A comparative study of co-precipitation and sol-gel synthetic approaches to fabricate cerium-substituted Mg-Al layered double hydroxides with luminescence properties

  1. Home

abstract

Mg/Al/Ce layered double hydroxides (LDHs) intercalated with carbonate and hydroxide anions were synthesized using co-precipitation and sol-gel method. The obtained materials were characterized by thermogravimetric (TG) analysis, X-ray diffraction (XRD) analysis, fluorescence spectroscopy (FLS) and scanning electron microscopy (SEM). The chemical composition, microstructure and luminescent properties of these LDHs were investigated and discussed. The Ce-3 (+) substitution effects were investigated in the Mg3Al1-xCex LDHs by changing the Ce-3 (+) concentration in the metal cation layers from 0.05 to 10 mol%. It was demonstrated, that luminescence properties of cerium-substituted LDHs depend on the morphological features of the host lattice.

keywords

LIGHT-EMITTING-DIODES; X-RAY-DIFFRACTION; OPTICAL-PROPERTIES; GARNET PHOSPHORS; PHOTOLUMINESCENCE; FILMS; LDH; INTERCALATION; NANOCOMPOSITE; NANOPARTICLES

subject category

Chemistry; Materials Science; Mineralogy

authors

Smalenskaite, A; Vieira, DEL; Salak, AN; Ferreira, MGS; Katelnikovas, A; Kareiva, A

our authors

foto Andrei Salak

Andrei Salak

Researcher
foto Daniel Eduardo Loureiro Vieira

Daniel Eduardo Loureiro Vieira

PhD Student
foto Mário Guerreiro Silva Ferreira

Mário Guerreiro Silva Ferreira

Full professor

Groups

2 - Multifunctional Ferroic Ceramics and Nanostructures
3 - Carbon Materials, Composites and Functional Coatings

Projects

TUneable Multiferroics based on oxygen OCtahedral Structures (TUMOCS)
New nanocontainers with extended functionality based on layered double hydroxides for application in corrosion protection (NANOCONCOR)

acknowledgements

The work has been done in frame of the project TUMOCS. This project has received funding from the European Union's Horizon 2020 - Research and innovation Framework Programme under the Marie Sklodowska-Curie grant agreement No 645660. The financial support of P2020 COMPETE and FCT-Portugal through project POCI-01-0145-FEDER-016686 - PTDC/CTM-NAN/2418/2014 (NANOCONCOR) is also acknowledged.

Share this project:

Related Publications

Publication Details

type
Journal Article
year
2017
journal
APPLIED CLAY SCIENCE
volume
143
publisher
ELSEVIER SCIENCE BV
issn
0169-1317
isbn
1872-9053
digital object identifier
10.1016/j.clay.2017.03.036
web of science article identifier
WOS:000403516000021

Journal Metrics (JCR 2019)

Journal Impact Factor
4.605
Journal Impact Factor (5 yrs)
4.549
category normalized journal percentile
78.885

Citations

Social Interaction

We use cookies for marketing activities and to offer you a better experience. By clicking “Accept Cookies” you agree with our cookie policy. Read about how we use cookies by clicking "Privacy and Cookie Policy".


Privacy and Cookie Policy

Personal data

CICECO-Aveiro Institute of Materials respects your privacy, ensuring confidentiality of personal data you share with the institution through this way, not collecting any personal information about you without your consent, under the terms required by General Data Protection Regulations (RGPD).

The data collected in forms are intended exclusively for processing user requests and will not be used for any other purpose, always safeguarding their confidentiality, under the terms of the protection conferred by the aforementioned regulation.

The collection and processing of data is the responsibility of CICECO and its storage is properly protected, only authorized CICECO employees can access the information within the scope of their functions, always being clear in the respective collection forms the purposes for which they are intended. The remaining issues to be considered in this matter will be handled by the University of Aveiro in accordance with the regime established by the GDPR.

Cookies policy

Cookies are small files with alphanumeric information that are stored on your computer's hard drive by your browser and are intended to improve the user experience and enhance website navigation.

Collection and use of technical information

The cookies used on CICECO are anonymous, and no information about our users that allows their personal identification is stored in them.

The technical information recorded consists of:

  • iP (Internet Protocol) address of the visitor;
  • the type of internet browser used by the website visitor and the respective operating system used;
  • the date and time of the consultation;
  • the pages visited on the site and the documents downloaded
  • The technical information collected is used for statistical purposes only.

Cookies used

Session cookies

These cookies are used to record user preferences, such as the language in which websites are displayed or to maintain authenticated user sessions, and are automatically deleted when the browser is closed.

Persistent cookies

These cookies store information that is needed between sessions. For example, a persistent cookie is set to record that you have been made aware of the cookie policy so that the message regarding this policy is not shown again the next time you visit the website. This cookie remains on the computer until it reaches its expiry date or is deleted by the user.

Data protection

The present privacy policy covers the Information System of the University of Aveiro (SIUA), governed by the General Data Protection Regulations (RGPD) Regulation (EU) No. 2016/679, of April 27th, 2016.

Data Protection Officer

The University of Aveiro has a Data Protection Officer (DPO), who ensures compliance of the processing of personal data with the legislation in force, and is available through the following email address epd@ua.pt.

Close