Production of ultra-deep sulfur-free diesels using a sustainable catalytic system based on UiO-66(Zr)

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abstract

The porous metal-organic framework UiO-66(Zr) obtained via non modulated synthesis, has revealed to be a notable heterogeneous catalyst, enabling extremely fast and very efficient desulfurization of a multicomponent model diesel and also a real diesel fuel.

keywords

METAL-ORGANIC FRAMEWORKS; OXIDATIVE DESULFURIZATION PROCESS; SOLVENT-EXTRACTION; IONIC LIQUIDS; GAS OIL; CHEMICAL OXIDATION; LIGHT OILS; FUELS; POLYOXOMETALATE; MIL-101

subject category

Chemistry

authors

Granadeiro, CM; Ribeiro, SO; Karmaoui, M; Valenca, R; Ribeiro, JC; de Castro, B; Cunha-Silva, L; Balula, SS

our authors

foto Mohamed Karmaoui

Mohamed Karmaoui

Post-doc Fellowship

Groups

Projects

Desulfurization of diesel using green heterogeneous oxidative catalytic processes (PTDC/EQU-EQU/121677/2010)
Design of Metal-Organic Framework materials from the micro- to nano-scale: optimization of gas adsorption and catalytic properties (PTDC/CTM/100357/2008)

acknowledgements

The work was partly financed by FEDER (Fundo Europeu de Desenvolvimento Regional) through COMPETE (Programa Operacional Factores de Competividade) and by national funds through the FCT (Fundacao para a Ciencia e a Tecnologia) within the projects FCOMP-01-0124-FEDER-020658 (FCT ref. PTDC/EQU-EQU/121677/2010), FCOMP-01-0124-FEDER-013026 (FCT ref. PTDC/CTM/100357/2008) and REQUIMTE/LAQV (Ref. FCT UID/QUI/50006/2013), and the fellowships SFRH/BPD/73191/2010 (to CMG), SFRH/BD/95571/2013 (to SOR) and SFRH/BPD/74477/2010 (to MK).

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Publication Details

type
Journal Article
year
2015
journal
CHEMICAL COMMUNICATIONS
volume
51
publisher
ROYAL SOC CHEMISTRY
issn
1359-7345
issue
72
digital object identifier
10.1039/c5cc03958d
web of science article identifier
WOS:000360113100023

Journal Metrics (JCR 2019)

Journal Impact Factor
5.996
Journal Impact Factor (5 yrs)
5.818
category normalized journal percentile
81.073

Citations

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