Rocha, J; Goncalves, IS
2010, ADVANCED SYNTHESIS & CATALYSIS, 352, 10, 1759-1769.

Catalytic olefin epoxidation with cationic molybdenum(VI) cis-dioxo complexes and ionic liquids

Gago, S; Balula, SS; Figueiredo, S; Lopes, AD; Valente, AA; Pillinger, M; Goncalves, IS
2010, APPLIED CATALYSIS A-GENERAL, 372, 1, 67-72.

Cyclopentadienyl molybdenum dicarbonyl eta(3)-allyl complexes as catalyst precursors for olefin epoxidation. Crystal structures of Cp ' Mo(CO)(2)(eta(3)-C3H5) (Cp ' = eta(5)-C5H4Me, eta(5)-C5Me5)

Neves, P; Pereira, CCL; Paz, FAA; Gago, S; Pillinger, M; Silva, CM; Valente, AA; Romao, CC; Goncalves, IS
2010, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 695, 21, 2311-2319.

Microwave-assisted molybdenum-catalysed epoxidation of olefins

Abrantes, M; Neves, P; Antunes, MM; Gago, S; Paz, FAA; Rodrigues, AE; Pillinger, M; Goncalves, IS; Silva, CM; Valente, AA
2010, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 320, 1-2, 19-26.

Complexation of crystal-like mesoporous phenylene-silica with Cr(CO)(3) and catalytic performance in the oxidation of cyclooctene

Coelho, AC; Balula, SS; Antunes, MM; Gerganova, TI; Bion, N; Ferreira, P; Pillinger, M; Valente, AA; Rocha, J; Goncalves, IS
2010, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 332, 1-2, 13-18.

Crystal and supramolecular structures of dioxomolybdenum(VI) and dioxotungsten(VI) complexes of dihydroxybenzoic acids

Monteiro, B; Cunha-Silva, L; Gago, S; Klinowski, J; Paz, FAA; Rocha, J; Goncalves, IS; Pillinger, M
2010, POLYHEDRON, 29, 2, 719-730.

Synthesis, Structure, and Catalytic Performance in Cyclooctene Epoxidation of a Molybdenum Oxide/Bipyridine Hybrid Material: {[MoO3(bipy)][MoO3(H2O)]}n

Abrantes, M; Amarante, TR; Antunes, MM; Gago, S; Paz, FAA; Margiolaki, I; Rodrigues, AE; Pillinger, M; Valente, AA; Goncalves, IS
2010, INORGANIC CHEMISTRY, 49, 15, 6865-6873.

Picosecond Dynamics of Dimer Formation in a Pyrene Labeled Polymer

Costa, T; de Melo, JSS; Castro, CS; Gago, S; Pillinger, M; Goncalves, IS
2010, JOURNAL OF PHYSICAL CHEMISTRY B, 114, 39, 12439-12447.

Investigation of Molybdenum Tetracarbonyl Complexes As Precursors to Mo-VI Catalysts for the Epoxidation of Olefins

Amarante, TR; Neves, P; Coelho, AC; Gago, S; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2010, ORGANOMETALLICS, 29, 4, 883-892.

Tripyridinium cis-tetrachloridodioxidomolybdate(VI) chloride

Fernandes, JA; Gomes, AC; Figueiredo, S; Gago, S; Ribeiro-Claro, PJA; Goncalves, IS; Paz, FAA
2010, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 66, M862-U1355.

Tetrapyridinium mu-oxido-di-mu-sulfato-bis[chloridodioxidomolybdate(VI)]

Fernandes, JA; Gomes, AC; Figueiredo, S; Gago, S; Lopes, AD; Pillinger, M; Ribeiro-Claro, PJA; Goncalves, IS; Paz, FAA
2010, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 66, M1005-U1354.

Synthesis and Catalytic Properties in Olefin Epoxidation of Octahedral Dichloridodioxidomolybdenum(VI) Complexes Bearing N,N-Dialkylamide Ligands: Crystal Structure of [Mo2O4(mu(2)-O)Cl-2(dmf)(4)]

Gago, S; Neves, P; Monteiro, B; Pessego, M; Lopes, AD; Valente, AA; Paz, FAA; Pillinger, M; Moreira, J; Silva, CM; Goncalves, IS
2009, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 29-30, 4528-4537.

Catalytic Epoxidation and Sulfoxidation Activity of a Dioxomolybdenum(VI) Complex Bearing a Chiral Tetradentate Oxazoline Ligand

Neves, P; Gago, S; Pereira, CCL; Figueiredo, S; Lemos, A; Lopes, AD; Goncalves, IS; Pillinger, M; Silva, CM; Valente, AA
2009, CATALYSIS LETTERS, 132, 1-2, 94-103.

Effect of an Ionic Liquid on the Catalytic Performance of Thiocyanatodioxomolybdenum(VI) Complexes for the Oxidation of Cyclooctene and Benzyl Alcohol

Monteiro, B; Gago, S; Neves, P; Valente, AA; Goncalves, IS; Pereira, CCL; Silva, CM; Pillinger, M
2009, CATALYSIS LETTERS, 129, 3-4, 350-357.

Amino acid-functionalized cyclopentadienyl molybdenum tricarbonyl complex and its use in catalytic olefin epoxidation

Abrantes, M; Paz, FAA; Valente, AA; Pereira, CCL; Gago, S; Rodrigues, AE; Klinowski, J; Pillinger, M; Goncalves, IS
2009, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 694, 12, 1826-1833.

Comparison of liquid-phase olefin epoxidation catalysed by dichlorobis-(dimethylformamide)dioxomolybdenum(VI) in homogeneous phase and grafted onto MCM-41

Monteiro, B; Balula, SS; Gago, S; Grosso, C; Figueiredo, S; Lopes, AD; Valente, AA; Pillinger, M; Lourenco, JP; Goncalves, IS
2009, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 297, 2, 110-117.

Liquid-phase oxidation catalysed by copper(II) immobilised in a pillared layered double hydroxide

Monteiro, B; Gago, S; Balula, SS; Valente, AA; Goncalves, IS; Pillinger, M
2009, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 312, 1-2, 23-30.

Structural and Photoluminescence Studies of a Europium(III) Tetrakis (beta-diketonate) Complex with Tetrabutylammonium, Imidazolium, Pyridinium and Silica-Supported Imidazolium Counterions

Bruno, SM; Ferreira, RAS; Paz, FAA; Carlos, LD; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2009, INORGANIC CHEMISTRY, 48, 11, 4882-4895.

Heterometallic complexes involving iron(II) and rhenium(VII) centers connected by mu-oxido bridges

Goncalves, IS; Lopes, AD; Amarante, TR; Paz, FAA; Silva, NJO; Pillinger, M; Gago, S; Palacio, F; Kuhn, FE; Romao, CC
2009, DALTON TRANSACTIONS, 46, 10199-10207.

Mo-4(eta(3)-allyl)(4)Cl-2(OH)(2)(CO)(8): the first cubane-type Mo2+ organometallic complex with mu(3)-OH and mu(3)-Cl bridges

Amarante, TR; Goncalves, IS; Paz, FAA
2009, ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 65, M168-M170.

2-(1H-Pyrazol-3-yl)pyridinium chloride monohydrate

Amarante, TR; Goncalves, IS; Paz, FAA
2009, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 65, O1962-U3860.

4,4 '-Di-tert-butyl-2,2 '-bipyridine

Amarante, TR; Figueiredo, S; Lopes, AD; Goncalves, IS; Paz, FAA
2009, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 65, O2047-U4597.

Microwave-Assisted Synthesis and Crystal Structure of Oxo(diperoxo)(4,4 '-di-tert-butyl-2,2 '-bipyridine)-molybdenum(VI)

Amarante, TR; Paz, FAA; Gago, S; Goncalves, IS; Pillinger, M; Rodrigues, AE; Abrantes, M
2009, MOLECULES, 14, 9, 3610-3620.

MCM-41 derivatised with pyridyl groups and its use as a support for luminescent europium(III) complexes

Bruno, SM; Coelho, AC; Ferreira, RAS; Carlos, LD; Pillinger, M; Valente, AA; Ribeiro-Claro, P; Goncalves, IS
2008, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 24, 3786-3795.

Spectroscopic studies of an europium(III) tris-beta-diketonate complex bearing a pyrazolylpyridine ligand

dos Santos, AM; Coelho, AC; Paz, FAA; Rocha, J; Goncalves, IS; Carlos, LD
2008, JOURNAL OF ALLOYS AND COMPOUNDS, 451, 1-2, 344-346.

Luminescence properties of the TRIMEB inclusion compound of a europium tris-beta-diketonate

Braga, SS; Coelho, AC; Goncalves, IS; Santos, G; Fonseca, FJ; Andrade, AM; Peres, M; Simoes, W; Monteiro, T; Pereira, L
2008, JOURNAL OF NON-CRYSTALLINE SOLIDS, 354, 19-25, 2736-2739.

Organic light emitting diodes with europium (III) emissive layers based on beta-diketonate complexes: The influence of the central ligand

Santos, G; Fonseca, FJ; Andrade, AM; Deichmann, VAF; Akcelrud, L; Braga, SS; Coelho, AC; Goncalves, IS; Peres, M; Simoes, W; Monteiro, T; Pereira, L
2008, JOURNAL OF NON-CRYSTALLINE SOLIDS, 354, 19-25, 2897-2900.

Synthesis, characterization and antitumor activity of 1,2-disubstituted ferrocenes and cyclodextrin inclusion complexes

Petrovski, Z; de Matos, MRPN; Braga, SS; Pereira, CCL; Matos, ML; Goncalves, IS; Pillinger, M; Alves, PM; Romao, CC
2008, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 693, 4, 675-684.

Synthesis and catalytic properties of manganese(II) and oxovanadium(IV) complexes anchored to mesoporous MCM-41

Fernandes, TA; Nunes, CD; Vaz, PD; Calhorda, MJ; Brandao, P; Rocha, J; Goncalves, IS; Valente, AA; Ferreira, LP; Godinho, M; Ferreira, P
2008, MICROPOROUS AND MESOPOROUS MATERIALS, 112, 1-3, 14-25.

Synthesis, characterisation and luminescence properties of MCM-41 impregnated with an Eu3+ beta-diketonate complex

Bruno, SM; Ferreira, RAS; Carlos, LD; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2008, MICROPOROUS AND MESOPOROUS MATERIALS, 113, 1-3, 453-462.

Investigation of layered double hydroxides intercalated by oxomolybdenum catecholate complexes

Monteiro, B; Gago, S; Paz, FAA; Bilsborrow, R; Goncalves, IS; Pillinger, M
2008, INORGANIC CHEMISTRY, 47, 19, 8674-8686.

Complex formation between heptakis(2,6-di-O-methyl)-beta-cyclodextrin and cyclopentadienyl molybdenum(II) dicarbonyl complexes: Structural studies and cytotoxicity evaluations

Pereira, CCL; Diogo, CV; Burgeiro, A; Oliveira, PJ; Marques, MPM; Braga, SS; Paz, FAA; Pillinger, M; Goncalves, IS
2008, ORGANOMETALLICS, 27, 19, 4948-4956.

Preparation and photophysical characterisation of Zn-Allayered double hydroxides intercalated by anionic pyrene derivatives

Gago, S; Costa, T; de Melo, JS; Goncalves, IS; Pillinger, M
2008, JOURNAL OF MATERIALS CHEMISTRY, 18, 8, 894-904.

1-hydroxy-1,1,3,3,3-pentaphenyldisiloxane, [Si2O(OH)(Ph)(5)], at 100 K

Coelho, AC; Amarante, TR; Klinowski, J; Goncalves, IS; Paz, FAA
2008, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 64, O237-U4707.

1-hydroxy-1,1,3,3,3-pentaphenyldisiloxane, [Si2O(OH)(Ph)(5)], at 150 K

Amarante, TR; Coelho, AC; Klinowski, J; Goncalves, IS; Paz, FA
2008, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 64, O239-U4733.

Immobilisation of Ferricinium Cation into ETS-10 by Ion Exchange under Microwave Irradiation

Coelho, AC; Brandao, P; dos Santos, AM; Rocha, J; Goncalves, IS
2008, ADVANCED MATERIALS FORUM IV, 587-588, 453-457.

Cyclodextrin encapsulation of biomimetic organometallic cancer drug candidates

Braga, SS; Paz, FAA; Mokal, V; Pillinger, M; Marques, MPM; Romao, CC; Goncalves, IS
2007, DRUGS OF THE FUTURE, 32, 101-101.

Characterization of a chiral menthyldimethyltin molybdate and its use as an olefin epoxidation catalyst

Abrantes, M; Valente, AA; Pillinger, M; Romao, CC; Goncalves, IS
2007, CATALYSIS LETTERS, 114, 1-2, 103-109.

Structural and catalytic studies of a trimethyltin vanadate coordination polymer

Abrantes, M; Balula, MS; Valente, AA; Paz, FAA; Pillinger, M; Romao, CC; Rocha, J; Goncalves, IS
2007, JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 17, 1, 215-222.

Synthesis and structural characterization of new mixed-ring indenyl derivatives of molybdenum containing phosphorus ligands

Goncalves, IS; Pereira, CCL; Gamelas, CA; Hazell, A; Romao, CC
2007, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 692, 7, 1593-1600.

New chloro and triphenylsiloxy derivatives of dioxomolybdenum(VI) chelated with pyrazolylpyridine ligands: Catalytic applications in olefin epoxidation

Bruno, SM; Pereira, CCL; Balula, MS; Nolasco, M; Valente, AA; Hazell, A; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2007, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 261, 1, 79-87.

Synthesis and catalytic properties in olefin epoxidation of dioxomolybdenurn(VI) complexes bearing a bidentate or tetradentate salen-type ligand

Bruno, SM; Balula, SS; Valente, AA; Paz, FAA; Pillinger, M; Sousa, C; Klinowski, J; Freire, C; Ribeiro-Claro, P; Goncalves, IS
2007, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 270, 1-2, 185-194.

A highly efficient dioxo(mu-oxo)molybdenum(VI) dimer catalyst for olefin epoxidation

Pereira, CCL; Balula, SS; Paz, FAA; Valente, AA; Pillinger, M; Klinowski, J; Goncalves, IS
2007, INORGANIC CHEMISTRY, 46, 21, 8508-8510.

A combined theoretical-experimental study of the inclusion of niobocene dichloride in native and permethylated beta-cyclodextrins

Pereira, CCL; Nolasco, M; Braga, SS; Almeida Paz, FA; Ribeiro-Claro, P; Pillinger, M; Goncalves, IS
2007, ORGANOMETALLICS, 26, 17, 4220-4228.

Influence of cyclodextrins on catalytic olefin epoxidation with metal-carbonyl compounds. Crystal structure of the TRIMEB complex with CpFe(CO)(2)Cl

Balula, SS; Coelho, AC; Braga, SS; Hazell, A; Valente, AA; Pillinger, M; Seixas, JD; Romao, CC; Goncalves, IS
2007, ORGANOMETALLICS, 26, 27, 6857-6863.

Redetermination of dipotassium mu-oxo-bis[aqua(oxalato-kappa O-2,O ') dioxomolybdate(VI)] at 150 K

Cunha-Silva, L; Monteiro, B; Pillinger, M; Goncalves, IS; Rocha, J; Paz, FAA
2007, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 63, M376-M378.

Ethyl [3-(2-pyridyl)pyrazol-1-yl]acetate monohydrate

Coelho, AC; Goncalves, IS; Paz, FAA
2007, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 63, o1380-o1382.

(2,2 '-bipyridine)tetracarbonylmolybdenum(0)

Braga, SS; Coelho, AC; Goncalves, IS; Paz, FAA
2007, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 63, m780-m782.

Dynamics of short as compared with long poly(acrylic acid) chains hydrophobically modified with pyrene, as followed by fluorescence techniques

de Melo, JS; Costa, T; Francisco, A; Macanita, AL; Gago, S; Goncalves, IS
2007, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 9, 11, 1370-1385.

Structural studies of beta-cyclodextrin and permethylated beta-cyclodextrin inclusion compounds of cyclopentadienyl metal carbonyl complexes

Braga, SS; Paz, FAA; Pillinger, M; Seixas, JD; Romao, CC; Goncalves, IS
2006, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 8, 1662-1669.

Structural studies of [CpMoL2(CO)(2)](+) (L = NCMe, L-2 =,2,2 '-biimidazole) complexes and their inclusion compounds with cyclodextrins

Pereira, CCL; Braga, SS; Paz, FAA; Pillinger, M; Klinowski, J; Goncalves, IS
2006, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 21, 4278-4288.

Modification of the luminescence properties of an Europium(III) tris(beta-diketonate) complex by inclusion in gamma-cyclodextrin and 2,3,6-trimethyl-gamma-cyclodextrin

Fernandes, JA; Braga, SS; Ferreira, RAS; Pillinger, M; Carlos, LD; Ribeiro-Claro, P; Goncalves, IS
2006, JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 55, 3-4, 329-333.

Dioxomolybdenum(VI) modified mesoporous materials for the catalytic epoxidation of olefins

Bruno, SM; Fernandes, JA; Martins, LS; Goncalves, IS; Pillinger, M; Ribeiro-Claro, P; Rocha, J; Valente, AA
2006, CATALYSIS TODAY, 114, 2-3, 263-271.

beta-cyclodextrin and permethylated beta-cyclodextrin inclusion compounds of a cyclopentadienyl molybdenum tricarbonyl complex and their use as cyclooctene epoxidation catalyst precursors

Braga, SS; Gago, S; Seixas, JD; Valente, AA; Pillinger, M; Santos, TM; Goncalves, IS; Romao, CC
2006, INORGANICA CHIMICA ACTA, 359, 15, 4757-4764.

Synthesis and characterization of layered double hydroxides intercalated by an oxomolybdenum complex

Gago, S; Dias, AS; Monteiro, B; Pillinger, M; Valente, AA; Santos, TM; Goncalves, IS
2006, JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 67, 5-6, 1011-1015.

Immobilisation of methyltrioxorhenium on functionalised MCM-41

Gago, S; Fernandes, JA; Abrantes, M; Kuhn, FE; Ribeiro-Claro, P; Pillinger, M; Santos, TM; Goncalves, IS
2006, MICROPOROUS AND MESOPOROUS MATERIALS, 89, 1-3, 284-290.

Molybdenum(VI) oxides bearing 1,4,7-triazacyclononane and 1,1,1-tris(aminomethyl)ethane ligands: Synthesis and catalytic applications

Petrovski, Z; Valente, AA; Pillinger, M; Dias, AS; Rodrigues, SS; Romao, CC; Goncalves, IS
2006, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 249, 1-2, 166-171.

Synthesis and catalytic properties in olefin epoxidation of chiral oxazoline dioxomolybdenum(VI) complexes

Bruno, SM; Monteiro, B; Balula, MS; Pedro, FM; Abrantes, M; Valente, AA; Pillinger, M; Ribeiro-Claro, P; Kuhn, FE; Goncalves, IS
2006, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 260, 1-2, 11-18.

beta-Cyclodextrin inclusion of europium(III) tris(beta-diketonate)-bipyridine

Fernandes, JA; Braga, SS; Pillinger, M; Ferreira, RAS; Carlos, LD; Hazell, A; Ribeiro-Claro, P; Goncalves, IS
2006, POLYHEDRON, 25, 6, 1471-1476.

Luminescence properties of composites made of a europium(III) complex and electroluminescent polymers with different energy gaps

Morgado, J; Charas, A; Fernandes, JA; Goncalves, IS; Carlos, LD; Alcacer, L
2006, JOURNAL OF PHYSICS D-APPLIED PHYSICS, 39, 16, 3582-3587.

Catalytic properties of the dioxomolybdenum siloxide MoO2(OSiPh3)(2) and its 2,2 '-bipyridine adduct MoO2(OSiPh3)(2)(bpy)

Bruno, SM; Monteiro, B; Balula, MS; Lourenco, C; Valente, AA; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2006, MOLECULES, 11, 4, 298-308.

Synthesis and structure of a sodium complex of an aromatic beta-diketone and pyrazolylpyridine

Coelho, AC; Paz, FAA; Klinowski, J; Pillinger, M; Goncalves, IS
2006, MOLECULES, 11, 7, 528-538.

Microwave assisted synthesis of molybdenum and tungsten tetracarbonyl complexes with a pyrazolylpyridine ligand. Crystal structure of cis-[Mo(CO)4{ethyl[3-(2-pyridyl)-1-pyrazolyl]acetate}]

Coelho, AC; Paz, FAA; Klinowski, J; Pillinger, M; Goncalves, IS
2006, MOLECULES, 11, 12, 940-952.

Kinetics of cyclooctene epoxidation with tert-butyl hydroperoxide in the presence of [MoO2X2L]-type catalysts (L = bidentate Lewis base)

Al-Ajlouni, A; Valente, AA; Nunes, CD; Pillinger, M; Santos, AM; Zhao, J; Romao, CC; Goncalves, IS; Kuhn, FE
2005, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 9, 1716-1723.

Experimental and theoretical study of the encapsulation of a linear oligo(ferrocenylsilane) trimer with beta-cyclodextrin

Fernandes, JA; Lima, S; Braga, SS; Pillinger, M; Rodriguez-Borges, JE; Ribeiro-Claro, P; Teixeira-Dias, JJC; Goncalves, IS
2005, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 23, 4729-4734.

CpMo(CO)(3)Cl as a precatalyst for the epoxidation of olefins

Valente, AA; Seixas, JD; Goncalves, IS; Abrantes, M; Pillinger, M; Romao, CC
2005, CATALYSIS LETTERS, 101, 1-2, 127-130.

Emission quantum yield of a europium(III) tris-beta-diketonate complex bearing a 1,4-diaza-1,3-butadiene: Comparison with theoretical prediction

Carlos, LD; Fernandes, JA; Ferreira, RAS; Malta, OL; Goncalves, IS; Ribeiro-Claro, P
2005, CHEMICAL PHYSICS LETTERS, 413, 1-3, 22-24.

Synthesis and characterization of the inclusion compound of a ferrocenyldiimine dioxomolybdenum complex with heptakis-2,3,6-tri-O-methyl-beta-cyclodextrin

Petrovski, Z; Braga, SS; Santos, AM; Rodrigues, SS; Goncalves, IS; Pillinger, M; Kuhn, FE; Romao, CC
2005, INORGANICA CHIMICA ACTA, 358, 4, 981-988.

Investigation of europium(III) and gadolinium(III) complexes with naphthoyltrifluoroacetone and bidentate heterocyclic amines

Fernandes, JA; Ferreira, RAS; Pillinger, M; Carlos, LD; Jepsen, J; Hazell, A; Ribeiro-Claro, P; Goncalves, IS
2005, JOURNAL OF LUMINESCENCE, 113, 1-2, 50-63.

Synthesis and reactivity of mixed-ring indenyl complexes of molybdenocene

Goncalves, IS; Gamelas, CA; Pereira, CCL; Romao, CC
2005, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690, 7, 1718-1725.

Inclusion of molybdenocene dichloride (Cp2MoCl2) in 2-hydroxypropyl- and trimethyl-beta-cyclodextrin: Structural and biological properties

Braga, SS; Marques, MPM; Sousa, JB; Pillinger, M; Teixeira-Dias, JJC; Goncalves, IS
2005, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690, 12, 2905-2912.

Inclusion complex formation of diferrocenyldimethylsilane with beta-cyclodextrin

Fernandes, JA; Lima, S; Braga, SS; Ribeiro-Claro, P; Rodriguez-Borges, JE; Teixeira, C; Pillinger, M; Teixeira-Dias, JJC; Goncalves, IS
2005, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 690, 21-22, 4801-4808.

Preparation and catalytic studies of bis(halogeno) dioxomolybdenum(VI)-diimine complexes

Petrovski, Z; Pillinger, M; Valente, AA; Goncalves, IS; Hazell, A; Romao, CC
2005, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 227, 1-2, 67-73.

Synthesis, characterization and catalytic studies of bis(chloro)dioxomolybdenum(VI)-chiral diimine complexes

Gago, S; Rodriguez-Borges, JE; Teixeira, C; Santos, AM; Zhao, J; Pillinger, M; Nunes, CD; Petrovski, Z; Santos, TM; Kuhn, FE; Romao, CC; Goncalves, IS
2005, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 236, 1-2, 1-6.

Organotin-oxomolybdate coordination polymers as catalysts for the epoxidation of cyclooctene

Abrantes, M; Valente, AA; Goncalves, IS; Pillinger, M; Romao, CC
2005, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 238, 1-2, 51-55.

Immobilization of lanthanide ions in a pillared layered double hydroxide

Gago, S; Pillinger, M; Ferreira, RAS; Carlos, LD; Santos, TM; Goncalves, IS
2005, CHEMISTRY OF MATERIALS, 17, 23, 5803-5809.

Highly luminescent tris(beta-diketonate)europium(III) complexes immobilized in a functionalized mesoporous silica

Gago, S; Fernandes, JA; Rainho, JP; Ferreira, RAS; Pillinger, M; Valente, AA; Santos, TM; Carlos, LD; Ribeiro-Claro, PJA; Goncalves, IS
2005, CHEMISTRY OF MATERIALS, 17, 20, 5077-5084.

Inclusion complexation of dimeric and trimeric oligo(ferrocenyldimethylsilanes) with gamma-cyclodextrin

Fernandes, JA; Lima, S; Braga, SS; Pillinger, M; Ribeiro-Claro, P; Rodriguez-Borges, JE; Lopes, AD; Teixeira-Dias, JJC; Goncalves, IS
2005, ORGANOMETALLICS, 24, 23, 5673-5677.

Synthesis of ferrocenyldiimine metal carbonyl complexes and an investigation of the Mo adduct encapsulated in cyclodextrin

Petrovski, Z; Braga, SS; Rodrigues, SS; Pereira, CCL; Goncalves, IS; Pillinger, M; Freire, C; Ramao, CC
2005, NEW JOURNAL OF CHEMISTRY, 29, 2, 347-354.

Structure-photoluminescence relationship in Eu(III) beta-diketonate-based organic-inorganic hybrids. Influence of the synthesis method: carboxylic acid solvolysis versus conventional hydrolysis

Fu, LS; Ferreira, RAS; Silva, NJO; Fernandes, JA; Ribeiro-Claro, P; Goncalves, IS; Bermudez, VD; Carlos, LD
2005, JOURNAL OF MATERIALS CHEMISTRY, 15, 30, 3117-3125.

Zn-Al layered double hydroxide pillared by different dicarboxylate anions

Gago, S; Pillinger, M; Santos, TM; Goncalves, IS
2004, CERAMICS-SILIKATY, 48, 4, 155-158.

Synthesis and properties of Zn-Al layered double hydroxides containing ferrocenecarboxylate anions

Gago, S; Pillinger, M; Santos, TM; Rocha, J; Goncalves, IS
2004, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 7, 1389-1395.

Spectroscopic studies of europium(III) and gadolinium(III) tris-beta-diketonate complexes with diazabutadiene ligands

Fernandes, JA; Ferreira, RAS; Pillinger, M; Carlos, LD; Goncalves, IS; Ribeiro-Claro, PJA
2004, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 19, 3913-3919.

Incorporation of a (cyclopentadienyl)molybdenum oxo complex in MCM-41 and its use as a catalyst for olefin epoxidation

Abrantes, M; Gago, S; Valente, AA; Pillinger, M; Goncalves, IS; Santos, TM; Rocha, J; Romao, CC
2004, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 24, 4914-4920.

Synthesis and characterization of a manganese(II) acetonitrile complex supported on functionalized MCM-41

Gago, S; Zhang, YM; Santos, AM; Kohler, K; Kuhn, FE; Fernandes, JA; Pillinger, M; Valente, AA; Santos, TM; Ribeiro-Claro, PJA; Goncalves, IS
2004, MICROPOROUS AND MESOPOROUS MATERIALS, 76, 1-3, 131-136.

Epoxidation of cyclooctene catalyzed by dioxomolybdenum(VI) complexes in ionic liquids

Valente, AA; Petrovski, Z; Branco, LC; Afonso, CAM; Pillinger, M; Lopes, AD; Romao, CC; Nunes, CD; Goncalves, IS
2004, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 218, 1, 5-11.

Immobilization of oxomolybdenum species in a layered double hydroxide pillared by 2,2 '-bipyridine-5,5 '-dicarboxylate anions

Gago, S; Pillinger, M; Valente, AA; Santos, TM; Rocha, J; Goncalves, IS
2004, INORGANIC CHEMISTRY, 43, 17, 5422-5431.

Dichloro and dimethyl dioxomolybdenum(VI)-diazabutadiene complexes as catalysts for the epoxidation of olefins

Valente, AA; Moreira, J; Lopes, AD; Pillinger, M; Nunes, CD; Romao, CC; Kuhn, FE; Goncalves, IS
2004, NEW JOURNAL OF CHEMISTRY, 28, 2, 308-313.

Preparation and characterization of organotin - Oxomolybdate coordination polymers and their use in sulfoxidation catalysis

Abrantes, M; Valente, AA; Pillinger, M; Goncalves, IS; Rocha, J; Romao, CC
2003, CHEMISTRY-A EUROPEAN JOURNAL, 9, 12, 2685-+.

Molecular structure - Activity relationships for the oxidation of organic compounds using mesoporous silica catalysts derivatised with bis(halogeno)dioxomolybdenum(VI) complexes

Nunes, CD; Valente, AA; Pillinger, M; Rocha, J; Goncalves, IS
2003, CHEMISTRY-A EUROPEAN JOURNAL, 9, 18, 4380-4390.

Dioxomolybdenum(VI)-modified mesoporous MCM-41 and MCM-48 materials for the catalytic epoxidation of olefins

Nunes, CD; Pillinger, M; Valente, AA; Rocha, J; Lopes, AD; Goncalves, IS
2003, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 21, 3870-3877.

Cyanide-isocyanide isomers in polynuclear complexes. Reactivity and theoretical studies

Calhorda, MJ; Costa, PJ; Drew, MGB; Felix, V; Gamelas, CA; Goncalves, IS; Pereira, CCL; Romao, CC
2003, INORGANICA CHIMICA ACTA, 356, 297-307.

Bimetallic transition metal-ruthenium(II) complexes containing bridging bipyrimidine ligands

Nunes, CD; Pillinger, M; Hazell, A; Jepsen, J; Santos, TM; Madureira, J; Lopes, AD; Goncalves, IS
2003, POLYHEDRON, 22, 20, 2799-2807.

Preparation and catalytic properties of a new dioxomolybdenum(VI) complex covalently anchored to mesoporous MCM-48

Nunes, CD; Pillinger, M; Valente, AA; Lopes, AD; Goncalves, IS
2003, INORGANIC CHEMISTRY COMMUNICATIONS, 6, 9, 1228-1233.

Interactions of omeprazole and precursors with beta-cyclodextrin host molecules

Braga, SS; Ribeiro-Claro, P; Pillinger, M; Goncalves, IS; Fernandes, AC; Pereira, F; Romao, CC; Correia, PB; Teixeira-Dias, JJC
2003, JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 47, 1-2, 47-52.

Encapsulation of sodium nimesulide and precursors in beta-cyclodextrin

Braga, SS; Ribeiro-Claro, P; Pillinger, M; Goncalves, IS; Pereira, F; Fernandes, AC; Romao, CC; Correia, PB; Teixeira-Dias, JJC
2003, ORGANIC & BIOMOLECULAR CHEMISTRY, 1, 5, 873-878.

Ordered benzene-silica hybrids with molecular-scale periodicity in the walls and different mesopore sizes

Bion, N; Ferreira, P; Valente, A; Goncalves, IS; Rocha, J
2003, JOURNAL OF MATERIALS CHEMISTRY, 13, 8, 1910-1913.

Epoxidation of olefins catalyzed by molybdenum-siloxane compounds

Abrantes, M; Valente, AA; Pillinger, M; Goncalves, IS; Rocha, J; Romao, CC
2002, INORGANIC CHEMISTRY COMMUNICATIONS, 5, 12, 1069-1072.

Usamos cookies para atividades de marketing e para lhe oferecer uma melhor experiência de navegação. Ao clicar em “Aceitar Cookies” você concorda com nossa política de cookies. Leia sobre como usamos cookies clicando em "Política de Privacidade e Cookies".