Anabela Tavares Aguiar Valente

Principal Researcher

Short CV

Her education background includes a 5-year degree in Chemical Engineering at the Universidade Nova de Lisboa (Portugal), and a PhD degree in Chemical Engineering-Catalysis from the same university (supervisor: Prof. Joaquim Vital). Afterwards she carried out post-doctoral work in Materials Science and Engineering, at the University of Aveiro (UA, Department of Chemistry, Portugal; supervised by Prof. João Rocha). In 2002, she became equated to Assistant Investigator at the UA, Centre for Research in Ceramics and Composite Materials (CICECO), and since 2015 she is Principal Investigator. She develops applied scientific research work in homogeneous and heterogeneous catalysis. She has supervised MSc, PhD students and post-doctoral fellows, and has been involved in research projects as team member or coordinator. She is (co-)author of ca.200 SCI papers, 230 communications in (inter)national scientific meetings, patent, book chapter.

Main scientific interests: oxidation catalysis, acid-base catalysis, catalytic routes for the chemical valorisation of biomass, synthesis and characterisation of materials.

Scientific Interests

- Synthesis and characterisation of heterogeneous catalysts.
- Homogeneous and heterogeneous catalysis: oxidation and acid-base reactions.
- Liquid-phase catalytic processing of biomass-derived compounds: oxidation of monoterpenes, conversion of saccharides into furan derivatives and bioesters, isomerization of sugars.

Present Research Group

TEAM:

Anabela A. Valente, Researcher.

Patrícia dos Santos Neves, Researcher.

Maria Margarida F. P. M. Antunes, Researcher.

Ana Sofia M. Bruno, P, Researcher.

Andreia de Freitas Silva Magalhães, CI of project nº 030075 (POCI-01-0145-FEDER-030075) of CICECO – Aveiro Institute of Materials

Supervisions:

Diana Gomes, BI/MSc grant of project nº 030075 (POCI-01-0145-FEDER-030075). Supervisors: Anabela A. Valente, Patrícia Neves, Martyn Pillinger (CICECO).

Martinique Nunes, BI/MSc grant of project nº 030075 (POCI-01-0145-FEDER-030075). Supervisors: Anabela A. Valente, Patrícia Neves, Isabel Gonçalves (CICECO).

Inês Vieira da Silva, MSc student. Thesis research work developed at the company Bresfor (supervisor at Bresfor, Inês Morais)

Carolina Duarte Bernardino, MSc student. Supervisors: Anabela A. Valente, Margarida Antunes (CICECO).

Main present collaborators

University of Aveiro, Portugal - Martyn Pillinger, Isabel S. Gonçalves, Filipe A. A. Paz, Luís Mafra, Carlos M. Silva (CICECO); Silvia M. Rocha (QOPNA/LAQV-REQUIMTE).

Centro de Química Estrutural, Instituto Superior Técnico, University of Lisbon, Portugal – Filipa Ribeiro, Auguste Fernandes.

Institut für Chemie and IRIS Adlershof, Humboldt-Universität zu Berlin, Germany - Nicola Pinna, Patrícia Russo.

Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Poland - Wiesław Łasocha.

Inorganic Chemistry Department, Taras Shevchenko National University of Kyiv, Ukraine - Andrey B. Lysenko.

Teaching Activity

Courses of Integrated Masters in Chemical Engineering:
Mass transport (recitations);
Separation Processes I (recitations);
Dissertation.

Present projects

Projecto Bosch, SGH – Smart Green Homes – Projecto nº 7678 (POCI-01-0247-FEDER-007678), Programa Bosch Termotecnologia, S.A. (FEDER, POCI). Desenvolvimento de sistema de adsorção para purificação do ar. Universidade de Aveiro. Member.

Bio-derived olefins conversion using reaction-induced self-separating catalysts: BiOle_AcidOxCat; reference POCI-01-0145-FEDER-030075 (FCT/MEC, POCI, FEDER/FNR, OE); University of Aveiro. Co-Investigator.

Stimuli-activated systems for carbon monoxide therapy: SASCOT; reference PTDC/QUI-QOR/28031/2017 (CENTRO 2020 Regional Operational Programme, FCT/MEC, OE); University of Aveiro and University of Coimbra. Member.

Selected Publications

http://www.researcherid.com/rid/H-5922-2013

Selected publications (2015/20):

A. F. Silva, P. Neves, S. M. Rocha, C. M. Silva, A. A. Valente, “Optimization of continuous-flow heterogeneous catalytic oligomerization of 1-butene by design of experiments and response surface methodology”, Fuel 259 (2020) 116256 in press.

J. M. Pinheiro, S. Salústio, J. Rocha, A. A. Valente, C. M. Silva, “Adsorption heat pumps for heating applications”, Renew. Sustain. Energy Rev. (2020) 109528 in press.

M. M. Antunes,  A. Fernandes, D. Falcão, M. Pillinger, M. F. Ribeiro, A. A. Valente, “Optimized preparation and regeneration of MFI type base catalysts for D-glucose isomerization in water”, Catal. Sci. Technol. 10  (2020) 3232-3246.

K. Skrodczky, M. M. Antunes, X. Han, Sa. Santangelo, G. Scholz, A. A. Valente, N. Pinna, P. A. Russo, “Niobium pentoxide nanomaterials with distorted structures as efficient acid catalysts: structure-acidity-activity relationships”, Commun. Chem. (Nature) 2, 129 (2019) 1-11.

S. M. Bruno, A. A. Valente, M. Pillinger, J. Amelse, C. C. Romão, I. S. Gonçalves, “Efficient Isomerization of α‑Pinene Oxide to Campholenic Aldehyde Promoted by a Mixed-Ring Analogue of Molybdenocene”, ACS Sustainable Chem. Eng. 7 (2019) 13639-13645.

A. F. Silva, A. Fernandes, M. M. Antunes, M. F. Ribeiro, C. M. Silva, A. A. Valente, “Olefin oligomerisation over nanocrystalline MFI-based micro/mesoporous zeotypes synthesised via bottom-up approaches”, Renewable Energy 138 (2019) 820-832.

M. M. Antunes, S. Lima, A. Fernandes, M. F. Ribeiro, D. Chadwick, K. Hellgardt, M. Pillinger, A. A. Valente, “One-pot hydrogen production and cascade reaction of furfural to bioproducts over bimetallic Pd-Ni TUD-1 type mesoporous catalysts”, Appl. Catal. B: Environ. 237 (2018) 521–537.

A. F. Silva, A. Fernandes, M. M. Antunes, P. Neves, S.M. Rocha, M. F. Ribeiro, M. Pillinger, J. Ribeiro, C. M. Silva, A. A. Valente, “TUD-1 type aluminosilicate acid catalysts for 1-butene oligomerisation”, Fuel 209 (2017) 371-382.

M. M. Antunes, S. Lima, P. Neves, A. L. Magalhães, E. Fazio, F. Neri, M. T. Pereira, A. F. Silva, C. M. Silva, S. M. Rocha, M. Pillinger, A. Urakawa, A. A. Valente, “Integrated reduction and acid-catalysed conversion of furfural in alcohol medium using Zr,Al-containing ordered micro/mesoporous silicates”, Appl. Catal. B: Environ. 182 (2016) 485-503.

T. R. Amarante, P. Neves, A. A. Valente, F. A. A. Paz, M. Pillinger, I. S. Gonçalves, “Metal Oxide-Triazole Hybrids as Heterogeneous or Reaction-Induced Self-Separating Catalysts”, J. Catal. 340 (2016) 354-367.

M. M. Antunes, S. Lima, P. Neves, A. L. Magalhães, E. Fazio, A. Fernandes, F. Neri, C. M. Silva, S. M. Rocha, M. F. Ribeiro, M. Pillinger, A. Urakawa, A. A. Valente, “One-pot conversion of furfural to useful bio-products in the presence of a Sn,Al-containing zeolite beta catalyst prepared via post-synthesis routes”, J. Catal. 329 (2015) 522–537.

P. Neves, A. C. Gomes, T. R. Amarante, F. A. A. Paz, M. Pillinger, I. S. Gonçalves, A. A. Valente, “Incorporation of a dioxomolybdenum(VI) complex in a ZrIV-based metal–organic framework and its application in catalytic olefin epoxidation”, Micropor. Mesopor. Mat. 202 (2015) 106–114.

T. R. Amarante, M. M. Antunes, A. A. Valente, F. A. A. Paz, M. Pillinger, I. S. Gonçalves, “Crystal Structure and Catalytic Behavior in Olefin Epoxidation of a One-Dimensional Tungsten Oxide/Bipyridine Hybrid”, Inorg. Chem. 54 (2015) 9690-9703.

Projects

Ansa-bridged Organorhenium(VII) oxides and their application as homogeneous and heterogeneous catalysts (PTDC/QUI/71198/2006)

PartnerFundação para a Ciência e a Tecnologia
catalysis chirality rhenium new materials

Catalytic conversion of carbohydrates into furan derivatives (POCI/QUI/56112/2004)

CoordinatorFundação para a Ciência e a Tecnologia
saccharides furfural heterogeneous catalysis solid acid

Conversao catalitica de olefinas derivadas da biomassa (BiOle_AcidOxCat)

PartnerFundação para a Ciência e a Tecnologia

Immobilized surface rare earth and actinide aryloxides Activation of small molecules (CO2,CH4,C2H6) (POCTI/QUI/42919/2001)

PartnerFundação para a Ciência e a Tecnologia
Organometallic surface chemistry Immobilized catalysts Block f elements aryloxides Activation of CO2, CH4, C2H6

Multifunctional anionic clays (POCI/CTM/58507/2004)

PartnerFundação para a Ciência e a Tecnologia
Layered double hydroxides Intercalation Host-guest systems Heterogeneous catalysis

Nano-sized Functional Metal-Organic Frameworks Based on Lanthanide Polyphosphonates (PTDC/QUI-QUI/098098/2008)

PartnerFundação para a Ciência e a Tecnologia
Metal-Organic Frameworks Crystal Engineering Photoluminescent thin films Heterogeneous Catalysts

New oxometal compounds with tailored catalytic properties (POCI/QUI/56109/2004)

PartnerFundação para a Ciência e a Tecnologia
Oxometal complexes Organic-inorganic hybrids Reaction mechanisms Oxidation catalysis

Novel Ceramic Membranes for Synthesis Gas Production (POCI/CTM/58570/2004)

PartnerFundação para a Ciência e a Tecnologia
mixed conductor ceramic membrane synthesis gas ionic transport

Robust Nanometric Coordination Polymers for Gas Separation and Light Emission (EXPL/CTM-NAN/0013/2013)

PartnerFundação para a Ciência e a Tecnologia
Photoluminescent Metal-Organic Frameworks Organic Ligand Design Heterogeneous Catalysts Selective Gas Sorption

Sistemas ativados por estímulos para a terapia com monóxido de carbono (SASCOT)

PartnerFundação para a Ciência e a Tecnologia

Use of molecular containers to modify metallocene-based catalysts (PTDC/QEQ-SUP/1906/2012)

PartnerFundação para a Ciência e a Tecnologia
Metallocenes Host-guest chemistry Molecular containers Organic transformations

Publications

Mild Liquid Phase Oxidation of Benzyl Alcohol in the Presence of Microporous Framework Copper Silicates

Neves, P; Valente, AA; Lin, Z
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 13, 1172-1176.
ISBN: 1099-0682

Optimization of continuous-flow heterogeneous catalytic oligomerization of 1-butene by design of experiments and response surface methodology

Silva, AF; Neves, P; Rocha, SM; Silva, CM; Valente, AA
2020, FUEL, 259.
ISBN: 1873-7153

Simple Hybrids Based on Mo or W Oxides and Diamines: Structure Determination and Catalytic Properties

Bozek, B; Neves, P; Oszajca, M; Valente, AA; Poltowicz, J; Pamin, K; Lasocha, W
2020, CATALYSIS LETTERS, 150, 3, 713-727.
ISBN: 1572-879X

Intercalation of (eta(5)-Pentamethylcyclopentadienyl)trioxomolybdenum(VI) in a Layered Double Hydroxide

Gomes, AC; Neves, P; Gago, S; Valente, AA; Goncalves, IS; Pillinger, M
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 25, 2408-2416.
ISBN: 1099-0682

Adsorption heat pumps for heating applications

Pinheiro, JM; Salustio, S; Rocha, J; Valente, AA; Silva, CM
2020, RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 119.

Ionic ammonium and anilinium based polymolybdate hybrid catalysts for olefin epoxidation (vol 564, pg 13, 2018)

Bozek, B; Neves, P; Lasocha, W; Valente, AA
2020, APPLIED CATALYSIS A-GENERAL, 602.
ISBN: 1873-3875

Modified Versions of AM-4 for the Aqueous Phase Isomerization of Aldo-Saccharides

Antunes, MM; Fernandes, A; Ribeiro, MF; Lin, Z; Valente, AA
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 17, 1579-1588.
ISBN: 1099-0682

Multifunctionality and cytotoxicity of a layered coordination polymer

Silva, P; Mendes, RF; Fernandes, C; Gomes, AC; Ananias, D; Remiao, F; Borges, F; Valente, AA; Paz, FAA
2020, DALTON TRANSACTIONS, 49, 13, 3989-3998.
ISBN: 1477-9234

One-Pot Intercalation Strategy for the Encapsulation of a CO-Releasing Organometallic Molecule in a Layered Double Hydroxide

Calhau, IB; Gomes, AC; Bruno, SM; Coelho, AC; Magalhaes, CIR; Romao, CC; Valente, AA; Goncalves, IS; Pillinger, M
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 28, 2726-2736.
ISBN: 1099-0682

Optimized preparation and regeneration of MFI type base catalysts for d-glucose isomerization in water

Antunes, MM; Fernandes, A; Falcao, D; Pillinger, M; Ribeiro, F; Valente, AA
2020, CATALYSIS SCIENCE & TECHNOLOGY, 10, 10, 3232-3246.
ISBN: 2044-4761

Oxidation of sulfides in aqueous media catalyzed by pyrazole-oxidoperoxido-molybdenum(VI) complexes

Bruno, SM; Amarante, TR; Paz, FAA; Pillinger, M; Valente, AA; Goncalves, IS
2020, INORGANICA CHIMICA ACTA, 511.
ISBN: 1873-3255

Olefin oligomerisation over nanocrystalline MFI-based micro/mesoporous zeotypes synthesised via bottom-up approaches

Silva, AF; Fernandes, A; Antunes, MM; Ribeiro, MF; Silva, CM; Valente, AA
2019, RENEWABLE ENERGY, 138, 820-832.

One-pot hydrogen production and cascade reaction of furfural to bioproducts over bimetallic Pd-Ni TUD-1 type mesoporous catalysts (vol 237, pg 521, 2018)

Antunes, MM; Lima, S; Fernandes, A; Ribeiro, MF; Chadwick, D; Hellgardt, K; Pillinger, M; Valente, AA
2019, APPLIED CATALYSIS B-ENVIRONMENTAL, 243, 801-801.
ISBN: 1873-3883

A Comparative Study of Molybdenum Carbonyl and Oxomolybdenum Derivatives Bearing 1,2,3-Triazole or 1,2,4-Triazole in Catalytic Olefin Epoxidation

Nogueira, LS; Neves, P; Gomes, AC; Amarante, TA; Paz, FAA; Valente, AA; Goncalves, IS; Pillinger, M
2019, MOLECULES, 24, 1.

Niobium pentoxide nanomaterials with distorted structures as efficient acid catalysts

Skrodczky, K; Antunes, MM; Han, XY; Santangelo, S; Scholz, G; Valente, AA; Pinna, N; Russo, PA
2019, COMMUNICATIONS CHEMISTRY, 2.

Catalytic Conversion of 1-butene over Modified Versions of Commercial ZSM-5 to Produce Clean Fuels and Chemicals

Silva, AF; Fernandes, A; Antunes, MM; Ribeiro, MF; Silva, CM; Valente, AA
2019, CHEMCATCHEM, 11, 16, 4196-4209.
ISBN: 1867-3899

Efficient Isomerization of alpha-Pinene Oxide to Campholenic Aldehyde Promoted by a Mixed-Ring Analogue of Molybdenocene

Bruno, SM; Valente, AA; Pillinger, M; Arnelse, J; Romao, CC; Goncalves, IS
2019, ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 7, 16, 13639-13645.

A hydrogen-bonded assembly of cucurbit[6]uril and [MoO2Cl2(H2O)(2)] with catalytic efficacy for the one-pot conversion of olefins to alkoxy products

Nogueira, LS; Antunes, MM; Gomes, AC; Cunha-Silva, L; Pillinger, M; Lopes, AD; Valente, AA; Goncalves, IS
2019, DALTON TRANSACTIONS, 48, 30, 11508-11519.
ISBN: 1477-9234

A Molybdenum Trioxide Hybrid Decorated by 3-(1,2,4-Triazol-4-yl)adamantane-1-carboxylic Acid: A Promising Reaction-Induced Self-Separating (RISS) Catalyst

Lysenko, AB; Senchyk, GA; Domasevitch, KV; Henfling, S; Erhart, O; Krautscheid, H; Neves, P; Valente, AA; Pillinger, M; Goncalves, IS
2019, INORGANIC CHEMISTRY, 58, 24, 16424-16433.
ISBN: 1520-510X

Performance of chiral tetracarbonylmolybdenum pyrindanyl amine complexes in catalytic olefin epoxidation

Neves, P; Nogueira, LS; Valente, AA; Pillinger, M; Goncalves, IS; Sampaio-Dias, IE; Sousa, CAD; Rizzo-Aguiar, F; Rodriguez-Borges, JE
2018, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 858, 29-36.

Acid-catalyzed epoxide alcoholysis in the presence of indenyl molybdenum carbonyl complexes

Bruno, SM; Goncalves, IS; Pillinger, M; Romao, CC; Valente, AA
2018, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 855, 12-17.

Measurement and modelling of tracer diffusivities of gallic acid in liquid ethanol and in supercritical CO2 modified with ethanol

Leite, J; Magalhaes, AL; Valente, AA; Silva, CM
2018, JOURNAL OF SUPERCRITICAL FLUIDS, 131, 130-139.

Molybdenum(0) tricarbonyl and tetracarbonyl complexes with a cationic pyrazolylpyridine ligand: synthesis, crystal structures and catalytic performance in olefin epoxidation

Nogueira, LS; Neves, P; Gomes, AC; Lavrador, P; Cunha-Silva, L; Valente, AA; Goncalves, IS; Pillinger, M
2018, RSC ADVANCES, 8, 29, 16294-16302.

An Organotin Vanadate with Sodalite Topology and Catalytic Versatility in Oxidative Transformations

Gomes, AC; Antunes, MM; Abrantes, M; Valente, AA; Paz, FAA; Goncalves, IS; Pillinger, M
2018, CHEMCATCHEM, 10, 16, 3481-3489.

High-yield synthesis and catalytic response of chainlike hybrid materials of the [(MoO3)(m)(2,2 '-bipyridine)(n)] family

Bruno, SM; Nogueira, LS; Gomes, AC; Valente, AA; Goncalves, IS; Pillinger, M
2018, NEW JOURNAL OF CHEMISTRY, 42, 20, 16483-16492.

One-pot hydrogen production and cascade reaction of furfural to bioproducts over bimetallic Pd-Ni TUD-1 type mesoporous catalysts

Antunes, MM; Lima, S; Fernandes, A; Ribeiro, MF; Chadwick, D; Hellgardt, K; Pillinger, M; Valente, AA
2018, APPLIED CATALYSIS B-ENVIRONMENTAL, 237, 521-537.

Ionic ammonium and anilinium based polymolybdate hybrid catalysts for olefin epoxidation

Bozek, B; Neves, P; Lasocha, W; Valente, AA
2018, APPLIED CATALYSIS A-GENERAL, 564, 13-25.

Detecting Proton Transfer in CO2 Species Chemisorbed on Amine-Modified Mesoporous Silicas by Using (CNMR)-C-13 Chemical Shift Anisotropy and Smart Control of Amine Surface Density

Cendak, T; Sequeira, L; Sardo, M; Valente, A; Pinto, ML; Mafra, L
2018, CHEMISTRY-A EUROPEAN JOURNAL, 24, 40, 10136-10145.

Mesostructured Catalysts Based on the BEA Topology for Olefin Oligomerisation

Silva, AF; Fernandes, A; Neves, P; Antunes, MM; Rocha, SM; Ribeiro, MF; Silva, CM; Valente, AA
2018, CHEMCATCHEM, 10, 13, 2741-2754.

A Linear Trinuclear Oxidodiperoxido-molybdenum(VI) Complex with Single Triazole Bridges: Catalytic Activity in Epoxidation, Alcoholysis, and Acetalization Reactions

Antunes, MM; Amarante, TR; Valente, AA; Paz, FAA; Goncalves, IS; Pillinger, M
2018, CHEMCATCHEM, 10, 13, 2782-2791.

Adsorption heat pump optimization by experimental design and response surface methodology

Pinheiro, JM; Salustio, S; Valente, AA; Silva, CM
2018, APPLIED THERMAL ENGINEERING, 138, 849-860.

TUD-1 type aluminosilicate acid catalysts for 1-butene oligomerisation

Silva, AF; Fernandes, A; Antunes, MM; Neves, P; Rocha, SM; Ribeiro, MF; Pillinger, M; Ribeiro, J; Silva, CM; Valente, AA
2017, FUEL, 209, 371-382.

Robust Multifunctional Yttrium-Based Metal Organic Frameworks with Breathing Effect

Firmino, ADG; Mendes, RF; Antunes, MM; Barbosa, PC; Vilela, SMF; Valente, AA; Figueiredo, FML; Tome, JPC; Paz, FAA
2017, INORGANIC CHEMISTRY, 56, 3, 1193-1208.
ISBN: 1520-510X

Performance of a tetracarbonylmolybdenum(0) pyrazolylpyridine (pre) catalyst in olefin epoxidation and epoxide alcoholysis

Nogueira, LS; Neves, P; Gomes, AC; Valente, AA; Pillinger, M; Goncalves, IS
2017, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 846, 185-192.
ISBN: 1872-8561

MFI Acid Catalysts with Different Crystal Sizes and Porosity for the Conversion of Furanic Compounds in Alcohol Media

Antunes, MM; Lima, S; Fernandes, A; Magalhaes, AL; Neves, P; Silva, CM; Ribeiro, MF; Chadwick, D; Hellgardt, K; Pillinger, M; Valente, AA
2017, CHEMCATCHEM, 9, 14, 2747-2759.
ISBN: 1867-3899

Synthesis, structure and catalytic olefin epoxidation activity of a dinuclear oxo-bridged oxodiperoxomolybdenum(VI) complex containing coordinated 4,4 '-bipyridinium

Neves, P; Gomes, AC; Paz, FAA; Valente, AA; Goncalves, IS; Pillinger, M
2017, MOLECULAR CATALYSIS, 432, 104-114.

Behavior of Triazolylmolybdenum(VI) Oxide Hybrids as Oxidation Catalysts with Hydrogen Peroxide

Neves, P; Lysenko, AB; Gomes, AC; Pillinger, M; Goncalves, IS; Valente, AA
2017, CATALYSIS LETTERS, 147, 5, 1133-1143.
ISBN: 1572-879X

Triazolyl, Imidazolyl, and Carboxylic Acid Moieties in the Design of Molybdenum Trioxide Hybrids: Photophysical and Catalytic Behavior

Lysenko, AB; Senchyk, GA; Domasevitch, KV; Kobalz, M; Krautscheid, H; Cichos, J; Karbowiak, M; Neves, P; Valente, AA; Goncalves, IS
2017, INORGANIC CHEMISTRY, 56, 8, 4380-4394.
ISBN: 1520-510X

Chemistry and Catalytic Performance of Pyridyl-Benzimidazole Oxidomolybdenum(VI) Compounds in (Bio)Olefin Epoxidation

Neves, P; Nogueira, LS; Gomes, AC; Oliveira, TSM; Lopes, AD; Valente, AA; Goncalves, IS; Pillinger, M
2017, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 19, 2617-2627.
ISBN: 1099-0682

Integrated reduction and acid-catalysed conversion of furfural in alcohol medium using Zr,Al-containing ordered micro/mesoporous silicates

Antunes, MM; Lima, S; Neves, P; Magalhaes, AL; Fazio, E; Neri, F; Pereira, MT; Silva, AF; Silva, CM; Rocha, SM; Pillinger, M; Urakawa, A; Valente, AA
2016, APPLIED CATALYSIS B-ENVIRONMENTAL, 182, 485-503.

A Lamellar Coordination Polymer with Remarkable Catalytic Activity

Mendes, RF; Antunes, MM; Silva, P; Barbosa, P; Figueiredo, F; Linden, A; Rocha, J; Valente, AA; Paz, FAA
2016, CHEMISTRY-A EUROPEAN JOURNAL, 22, 37, 13136-13146.

Analysis of equilibrium and kinetic parameters of water adsorption heating systems for different porous metal/metalloid oxide adsorbents

Pinheiro, JM; Salustio, S; Rocha, J; Valente, AA; Silva, CM
2016, APPLIED THERMAL ENGINEERING, 100, 215-226.

Bulk and composite catalysts combining BEA topology and mesoporosity for the valorisation of furfural

Antunes, MM; Neves, P; Fernandes, A; Lima, S; Silva, AF; Ribeiro, MF; Silva, CM; Pillinger, M; Valente, AA
2016, CATALYSIS SCIENCE & TECHNOLOGY, 6, 21, 7812-7829.

Catalytic alcoholysis of epoxides using metal-free cucurbituril-based solids

Bruno, SM; Gomes, AC; Oliveira, TSM; Antunes, MM; Lopes, AD; Valente, AA; Goncalves, IS; Pillinger, M
2016, ORGANIC & BIOMOLECULAR CHEMISTRY, 14, 16, 3873-3877.

Catalytic Application of an Octamolybdate Salt (H(3)biim)(4)[beta-Mo8O26] in Olefin Epoxidation (H(2)biim=2,2'-biimidazole)

Neves, P; Amarante, TR; Valente, AA; Pillinger, M; Goncalves, IS
2016, CATALYSIS LETTERS, 146, 4, 841-850.

Experimental and theoretical analysis of the diffusion behavior of chromium(III) acetylacetonate in supercritical CO2

Cordeiro, J; Magalhaes, AL; Valente, AA; Silva, CM
2016, JOURNAL OF SUPERCRITICAL FLUIDS, 118, 153-162.

Measurement and modeling of tracer diffusivities of alpha-pinene in supercritical CO2, and analysis of their hydrodynamic and free-volume behaviors

Vaz, RV; Magalhaes, AL; Valente, AA; Silva, CM
2016, JOURNAL OF SUPERCRITICAL FLUIDS, 107, 690-698.

Metal oxide-triazole hybrids as heterogeneous or reaction-induced self-separating catalysts

Amarante, TR; Neves, P; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2016, JOURNAL OF CATALYSIS, 340, 354-367.

Oxidomolybdenum complexes for acid catalysis using alcohols as solvents and reactants

Gomes, AC; Neves, P; Cunha-Silva, L; Valente, AA; Goncalves, IS; Pillinger, M
2016, CATALYSIS SCIENCE & TECHNOLOGY, 6, 13, 5207-5218.

Photoluminescent porous and layered lanthanide silicates: A review

Figueiredo, BR; Valente, AA; Lin, Z; Silva, CM
2016, MICROPOROUS AND MESOPOROUS MATERIALS, 234, 73-97.

Crystal structure and temperature-dependent luminescence of a heterotetranuclear sodium-europium(III) beta-diketonate complex

Bruno, SM; Ananias, D; Paz, FAA; Pillinger, M; Valente, AA; Carlos, LD; Goncalves, IS
2015, DALTON TRANSACTIONS, 44, 2, 488-492.

Ring-opening of epoxides promoted by organomolybdenum complexes of the type [eta(5)-C5H4R)mo(CO)(2)(773-C3H5)] and [(eta(5)-C5H5) Mo(CO)(3)(CH2R)]

Bruno, SM; Gomes, AC; Abrantes, M; Valente, AA; Pillinger, M; Goncalves, IS
2015, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 799-800, 179-183.

One-pot conversion of furfural to useful bio-products in the presence of a Sn,Al-containing zeolite beta catalyst prepared via post-synthesis routes

Antunes, MM; Lima, S; Neves, P; Magalhaes, AL; Fazio, E; Fernandes, A; Neri, F; Silva, CM; Rocha, SM; Eiro, MFR; Pillinger, M; Urakawa, A; Valente, AA
2015, JOURNAL OF CATALYSIS, 329, 522-537.

Application of the novel ETS-10/water pair in cyclic adsorption heating processes: Measurement of equilibrium and kinetics properties and simulation studies

Pinheiro, JM; Valente, AA; Salustio, S; Ferreira, N; Rocha, J; Silva, CM
2015, APPLIED THERMAL ENGINEERING, 87, 412-423.

Crystal Structure and Catalytic Behavior in Olefin Epoxidation of a One-Dimensional Tungsten Oxide/Bipyridine Hybrid

Amarante, TR; Antunes, MM; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2015, INORGANIC CHEMISTRY, 54, 20, 9690-9703.

Synthesis and Structural Elucidation of Triazolylmolybdenum(VI) Oxide Hybrids and Their Behavior as Oxidation Catalysts

Lysenko, AB; Senchyk, GA; Domasevitch, KV; Hauser, J; Fuhrmann, D; Kobalz, M; Krautscheid, H; Neves, P; Valente, AA; Goncalves, IS
2015, INORGANIC CHEMISTRY, 54, 17, 8327-8338.

Sustainable synthesis of a catalytic active one-dimensional lanthanide-organic coordination polymer

Mendes, RF; Silva, P; Antunes, MM; Valente, AA; Paz, FAA
2015, CHEMICAL COMMUNICATIONS, 51, 54, 10807-10810.

Incorporation of a dioxomolybdenum(VI) complex in a Zr-IV-based Metal-Organic Framework and its application in catalytic olefin epoxidation

Neves, P; Gomes, AC; Amarante, TR; Paz, FAA; Pillinger, M; Goncalves, IS; Valente, AA
2015, MICROPOROUS AND MESOPOROUS MATERIALS, 202, 106-114.

Catalytic isomerisation of alpha-pinene oxide in the presence of ETS-10 supported ferrocenium ions

Bruno, SM; Gomes, AC; Coelho, AC; Brandao, P; Valente, AA; Pillinger, M; Goncalves, IS
2015, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 791, 66-71.

Multifunctional micro-and nanosized metalorganic frameworks assembled from bisphosphonates and lanthanides

Vilela, SMF; Ananias, D; Fernandes, JA; Silva, P; Gomes, AC; Silva, NJO; Rodrigues, MO; Tome, JPC; Valente, AA; Ribeiro-Claro, P; Carlos, LD; Rocha, J; Paz, FAA
2014, JOURNAL OF MATERIALS CHEMISTRY C, 2, 17, 3311-3327.

Catalytic olefin epoxidation with a carboxylic acid-functionalized cyclopentadienyl molybdenum tricarbonyl complex

Gomes, AC; Bruno, SM; Abrantes, M; Magalhaes, CIR; Goncalves, IS; Valente, AA; Pillinger, M
2014, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 760, 205-211.

Post-synthetic modification of crystal-like periodic mesoporous phenylene-silica with ferrocenyl groups

Gomes, AC; Lourenco, MAO; Bruno, SM; Ferreira, P; Valente, AA; Pillinger, M; Goncalves, IS
2014, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 751, 501-507.

Solid acids with SO3H groups and tunable surface properties: versatile catalysts for biomass conversion

Russo, PA; Antunes, MM; Neves, P; Wiper, PV; Fazio, E; Neri, F; Barreca, F; Mafra, L; Pillinger, M; Pinna, N; Valente, AA
2014, JOURNAL OF MATERIALS CHEMISTRY A, 2, 30, 11813-11824.

Sulfonated Graphene Oxide as Effective Catalyst for Conversion of 5-( Hydroxymethyl)-2-furfural into Biofuels

Antunes, MM; Russo, PA; Wiper, PV; Veiga, JM; Pillinger, M; Mafra, L; Evtuguin, DV; Pinna, N; Valente, AA
2014, CHEMSUSCHEM, 7, 3, 804-812.

Mesoporous carbon-silica solid acid catalysts for producing useful bio-products within the sugar-platform of biorefineries

Russo, PA; Antunes, MM; Neves, P; Wiper, PV; Fazio, E; Neri, F; Barreca, F; Mafra, L; Pillinger, M; Pinna, N; Valente, AA
2014, GREEN CHEMISTRY, 16, 9, 4292-4305.

Mesoporous zirconia-based mixed oxides as versatile acid catalysts for producing bio-additives from furfuryl alcohol and glycerol

Neves, P; Russo, PA; Fernandes, A; Antunes, MM; Farinha, J; Pillinger, M; Ribeiro, MF; Castanheiro, JE; Valente, AA
2014, APPLIED CATALYSIS A-GENERAL, 487, 148-157.

Application of an indenyl molybdenum dicarbonyl complex in the isomerisation of alpha-pinene oxide to campholenic aldehyde

Bruno, SM; Gomes, AC; Gamelas, CA; Abrantes, M; Oliveira, MC; Valente, AA; Paz, FAA; Pillinger, M; Romao, CC; Goncalves, IS
2014, NEW JOURNAL OF CHEMISTRY, 38, 7, 3172-3180.

Synthesis, Structural Elucidation, and Catalytic Properties in Olefin Epoxidation of the Polymeric Hybrid Material [Mo3O9(2-[3(5)-Pyrazolyl]pyridine)](n)

Amarante, TR; Neves, P; Gomes, AC; Nolasco, MM; Ribeiro-Claro, P; Coelho, AC; Valente, AA; Paz, FAA; Smeets, S; McCusker, LB; Pillinger, M; Goncalves, IS
2014, INORGANIC CHEMISTRY, 53, 5, 2652-2665.

Investigation of a dichlorodioxomolybdenum(VI)-pyrazolylpyridine complex and a hybrid derivative as catalysts in olefin epoxidation

Amarante, TR; Neves, P; Paz, FAA; Valente, AA; Pillinger, M; Goncalves, IS
2014, DALTON TRANSACTIONS, 43, 16, 6059-6069.

Triazolyl-Based Copper-Molybdate Hybrids: From Composition Space Diagram to Magnetism and Catalytic Performance

Senchyk, GA; Lysenko, AB; Babaryk, AA; Rusanov, EB; Krautscheid, H; Neves, P; Valente, AA; Goncalves, IS; Kramer, KW; Liu, SX; Decurtins, S; Domasevitch, KV
2014, INORGANIC CHEMISTRY, 53, 19, 10112-10121.

Isomerization of alpha-pinene oxide in the presence of methyltrioxorhenium(VII)

Bruno, SM; Pillinger, M; Kuhn, FE; Goncalves, IS; Valente, AA
2013, CATALYSIS COMMUNICATIONS, 35, 40-44.

A dinuclear oxo-bridged molybdenum(VI) complex containing a bidentate pyrazolylpyridine ligand: Structure, characterization and catalytic performance for olefin epoxidation

Amarante, TR; Gomes, AC; Neves, P; Paz, FAA; Valente, AA; Pillinger, M; Goncalves, IS
2013, INORGANIC CHEMISTRY COMMUNICATIONS, 32, 59-63.

Synthesis and characterization of CpMo(CO)(3)(CH2-pC(6)H(4)-CO2CH3) and its inclusion compounds with methylated cyclodextrins. Applications in olefin epoxidation catalysis

Gomes, AC; Bruno, SM; Tome, C; Valente, AA; Pillinger, M; Abrantes, M; Goncalves, IS
2013, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 730, 116-122.

Hydrothermal Synthesis, Crystal Structure, and Catalytic Potential of a One-Dimensional Molybdenum Oxide/Bipyridinedicarboxylate Hybrid

Amarante, TR; Neves, P; Valente, AA; Paz, FAA; Fitch, AN; Pillinger, M; Goncalves, IS
2013, INORGANIC CHEMISTRY, 52, 8, 4618-4628.

Tris(pyrazolyl)methane molybdenum tricarbonyl complexes as catalyst precursors for olefin epoxidation

Gomes, AC; Neves, P; Figueiredo, S; Fernandes, JA; Valente, AA; Paz, FAA; Pillinger, M; Lopes, AD; Goncalves, IS
2013, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 370, 64-74.

Alkoxylation of camphene over silica-occluded tungstophosphoric acid

Caiado, M; Machado, A; Santos, RN; Matos, I; Fonseca, IM; Ramos, AM; Vital, J; Valente, AA; Castanheiro, JE
2013, APPLIED CATALYSIS A-GENERAL, 451, 36-42.

Aqueous phase reactions of pentoses in the presence of nanocrystalline zeolite beta: Identification of by-products and kinetic modelling

Ferreira, LR; Lima, S; Neves, P; Antunes, MM; Rocha, SM; Pillinger, M; Portugal, I; Valente, AA
2013, CHEMICAL ENGINEERING JOURNAL, 215, 772-783.

Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties

Vilela, SMF; Firmino, ADG; Mendes, RF; Fernandes, JA; Ananias, D; Valente, AA; Ott, H; Carlos, LD; Rocha, J; Tome, JPC; Paz, FAA
2013, CHEMICAL COMMUNICATIONS, 49, 57, 6400-6402.

Intercalation of a molybdenum eta(3)-allyl dicarbonyl complex in a layered double hydroxide and catalytic performance in olefin epoxidation

Gomes, AC; Bruno, SM; Gamelas, CA; Valente, AA; Abrantes, M; Goncalves, IS; Romao, CC; Pillinger, M
2013, DALTON TRANSACTIONS, 42, 23, 8231-8240.

Microwave-assisted coating of carbon nanostructures with titanium dioxide for the catalytic dehydration of D-xylose into furfural

Russo, PA; Lima, S; Rebuttini, V; Pillinger, M; Willinger, MG; Pinna, N; Valente, AA
2013, RSC ADVANCES, 3, 8, 2595-2603.

Conversion of furfuryl alcohol to ethyl levulinate using porous aluminosilicate acid catalysts

Neves, P; Lima, S; Pillinger, M; Rocha, SM; Rocha, J; Valente, AA
2013, CATALYSIS TODAY, 218, 76-84.

Production of biomass-derived furanic ethers and levulinate esters using heterogeneous acid catalysts

Neves, P; Antunes, MM; Russo, PA; Abrantes, JP; Lima, S; Fernandes, A; Pillinger, M; Rocha, SM; Ribeiro, MF; Valente, AA
2013, GREEN CHEMISTRY, 15, 12, 3367-3376.

Preparation of crystal-like periodic mesoporous phenylene-silica derivatized with ferrocene and its use as a catalyst for the oxidation of styrene

Gomes, AC; Ferreira, MJ; Bruno, SM; Bion, N; Ferreira, P; Valente, AA; Pillinger, M; Rocha, J; Goncalves, IS
2013, DALTON TRANSACTIONS, 42, 40, 14612-14620.

Photoluminescent Metal-Organic Frameworks - Rapid Preparation, Catalytic Activity, and Framework Relationships

Silva, P; Ananias, D; Bruno, SM; Valente, AA; Carlos, LD; Rocha, J; Paz, FAA
2013, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 32, 5576-5591.

Intercalation of a molybdenum(0)-tetracarbonyl-bipyridine complex in a layered double hydroxide

Gomes, AC; Bruno, SM; Valente, AA; Goncalves, IS; Pillinger, M
2013, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 744, 53-59.

Molybdenum(II) Diiodo-Tricarbonyl Complexes Containing Nitrogen Donor Ligands as Catalyst Precursors for the Epoxidation of Methyl Oleate

Gamelas, CA; Neves, P; Gomes, AC; Valente, AA; Romao, CC; Goncalves, IS; Pillinger, M
2012, CATALYSIS LETTERS, 142, 10, 1218-1224.

Aqueous-phase dehydration of xylose to furfural in the presence of MCM-22 and ITQ-2 solid acid catalysts

Antunes, MM; Lima, S; Fernandes, A; Pillinger, M; Ribeiro, MF; Valente, AA
2012, APPLIED CATALYSIS A-GENERAL, 417, 243-252.

Isomerisation of alpha-pinene oxide in the presence of indenyl allyl dicarbonyl molybdenum(II) and tungsten(II) complexes

Bruno, SM; Gamelas, CA; Gomes, AC; Valente, AA; Pillinger, M; Romao, CC; Goncalves, IS
2012, CATALYSIS COMMUNICATIONS, 23, 58-61.

Catalytic dehydration of D-xylose to 2-furfuraldehyde in the presence of Zr-(W,Al) mixed oxides. Tracing by-products using two-dimensional gas chromatography-time-of-flight mass spectrometry

Antunes, MM; Lima, S; Fernandes, A; Candeias, J; Pillinger, M; Rocha, SM; Ribeiro, MF; Valente, AA
2012, CATALYSIS TODAY, 195, 1, 127-135.

Epoxidation of olefins using a dichlorodioxomolybdenum(VI)-pyridylimine complex as catalyst

Balula, SS; Bruno, SM; Gomes, AC; Valente, AA; Pillinger, M; Goncalves, IS; Macquarrie, DJ; Clark, JH
2012, INORGANICA CHIMICA ACTA, 387, 234-239.

A dinuclear oxomolybdenum(VI) complex, [Mo2O6(4,4 '-di-tert-butyl-2,2 '-bipyridine)(2)], displaying the {MoO2(mu-O)(2)MoO2}(0) core, and its use as a catalyst in olefin epoxidation

Amarante, TR; Neves, P; Paz, FAA; Pillinger, M; Valente, AA; Goncalves, IS
2012, INORGANIC CHEMISTRY COMMUNICATIONS, 20, 147-152.

An Octanuclear Molybdenum(VI) Complex Containing Coordinative ly Bound 4,4 '-di-tert-Butyl-2,2 '-Bipyridine, [Mo8O22(OH)(4)(di-tBu-bipy)(4)]: Synthesis, Structure, and Catalytic Epoxidation of Bio-Derived Olefins

Amarante, TR; Neves, P; Tome, C; Abrantes, M; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2012, INORGANIC CHEMISTRY, 51, 6, 3666-3676.

Synthesis, Structural Elucidation, and Application of a Pyrazolylpyridine-Molybdenum Oxide Composite as a Heterogeneous Catalyst for Olefin Epoxidation

Figueiredo, S; Gomes, AC; Neves, P; Amarante, TR; Paz, FAA; Soares, R; Lopes, AD; Valente, AA; Pillinger, M; Goncalves, IS
2012, INORGANIC CHEMISTRY, 51, 15, 8629-8635.

Molybdenum(VI) catalysts obtained from eta(3)-allyl dicarbonyl precursors: Synthesis, characterization and catalytic performance in cyclooctene epoxidation

Gamelas, CA; Gomes, AC; Bruno, SM; Paz, FAA; Valente, AA; Pillinger, M; Romao, CC; Goncalves, IS
2012, DALTON TRANSACTIONS, 41, 12, 3474-3484.

Multi-functional metal-organic frameworks assembled from a tripodal organic linker

Vilela, SMF; Ananias, D; Gomes, AC; Valente, AA; Carlos, LD; Cavaleiro, JAS; Rocha, J; Tome, JPC; Paz, FAA
2012, JOURNAL OF MATERIALS CHEMISTRY, 22, 35, 18354-18371.

Coupling of Nanoporous Chromium, Aluminium-Containing Silicates with an Ionic Liquid for the Transformation of Glucose into 5-(Hydroxymethyl)-2-furaldehyde

Antunes, MM; Lima, S; Pillinger, M; Valente, AA
2012, MOLECULES, 17, 4, 3690-3707.

Ionic Liquids as Tools for the Acid-Catalyzed Hydrolysis/Dehydration of Saccharides to Furanic Aldehydes

Lima, S; Antunes, MM; Pillinger, M; Valente, AA
2011, CHEMCATCHEM, 3, 11, 1686-1706.

Oxidation of Ethylbenzene in the Presence of an MCM-41-Supported or Ionic Liquid-Standing Bischlorocopper(II) Complex

Gago, S; Bruno, SM; Queiros, DC; Valente, AA; Goncalves, IS; Pillinger, M
2011, CATALYSIS LETTERS, 141, 7, 1009-1017.

Heterogeneous oxidation catalysts formed in situ from molybdenum tetracarbonyl complexes and tert-butyl hydroperoxide

Neves, P; Amarante, TR; Gomes, AC; Coelho, AC; Gago, S; Pillinger, M; Goncalves, IS; Silva, CM; Valente, AA
2011, APPLIED CATALYSIS A-GENERAL, 395, 1-2, 71-77.

Catalytic dehydration of xylose to furfural: vanadyl pyrophosphate as source of active soluble species

Sadaba, I; Lima, S; Valente, AA; Granados, ML
2011, CARBOHYDRATE RESEARCH, 346, 17, 2785-2791.

Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor

Abrantes, M; Bruno, SM; Tome, C; Pillinger, M; Goncalves, IS; Valente, AA
2011, CATALYSIS COMMUNICATIONS, 15, 1, 64-67.

Epoxidation of cyclooctene using soluble or MCM-41-supported molybdenum tetracarbonyl-pyridylimine complexes as catalyst precursors

Gomes, AC; Bruno, SM; Gago, S; Lopes, RP; Machado, DA; Carminatti, AP; Valente, AA; Pillinger, M; Goncalves, IS
2011, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 696, 22, 3543-3550.

Chemistry and Catalytic Activity of Molybdenum(VI)-Pyrazolylpyridine Complexes in Olefin Epoxidation. Crystal Structures of Monomeric Dioxo, Dioxo-mu-oxo, and Oxodiperoxo Derivatives

Coelho, AC; Nolasco, M; Balula, SS; Antunes, MM; Pereira, CCL; Paz, FAA; Valente, AA; Pillinger, M; Ribeiro-Claro, P; Klinowski, J; Goncalves, IS
2011, INORGANIC CHEMISTRY, 50, 2, 525-538.

Synthesis and Catalytic Properties of Molybdenum(VI) Complexes with Tris(3,5-dimethyl-1-pyrazolyl)methane

Neves, P; Gago, S; Balula, SS; Lopes, AD; Valente, AA; Cunha-Silva, L; Paz, FAA; Pillinger, M; Rocha, J; Silva, CM; Goncalves, IS
2011, INORGANIC CHEMISTRY, 50, 8, 3490-3500.

Thermal Transformation of a Layered Multifunctional Network into a Metal-Organic Framework Based on a Polymeric Organic Linker

Silva, P; Vieira, F; Gomes, AC; Ananias, D; Fernandes, JA; Bruno, SM; Soares, R; Valente, AA; Rocha, J; Paz, FAA
2011, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133, 38, 15120-15138.

IONIC LIQUIDS-ADVANCED REACTION MEDIA FOR ORGANIC SYNTHESIS

Ignat'ev, NV; Schulte, M; Koppe, K; Barthen, P; Zlotin, SG; Makhova, NN; Sheremetev, AB; Valente, AA
2011, PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 186, 5, 1205-1216.

Grafting of Molecularly Ordered Mesoporous Phenylene-Silica with Molybdenum Carbonyl Complexes: Efficient Heterogeneous Catalysts for the Epoxidation of Olefins

Coelho, AC; Balula, SS; Bruno, SM; Alonso, JC; Bion, N; Ferreira, P; Pillinger, M; Valente, AA; Rocha, J; Goncalves, IS
2010, ADVANCED SYNTHESIS & CATALYSIS, 352, 10, 1759-1769.

Dioxomolybdenum(VI) Epoxidation Catalyst Supported on Mesoporous Silica Containing Phosphane Oxide Groups

Castro, A; Alonso, JC; Neves, P; Valente, AA; Ferreira, P
2010, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 4, 602-607.

Nanostructured Dioxomolybdenum(VI) Catalyst for the Liquid-Phase Epoxidation of Olefins

Castro, A; Alonso, JC; Valente, AA; Neves, P; Brandao, P; Felix, V; Ferreira, P
2010, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 9, 1405-1412.

Dehydration of Xylose into Furfural in the Presence of Crystalline Microporous Silicoaluminophosphates

Lima, S; Fernandes, A; Antunes, MM; Pillinger, M; Ribeiro, F; Valente, AA
2010, CATALYSIS LETTERS, 135, 1-2, 41-47.

Catalytic olefin epoxidation with cationic molybdenum(VI) cis-dioxo complexes and ionic liquids

Gago, S; Balula, SS; Figueiredo, S; Lopes, AD; Valente, AA; Pillinger, M; Goncalves, IS
2010, APPLIED CATALYSIS A-GENERAL, 372, 1, 67-72.

Catalytic cyclodehydration of xylose to furfural in the presence of zeolite H-Beta and a micro/mesoporous Beta/TUD-1 composite material

Lima, S; Antunes, MM; Fernandes, A; Pillinger, M; Ribeiro, MF; Valente, AA
2010, APPLIED CATALYSIS A-GENERAL, 388, 1-2, 141-148.

Cyclopentadienyl molybdenum dicarbonyl eta(3)-allyl complexes as catalyst precursors for olefin epoxidation. Crystal structures of Cp ' Mo(CO)(2)(eta(3)-C3H5) (Cp ' = eta(5)-C5H4Me, eta(5)-C5Me5)

Neves, P; Pereira, CCL; Paz, FAA; Gago, S; Pillinger, M; Silva, CM; Valente, AA; Romao, CC; Goncalves, IS
2010, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 695, 21, 2311-2319.

Microwave-assisted molybdenum-catalysed epoxidation of olefins

Abrantes, M; Neves, P; Antunes, MM; Gago, S; Paz, FAA; Rodrigues, AE; Pillinger, M; Goncalves, IS; Silva, CM; Valente, AA
2010, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 320, 1-2, 19-26.

Complexation of crystal-like mesoporous phenylene-silica with Cr(CO)(3) and catalytic performance in the oxidation of cyclooctene

Coelho, AC; Balula, SS; Antunes, MM; Gerganova, TI; Bion, N; Ferreira, P; Pillinger, M; Valente, AA; Rocha, J; Goncalves, IS
2010, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 332, 1-2, 13-18.

Fast Microwave Synthesis of a Microporous Lanthanide Organic Framework

Silva, P; Valente, AA; Rocha, J; Paz, FAA
2010, CRYSTAL GROWTH & DESIGN, 10, 5, 2025-2028.

Synthesis, Structure, and Catalytic Performance in Cyclooctene Epoxidation of a Molybdenum Oxide/Bipyridine Hybrid Material: {[MoO3(bipy)][MoO3(H2O)]}n

Abrantes, M; Amarante, TR; Antunes, MM; Gago, S; Paz, FAA; Margiolaki, I; Rodrigues, AE; Pillinger, M; Valente, AA; Goncalves, IS
2010, INORGANIC CHEMISTRY, 49, 15, 6865-6873.

Investigation of Molybdenum Tetracarbonyl Complexes As Precursors to Mo-VI Catalysts for the Epoxidation of Olefins

Amarante, TR; Neves, P; Coelho, AC; Gago, S; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS
2010, ORGANOMETALLICS, 29, 4, 883-892.

Catalytic Performance of Ceria Nanorods in Liquid-Phase Oxidations of Hydrocarbons with tert-Butyl Hydroperoxide

Macedo, AG; Fernandes, SEM; Valente, AA; Ferreira, RAS; Carlos, LD; Rocha, J
2010, MOLECULES, 15, 2, 747-765.

Acid-Catalysed Conversion of Saccharides into Furanic Aldehydes in the Presence of Three-Dimensional Mesoporous Al-TUD-1

Lima, S; Antunes, MM; Fernandes, A; Pillinger, M; Ribeiro, MF; Valente, AA
2010, MOLECULES, 15, 6, 3863-3877.

Synthesis and Catalytic Properties in Olefin Epoxidation of Octahedral Dichloridodioxidomolybdenum(VI) Complexes Bearing N,N-Dialkylamide Ligands: Crystal Structure of [Mo2O4(mu(2)-O)Cl-2(dmf)(4)]

Gago, S; Neves, P; Monteiro, B; Pessego, M; Lopes, AD; Valente, AA; Paz, FAA; Pillinger, M; Moreira, J; Silva, CM; Goncalves, IS
2009, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 29-30, 4528-4537.

Catalytic Epoxidation and Sulfoxidation Activity of a Dioxomolybdenum(VI) Complex Bearing a Chiral Tetradentate Oxazoline Ligand

Neves, P; Gago, S; Pereira, CCL; Figueiredo, S; Lemos, A; Lopes, AD; Goncalves, IS; Pillinger, M; Silva, CM; Valente, AA
2009, CATALYSIS LETTERS, 132, 1-2, 94-103.

Effect of an Ionic Liquid on the Catalytic Performance of Thiocyanatodioxomolybdenum(VI) Complexes for the Oxidation of Cyclooctene and Benzyl Alcohol

Monteiro, B; Gago, S; Neves, P; Valente, AA; Goncalves, IS; Pereira, CCL; Silva, CM; Pillinger, M
2009, CATALYSIS LETTERS, 129, 3-4, 350-357.

Conversion of mono/di/polysaccharides into furan compounds using 1-alkyl-3-methylimidazolium ionic liquids

Lima, S; Neves, P; Antunes, MM; Pillinger, M; Ignatyev, N; Valente, AA
2009, APPLIED CATALYSIS A-GENERAL, 363, 1-2, 93-99.

Amino acid-functionalized cyclopentadienyl molybdenum tricarbonyl complex and its use in catalytic olefin epoxidation

Abrantes, M; Paz, FAA; Valente, AA; Pereira, CCL; Gago, S; Rodrigues, AE; Klinowski, J; Pillinger, M; Goncalves, IS
2009, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 694, 12, 1826-1833.

Comparison of liquid-phase olefin epoxidation catalysed by dichlorobis-(dimethylformamide)dioxomolybdenum(VI) in homogeneous phase and grafted onto MCM-41

Monteiro, B; Balula, SS; Gago, S; Grosso, C; Figueiredo, S; Lopes, AD; Valente, AA; Pillinger, M; Lourenco, JP; Goncalves, IS
2009, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 297, 2, 110-117.

Liquid-phase oxidation catalysed by copper(II) immobilised in a pillared layered double hydroxide

Monteiro, B; Gago, S; Balula, SS; Valente, AA; Goncalves, IS; Pillinger, M
2009, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 312, 1-2, 23-30.

Multi-functional rare-earth hybrid layered networks: photoluminescence and catalysis studies

Cunha-Silva, L; Lima, S; Ananias, D; Silva, P; Mafra, L; Carlos, LD; Pillinger, M; Valente, AA; Paz, FAA; Rocha, J
2009, JOURNAL OF MATERIALS CHEMISTRY, 19, 17, 2618-2632.

Immobilisation of eta(3)-allyidicarbonyl complexes of Mo-II with bidentate nitrogen ligands within aluminium-pillared clays

Alonso, JC; Neves, P; Silva, C; Valente, AA; Brandao, P; Quintal, S; de Brito, MJV; Pinto, P; Felix, V; Drew, MGB; Pires, J; Carvalho, AP; Calhorda, MJ; Ferreira, P
2008, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 7, 1147-1156.

MCM-41 derivatised with pyridyl groups and its use as a support for luminescent europium(III) complexes

Bruno, SM; Coelho, AC; Ferreira, RAS; Carlos, LD; Pillinger, M; Valente, AA; Ribeiro-Claro, P; Goncalves, IS
2008, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 24, 3786-3795.

Isomerization of D-glucose to D-fructose over metallosilicate solid bases

Lima, S; Dias, AS; Lin, Z; Brandao, P; Ferreira, P; Pillinger, M; Rocha, J; Calvino-Casilda, V; Valente, AA
2008, APPLIED CATALYSIS A-GENERAL, 339, 1, 21-27.

Dehydration of D-xylose into furfural catalysed by solid acids derived from the layered zeolite Nu-6(1)

Lima, S; Pillinger, M; Valente, AA
2008, CATALYSIS COMMUNICATIONS, 9, 11-12, 2144-2148.

Performance of tubular SrFe(Al)O(3-delta)-SrAl(2)O(4) composite membranes in CO(2)- and CH(4)-containing atmospheres

Yaremchenko, AA; Kharton, VV; Valente, AA; Snijkers, FMM; Cooymans, JFC; Luyten, JJ; Marques, FMB
2008, JOURNAL OF MEMBRANE SCIENCE, 319, 1-2, 141-148.

Synthesis and catalytic properties of manganese(II) and oxovanadium(IV) complexes anchored to mesoporous MCM-41

Fernandes, TA; Nunes, CD; Vaz, PD; Calhorda, MJ; Brandao, P; Rocha, J; Goncalves, IS; Valente, AA; Ferreira, LP; Godinho, M; Ferreira, P
2008, MICROPOROUS AND MESOPOROUS MATERIALS, 112, 1-3, 14-25.

Characterization of a chiral menthyldimethyltin molybdate and its use as an olefin epoxidation catalyst

Abrantes, M; Valente, AA; Pillinger, M; Romao, CC; Goncalves, IS
2007, CATALYSIS LETTERS, 114, 1-2, 103-109.

Modified versions of sulfated zirconia as catalysts for the conversion of xylose to furfural

Dias, AS; Lima, S; Pillinger, M; Valente, AA
2007, CATALYSIS LETTERS, 114, 3-4, 151-160.

Structural and catalytic studies of a trimethyltin vanadate coordination polymer

Abrantes, M; Balula, MS; Valente, AA; Paz, FAA; Pillinger, M; Romao, CC; Rocha, J; Goncalves, IS
2007, JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 17, 1, 215-222.

Metatungstate and tungstoniobate-containing LDHs: Preparation, characterisation and activity in epoxidation of cyclooctene

Carriazo, D; Lima, S; Martin, C; Pillinger, M; Valente, AA; Rives, V
2007, JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 68, 10, 1872-1880.

New chloro and triphenylsiloxy derivatives of dioxomolybdenum(VI) chelated with pyrazolylpyridine ligands: Catalytic applications in olefin epoxidation

Bruno, SM; Pereira, CCL; Balula, MS; Nolasco, M; Valente, AA; Hazell, A; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2007, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 261, 1, 79-87.

Synthesis and catalytic properties in olefin epoxidation of dioxomolybdenurn(VI) complexes bearing a bidentate or tetradentate salen-type ligand

Bruno, SM; Balula, SS; Valente, AA; Paz, FAA; Pillinger, M; Sousa, C; Klinowski, J; Freire, C; Ribeiro-Claro, P; Goncalves, IS
2007, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 270, 1-2, 185-194.

A highly efficient dioxo(mu-oxo)molybdenum(VI) dimer catalyst for olefin epoxidation

Pereira, CCL; Balula, SS; Paz, FAA; Valente, AA; Pillinger, M; Klinowski, J; Goncalves, IS
2007, INORGANIC CHEMISTRY, 46, 21, 8508-8510.

Selective adsorption of volatile organic compounds in micropore aluminum methylphosphonate-alpha: A combined molecular simulation-experimental approach

Herdes, C; Valente, A; Lin, Z; Rocha, J; Coutinho, JAP; Medina, F; Vega, LF
2007, LANGMUIR, 23, 13, 7299-7305.

Molybdenum eta(3)-allyl dicarbonyl complexes as a new class of precursors for highly reactive epoxidation catalysts with tert-butyl hydroperoxide

Alonso, JC; Neves, P; da Silva, MJ; Quintal, S; Vaz, PD; Silva, C; Valente, AA; Ferreira, P; Calhorda, MJ; Felix, V; Drew, MGB
2007, ORGANOMETALLICS, 26, 23, 5548-5556.

Influence of cyclodextrins on catalytic olefin epoxidation with metal-carbonyl compounds. Crystal structure of the TRIMEB complex with CpFe(CO)(2)Cl

Balula, SS; Coelho, AC; Braga, SS; Hazell, A; Valente, AA; Pillinger, M; Seixas, JD; Romao, CC; Goncalves, IS
2007, ORGANOMETALLICS, 26, 27, 6857-6863.

Methane oxidation over mixed-conducting SrFe(Al)O3-delta-SrAl2O4 composite

Yaremchenko, AA; Kharton, VV; Valente, AA; Veniaminov, SA; Belyaev, VD; Sobyanin, VA; Marques, FMB
2007, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 9, 21, 2744-2752.

Liquid-phase dehydration of D-xylose over microporous and mesoporous niobium silicates

Dias, AS; Lima, S; Brandao, P; Pillinger, M; Rocha, J; Valente, AA
2006, CATALYSIS LETTERS, 108, 3-4, 179-186.

Methane oxidation over nanocrystalline Ce0.45Zr0.45La0.10O2-delta/Pt and Ce0.9Sm0.1O2-delta/Pt anodes

Yaremchenko, AA; Kharton, VV; Valente, AA; Frolova, EV; Ivanovskaya, MI; Kovalevsky, AV; Marques, FMB; Rocha, J
2006, CATALYSIS LETTERS, 112, 1-2, 19-26.

Acidic cesium salts of 12-tungstophosphoric acid as catalysts for the dehydration of xylose into furfural

Dias, AS; Lima, S; Pillinger, M; Valente, AA
2006, CARBOHYDRATE RESEARCH, 341, 18, 2946-2953.

Dioxomolybdenum(VI) modified mesoporous materials for the catalytic epoxidation of olefins

Bruno, SM; Fernandes, JA; Martins, LS; Goncalves, IS; Pillinger, M; Ribeiro-Claro, P; Rocha, J; Valente, AA
2006, CATALYSIS TODAY, 114, 2-3, 263-271.

beta-cyclodextrin and permethylated beta-cyclodextrin inclusion compounds of a cyclopentadienyl molybdenum tricarbonyl complex and their use as cyclooctene epoxidation catalyst precursors

Braga, SS; Gago, S; Seixas, JD; Valente, AA; Pillinger, M; Santos, TM; Goncalves, IS; Romao, CC
2006, INORGANICA CHIMICA ACTA, 359, 15, 4757-4764.

Exfoliated titanate, niobate and titanoniobate nanosheets as solid acid catalysts for the liquid-phase dehydration of D-xylose into furfural

Dias, AS; Lima, S; Carriazo, D; Rives, V; Pillinger, M; Valente, AA
2006, JOURNAL OF CATALYSIS, 244, 2, 230-237.

Synthesis and characterization of layered double hydroxides intercalated by an oxomolybdenum complex

Gago, S; Dias, AS; Monteiro, B; Pillinger, M; Valente, AA; Santos, TM; Goncalves, IS
2006, JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 67, 5-6, 1011-1015.

Mesoporous silica-supported 12-tungstophosphoric acid catalysts for the liquid phase dehydration of D-xylose

Dias, AS; Pillinger, M; Valente, AA
2006, MICROPOROUS AND MESOPOROUS MATERIALS, 94, 1-3, 214-225.

Optically functional nanocomposites with poly(oxyethylene)-based di-ureasils and mesoporous MCM-41

Fu, LS; Ferreira, RAS; Valente, A; Rocha, J; Carlos, LD
2006, MICROPOROUS AND MESOPOROUS MATERIALS, 94, 1-3, 185-192.

Molybdenum(VI) oxides bearing 1,4,7-triazacyclononane and 1,1,1-tris(aminomethyl)ethane ligands: Synthesis and catalytic applications

Petrovski, Z; Valente, AA; Pillinger, M; Dias, AS; Rodrigues, SS; Romao, CC; Goncalves, IS
2006, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 249, 1-2, 166-171.

Hepta-coordinate halocarbonyl molybdenum(II) and tungsten(II) complexes as heterogeneous polymerization catalysts

Gimenez, J; Nunes, CD; Vaz, PD; Valente, AA; Ferreira, P; Calhorda, MJ
2006, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 256, 1-2, 90-98.

Synthesis and catalytic properties in olefin epoxidation of chiral oxazoline dioxomolybdenum(VI) complexes

Bruno, SM; Monteiro, B; Balula, MS; Pedro, FM; Abrantes, M; Valente, AA; Pillinger, M; Ribeiro-Claro, P; Kuhn, FE; Goncalves, IS
2006, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 260, 1-2, 11-18.

Mixed conductivity and electrocatalytic performance of SrFeO3-delta-SrAl2O4 composite membranes

Yaremchenko, AA; Kharton, VV; Valente, AA; Shaula, AL; Marques, FMB; Rocha, J
2006, SOLID STATE IONICS, 177, 26-32, 2285-2289.

Methane oxidation over SOFC anodes with nanocrystalline ceria-based phases

Kharton, VV; Yaremchenko, AA; Valente, AA; Frolova, EV; Ivanovskaya, MI; Frade, JR; Marques, FMB; Rocha, J
2006, SOLID STATE IONICS, 177, 19-25, 2179-2183.

Catalytic properties of the dioxomolybdenum siloxide MoO2(OSiPh3)(2) and its 2,2 '-bipyridine adduct MoO2(OSiPh3)(2)(bpy)

Bruno, SM; Monteiro, B; Balula, MS; Lourenco, C; Valente, AA; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2006, MOLECULES, 11, 4, 298-308.

Kinetics of cyclooctene epoxidation with tert-butyl hydroperoxide in the presence of [MoO2X2L]-type catalysts (L = bidentate Lewis base)

Al-Ajlouni, A; Valente, AA; Nunes, CD; Pillinger, M; Santos, AM; Zhao, J; Romao, CC; Goncalves, IS; Kuhn, FE
2005, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 9, 1716-1723.

Transport and electrocatalytic properties of La0.3Sr0.7Co0.8Ga0.2O3-delta membranes

Kharton, VV; Tsipis, EV; Marozau, IP; Yaremchenko, AA; Valente, AA; Viskup, AP; Frade, JR; Naumovich, EN; Rocha, J
2005, JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 9, 1, 10-20.

CpMo(CO)(3)Cl as a precatalyst for the epoxidation of olefins

Valente, AA; Seixas, JD; Goncalves, IS; Abrantes, M; Pillinger, M; Romao, CC
2005, CATALYSIS LETTERS, 101, 1-2, 127-130.

Mossbauer spectra and catalytic behavior of perovskite-like SrFe0.7Al0.3O3-delta

Kharton, VV; Waerenborgh, JC; Rojas, DP; Yaremchenko, AA; Valente, AA; Shaula, AL; Patrakeev, MV; Marques, FMB; Rocha, J
2005, CATALYSIS LETTERS, 99, 3-4, 249-255.

Liquid phase dehydration Of D-xylose in the presence of Keggin-type heteropolyacids

Dias, AS; Pillinger, M; Valente, AA
2005, APPLIED CATALYSIS A-GENERAL, 285, 1-2, 126-131.

Dehydration of xylose into furfural over micro-mesoporous sulfonic acid catalysts

Dias, AS; Pillinger, M; Valente, AA
2005, JOURNAL OF CATALYSIS, 229, 2, 414-423.

Processing, stability and oxygen permeability of Sr(Fe, Al)O-3-based ceramic membranes

Kharton, VV; Shaula, AL; Snijkers, FMM; Cooymans, JFC; Luyten, JJ; Yaremchenko, AA; Valente, AA; Tsipis, EV; Frade, JR; Marques, FMB; Rocha, J
2005, JOURNAL OF MEMBRANE SCIENCE, 252, 1-2, 215-225.

Preparation and catalytic studies of bis(halogeno) dioxomolybdenum(VI)-diimine complexes

Petrovski, Z; Pillinger, M; Valente, AA; Goncalves, IS; Hazell, A; Romao, CC
2005, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 227, 1-2, 67-73.

Asymmetric cationic methyl pyridyl and pentafluorophenyl porphyrin encapsulated in zeolites: A cytochrome P-450 model

Skrobot, FC; Rosa, ILV; Marques, APA; Martins, PR; Rocha, J; Valente, AA; Iamamoto, Y
2005, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 237, 1-2, 86-92.

Organotin-oxomolybdate coordination polymers as catalysts for the epoxidation of cyclooctene

Abrantes, M; Valente, AA; Goncalves, IS; Pillinger, M; Romao, CC
2005, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 238, 1-2, 51-55.

Methane oxidation over Fe-, Co-, Ni- and V-containing mixed conductors

Kharton, VV; Yaremchenko, AA; Valente, AA; Sobyanin, VA; Belyaev, VD; Semin, GL; Veniaminov, SA; Tsipis, EV; Shaula, AL; Frade, JR; Rocha, J
2005, SOLID STATE IONICS, 176, 7-8, 781-791.

Highly luminescent tris(beta-diketonate)europium(III) complexes immobilized in a functionalized mesoporous silica

Gago, S; Fernandes, JA; Rainho, JP; Ferreira, RAS; Pillinger, M; Valente, AA; Santos, TM; Carlos, LD; Ribeiro-Claro, PJA; Goncalves, IS
2005, CHEMISTRY OF MATERIALS, 17, 20, 5077-5084.

Incorporation of a (cyclopentadienyl)molybdenum oxo complex in MCM-41 and its use as a catalyst for olefin epoxidation

Abrantes, M; Gago, S; Valente, AA; Pillinger, M; Goncalves, IS; Santos, TM; Rocha, J; Romao, CC
2004, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 24, 4914-4920.

Characterization of mixed-conducting La2Ni0.9Co0.1O4+delta membranes for dry methane oxidation

Kharton, VV; Yaremchenko, AA; Tsipis, EV; Valente, AA; Patrakeev, MV; Shaula, AL; Frade, JR; Rocha, J
2004, APPLIED CATALYSIS A-GENERAL, 261, 1, 25-35.

First stoichiometric large-pore chromium(III) silicate catalyst

Brandao, P; Valente, A; Ferreira, A; Amaral, VS; Rocha, J
2004, MICROPOROUS AND MESOPOROUS MATERIALS, 69, 3, 209-215.

Synthesis and characterization of a manganese(II) acetonitrile complex supported on functionalized MCM-41

Gago, S; Zhang, YM; Santos, AM; Kohler, K; Kuhn, FE; Fernandes, JA; Pillinger, M; Valente, AA; Santos, TM; Ribeiro-Claro, PJA; Goncalves, IS
2004, MICROPOROUS AND MESOPOROUS MATERIALS, 76, 1-3, 131-136.

Epoxidation of cyclooctene catalyzed by dioxomolybdenum(VI) complexes in ionic liquids

Valente, AA; Petrovski, Z; Branco, LC; Afonso, CAM; Pillinger, M; Lopes, AD; Romao, CC; Nunes, CD; Goncalves, IS
2004, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 218, 1, 5-11.

Immobilization of oxomolybdenum species in a layered double hydroxide pillared by 2,2 '-bipyridine-5,5 '-dicarboxylate anions

Gago, S; Pillinger, M; Valente, AA; Santos, TM; Rocha, J; Goncalves, IS
2004, INORGANIC CHEMISTRY, 43, 17, 5422-5431.

Dichloro and dimethyl dioxomolybdenum(VI)-diazabutadiene complexes as catalysts for the epoxidation of olefins

Valente, AA; Moreira, J; Lopes, AD; Pillinger, M; Nunes, CD; Romao, CC; Kuhn, FE; Goncalves, IS
2004, NEW JOURNAL OF CHEMISTRY, 28, 2, 308-313.

Hydrothermal synthesis and characterisation of two novel large-pore framework vanadium silicates

Brandao, P; Valente, A; Philippou, A; Ferreira, A; Anderson, MW; Rocha, J
2003, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 6, 1175-1180.

Preparation and characterization of organotin - Oxomolybdate coordination polymers and their use in sulfoxidation catalysis

Abrantes, M; Valente, AA; Pillinger, M; Goncalves, IS; Rocha, J; Romao, CC
2003, CHEMISTRY-A EUROPEAN JOURNAL, 9, 12, 2685-+.

Molecular structure - Activity relationships for the oxidation of organic compounds using mesoporous silica catalysts derivatised with bis(halogeno)dioxomolybdenum(VI) complexes

Nunes, CD; Valente, AA; Pillinger, M; Rocha, J; Goncalves, IS
2003, CHEMISTRY-A EUROPEAN JOURNAL, 9, 18, 4380-4390.

Dioxomolybdenum(VI)-modified mesoporous MCM-41 and MCM-48 materials for the catalytic epoxidation of olefins

Nunes, CD; Pillinger, M; Valente, AA; Rocha, J; Lopes, AD; Goncalves, IS
2003, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 21, 3870-3877.

Oxidation of pinane over phthalocyanine complexes supported on activated carbon: Effect of the support surface treatment

Valente, A; Palma, C; Fonseca, IM; Ramos, AM; Vital, J
2003, CARBON, 41, 14, 2793-2803.

Preparation and catalytic properties of a new dioxomolybdenum(VI) complex covalently anchored to mesoporous MCM-48

Nunes, CD; Pillinger, M; Valente, AA; Lopes, AD; Goncalves, IS
2003, INORGANIC CHEMISTRY COMMUNICATIONS, 6, 9, 1228-1233.

Direct oxidation of dry methane on nanocrystalline Ce0.8Gd0.2O2-delta/Pt anodes

Yaremchenko, AA; Valente, AA; Kharton, VV; Bashmakov, IA; Rocha, J; Marques, FMB
2003, CATALYSIS COMMUNICATIONS, 4, 9, 477-483.

Oxidation of dry methane on the surface of oxygen ion-conducting membranes

Yaremchenko, AA; Valente, AA; Kharton, VV; Tsipis, EV; Frade, JR; Naumovich, EN; Rocha, J; Marques, FMB
2003, CATALYSIS LETTERS, 91, 3-4, 169-174.

Ordered benzene-silica hybrids with molecular-scale periodicity in the walls and different mesopore sizes

Bion, N; Ferreira, P; Valente, A; Goncalves, IS; Rocha, J
2003, JOURNAL OF MATERIALS CHEMISTRY, 13, 8, 1910-1913.

Epoxidation of olefins catalyzed by molybdenum-siloxane compounds

Abrantes, M; Valente, AA; Pillinger, M; Goncalves, IS; Rocha, J; Romao, CC
2002, INORGANIC CHEMISTRY COMMUNICATIONS, 5, 12, 1069-1072.

Patents

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