Ana Sofia Madureira Bruno

Auxiliary Researcher

Short CV

  • Researcher at the associated laboratory CICECO since 2019
  • Post-doctoral associate at the associated laboratory CICECO, 2009-2019
  • X-Ray Diffraction technician at the Central Analysis Laboratory of the University of Aveiro, 2009
  • PhD degree in Chemistry by the University of Aveiro, Department of Chemistry under the direction of Prof. Isabel Sousa Gonçalves and Prof. Paulo Ribeiro Claro, 2009
  • Graduation in Chemistry by the Faculty of Sciences of the University of Lisbon, including a 9 month stay at the University of Bourgogne, Dijon, France, 2004

Scientific Interests

  • Organometallic complexes
  • Immobilization and impregnation of organometallic oxides and carbonyl derivatives
  • Homogeneous and heterogenous catalysts
  • Oxidation catalysis
  • Acid-catalyzed alcoholysis of epoxides
  • Catalytic isomerization of monoterpenes

Main present collaborators

  • Professor Isabel Gonçalves
  • Professor Paulo Ribeiro Claro
  • Professor Luís Dias Carlos
  • Professor Carlos Romão (ITQB-UNL)
  • Dr Maria Rute Sá Ferreira
  • Dr Susana Santos Braga
  • Dr Filipe Paz
  • Dr Marta Abrantes (IST-UTL)
  • Dr Carla Gamelas (ITQB-UNL)

Publications

Catalytic studies of homo/heterogeneous (pre)catalysts for acid-catalysed reactions

Heterogeneous (pre)catalysts

  •  “Catalytic alcoholysis of epoxides using metal-free cucurbituril-based solids”, Sofia M. Bruno, Ana C. Gomes, Tânia S. M. Oliveira, Margarida M. Antunes, André D. Lopes, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Organic & Biomolecular Chemistry, 14 (2016) 3873-3877. DOI
  • "Catalytic isomerization of alfa–pinene oxide in the presence of ETS-10 supported ferricinium ions", Sofia M. Bruno, Ana C. Gomes, Ana C. Coelho, Paula Brandão, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Journal of Organometallic Chemistry, 791 (2015) 66-71. DOI

 Homogeneous (pre)catalysts

  • "Efficient isomerization of a-pinene oxide to campholenic aldehyde promoted by a mixed-ring analogue of molybdenocene", Sofia M. Bruno, Anabela A. Valente, Martyn Pillinger, Jeffrey Amelse, Carlos C. Romão, Isabel S. Gonçalves, ACS Sustainable Chem. Eng., 7 (2019) 13639-13645. DOI
  • "Acid-catalyzed epoxide alcoholysis in the presence of indenyl molybdenum carbonyl complexes", Sofia M. Bruno, Isabel S. Gonçalves, Martyn Pillinger, Carlos C. Romão, Anabela A. Valente, Journal of Organometallic Chemistry, 855 (2018) 12-17. DOI
  • Acid-catalysed epoxide ring-opening reactions promoted by organometallic complexes of the type [(η5-C5H4-R)Mo(CO)23-C3H5)] and [(η5-C5H5)Mo(CO)3(CH2R)]”, Sofia M. Bruno, Ana C. Gomes, Marta Abrantes, Martyn Pillinger, Isabel S. Gonçalves, Anabela A. Valente, Journal of Organometallic Chemistry, 799-800 (2015) 179-183. DOI
  • "Application of an indenyl molybdenum dicarbonyl complex in the isomerisation of alpha-pinene oxide to campholenic aldehyde", Sofia M. Bruno, Ana C. Gomes, Carla A. Gamelas, Marta Abrantes, Maria Conceição Oliveira, Anabela A. Valente, Filipe A. Almeida Paz, Martyn Pillinger, Carlos C. Romão, Iisabel S. Gonçalves, New Journal of Chemistry, 38 (2014) 3172-3180. DOI
  • "Isomerization of alfa-pinene oxide in the presence of methyltrioxorhenium(VII)", Sofia M. Bruno, Martyn Pillinger, Fritz E. Kühn, Isabel S. Gonçalves, Anabela A. Valente, Catalysis Communications, 35 (2013) 40-44. DOI
  • "Isomerization of alpha-pinene oxide in the presence of indenyl allyl dicarbonyl molybdenum(II) and tungsten(II) complexes", Sofia M. Bruno, Carla A. Gamelas, Ana C. Gomes, Anabela A. Valente, Martyn Pillinger, Carlos C. Romão, Isabel S. Gonçalves, Catalysis Communications, 23 (2012) 58-61. DOI

 

Catalytic studies of homo/heterogeneous (pre)catalysts for sulfoxidation

  • "Oxidation of sulfides in aqueous media catalyzed by pyrazole-oxidoperoxido-molybdenum(VI) complexes", Sofia M. Bruno, Tatiana R. Amarante, Filipe A. Almeida Paz, Martyn Pillinger, Anabela A.Valente, Isabel S.Gonçalves, Inorg. Chim. Acta, 511 (2020) 119814-119819. DOI

 

Catalytic studies of homo/heterogeneous (pre)catalysts for olefin epoxidation

Homogeneous (pre)catalysts

  • "High-yield synthesis and catalytic response of chainlike hybrid materials of the [(MoO3)m(2,2'-bipyridine)n] family", Sofia M. Bruno, Lucie S. Nogueira, Ana C. Gomes, Anabela A. Valente, Isabel S. Gonçalves, Martyn Pillinger, New Journal of Chemistry, 42 (2018) 16483-16492. DOI
  • “Catalytic olefin epoxidation with a carboxylic acid-functionalized cyclopentadienyl molybdenum tricarbonyl complex”, Ana C. Gomes, Sofia M. Bruno, Marta Abrantes, Clara I. R. Magalhães, Isabel S. Gonçalves, Anabela A. Valente, Martyn Pillinger, Journal of Organometallic Chemistry, 760 (2014) 205-211. DOI
  • "Epoxidation of olefins using a dichlorodioxomolybdenum(VI)-pyridylimine complex as catalyst", Salete S. Balula, Sofia M. Bruno, Ana C. Gomes, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Duncan J. Macquarrie, James H. Clark, Inorganica Chimica Acta, 387 (2012) 234-239. DOI
  • "Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor", Marta Abrantes, Sofia M. Bruno, Cátia Tomé, Martyn Pillinger, Isabel S. Gonçalves, Anabela A. Valente, Catalysis Communications, 15 (2011) 64-67. DOI
  • "Synthesis and catalytic properties in olefin epoxidation of dioxomolybdenum(VI) complexes bearing a bidentate or tetradentate salen-type ligand", Sofia M. Bruno, Salete S. Balula, Anabela A. Valente, Filipe A. Almeida Paz, Martyn Pillinger, Carla Sousa, Jacek Klinowski, Cristina Freire, Paulo Ribeiro-Claro, Isabel S. Gonçalves, Journal of Molecular Catalysis A: Chemical, 270 (2007) 185-194. DOI
  • "New chloro and triphenylsiloxy derivatives of dioxomolybdenum(VI) chelated with pyrazolylpyridine ligands: Catalytic applications in olefin epoxidation", Sofia M. Bruno, Cláudia C. L. Pereira, Maria S. Balula, Mariela Nolasco, Anabela A. Valente, Alan Hazell, Martyn Pillinger, Paulo Ribeiro-Claro, Isabel S. Gonçalves, Journal of Molecular Catalysis A: Chemical, 261 (2006) 79-87. DOI
  • "Synthesis and catalytic properties in olefin epoxidation of chiral oxazoline dioxomolybdenum(VI) complexes", Sofia M. Bruno, Bernardo Monteiro, Maria S. Balula, Filipe M. Pedro, Marta Abrantes, Anabela A. Valente, Martyn Pillinger, Paulo Ribeiro-Claro, Fritz E. Kühn, Isabel S. Gonçalves, Journal of Molecular Catalysis A: Chemical, 260 (2006) 11-18. DOI

   Heterogeneous (pre)catalysts in:

        Ordered Mesoporous MCM-41

      • "Epoxidation of cyclooctene using soluble or MCM-41-supported molybdenum tetracarbonyl-pyridylimine complexes as catalyst precursors", Ana C. Gomes, Sofia M. Bruno, Sandra Gago, Rita P. Lopes, David A. Machado, Anna P. Carminatti, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Journal of Organometallic Chemistry, 696 (2011) 3543-3550. DOI
      • "Oxidation of ethylbenzene in the presence of an MCM-41-supported or ionic liquid-standing bischlorocopper(II) complex", Sandra Gago, Sofia M. Bruno, Diogo C. Queirós, Anabela A. Valente, Isabel S. Gonçalves Martyn Pillinger, Catalysis Letters, 141 (2011) 1009-1017. DOI
      • "Dioxomolybdenum(VI) modified mesoporous materials for the catalytic epoxidation of olefins", Sofia M. Bruno, José A. Fernandes, Luísa S. Martins, Isabel S. Gonçalves, Martyn Pillinger, Paulo Ribeiro-Claro, João Rocha, Anabela A. Valente, Catalysis Today, 114 (2006) 263-271. DOI

        Periodic Mesoporous Organosilica

      • “Post-Synthetic Modification of Crystal-Like Periodic Mesoporous Phenylene-Silica with Ferrocenyl Groups”, Ana C. Gomes, Mirtha A. O. Lourenço, Sofia M. Bruno, Paula Ferreira, Anabela A. Valente, Martyn Pillinger, Isabel S. Gonçalves, Journal of Organometallic Chemistry, 751 (2014) 501-507. DOI
      • "Preparation of crystal-like periodic mesoporous phenylene-silica derivatized with ferrocene and its application as a catalyst for the oxidation of styrene", Ana C. Gomes, Maria J. Ferreira, Sofia M. Bruno, Nicolas Bion, Paula Ferreira, Anabela A. Valente, Martyn Pillinger, João Rocha, Isabel S. Gonçalves, Dalton Transactions, 42 (2013) 14612-14620. DOI
      • "Grafting of molecularly ordered mesoporous phenylene-silica with molybdenum carbonyl complexes: efficient heterogeneous catalysts for the epoxidation of olefins", Ana C. Coelho, Salete S. Balula, Sofia M. Bruno, João C. Alonso, Nicolas Bion, Paula Ferreira, Martyn Pillinger, Anabela A. Valente, João Rocha, Isabel S. Gonçalves, Advanced Synthesis and Catalysis, 352 (2010) 1759-1769. DOI

       Layered Double Hydroxide

      • "Intercalation of a molybdenum(0)-tetracarbonyl-bipyridine complex in a layered double hydroxide", Ana C. Gomes, Sofia M. Bruno, Anabela A. Valente, Isabel S. Gonçalves, Martyn Pillinger, Journal of Organometallic Chemistry, 744 (2013) 53-59. DOI
      • "Intercalation of a molybdenum eta3-allyl dicarbonyl complex in a layered double hydroxide and catalytic performance in olefin epoxidation", Ana C. Gomes, Sofia M. Bruno, Carla A. Gamelas, Anabela A. Valente, Marta Abrantes, Isabel S. Gonçalves, Carlos C. Romão, Martyn Pillinger, Dalton, 42 (2013) 8231-8240. DOI

       Cyclodextrins

      • "Synthesis and characterization of CpMo(CO)3(CH2PhCO2CH3) and its inclusion compounds with methylated cyclodextrins. Applications in Olefin Epoxidation Catalysis", Ana C. Gomes, Sofia M. Bruno, Cátia Tomé, Anabela A. Valente, Martyn Pillinger, Marta Abrantes, Isabel S. Gonçalves, Journal of Organometallic Chemistry, 730 (2013) 116-122. DOI

       Metal-Organic Frameworks

      • "Photoluminescent Metal-Organic Frameworks: Rapid Preparations, Catalytic Activity and Framework Relationships", Patrícia Silva, Duarte Ananias, Sofia M. Bruno, Anabela A. Valente, Luís Dias Carlos, João Rocha, Filipe A. Almeida Paz, European Journal of Inorganic Chemistry, 2013 (2013) 5576-5591. DOI
      • "Thermal transformation of a layered multi-functional network into a metal-organic framework based on a polymeric organic linker", Patrícia Silva, Fabiana Vieira, Ana C. Gomes, Duarte Ananias, José A. Fernandes, Sofia M. Bruno, Rosário Soares, Anabela A. Valente, João Rocha, Filipe A. Almeida Paz, Journal of American Chemical Society, 133 (2011) 15120-15138. DOI

 

Cytotoxic studies

  • "Structural studies and cytotoxicity of trimethyl(ferrocenylmethyl)ammonium iodide encapsulated in ß-Cyclodextrin", Sofia M. Bruno, José A. Fernandes, Joana Marques, Sara C. Neto, Paulo J. Ribeiro-Claro, Martyn Pillinger, Filipe A. Almeida Paz, Maria Paula M. Marques, Susana S. Braga, Isabel S. Gonçalves, European Journal of Inorganic Chemistry, 32 (2011) 4955-4963. DOI

 

Photoluminescence studies

  • "Crystal structure and temperature-dependent luminescence of a heterotetranuclear sodium-europium(III) β-diketone complex", Sofia M. Bruno, Duarte Ananias, Filipe Almeida A. Paz, Martyn Pillinger, Anabela A. Valente, Luís D. Carlos, Isabel S. Gonçalves, Dalton Trans., 44 (2015) 488-492. DOI
  • "Structural and photoluminescence studies of a europium(III) tetrakis(ß-diketonate) complex with tetrabutylammonium, imidazolium, pyridinium and silica-supported imidazolium counterions", Sofia M. Bruno, Rute A. Sá Ferreira, Filipe A. Almeida Paz, Luís D. Carlos, Martyn Pillinger, Paulo Ribeiro-Claro, Isabel S. Gonçalves, Inorganic Chemistry, 48 (2009) 4882-4895. DOI
  • "MCM-41 derivatised with pyridyl groups and its use as a support for luminescent europium(III) complexes", Sofia M. Bruno, Ana C. Coelho, Rute A. Sá Ferreira, Luís D. Carlos, Martyn Pillinger, Anabela A. Valente, Paulo Ribeiro-Claro, Isabel S. Gonçalves, European Journal of Inorganic Chemistry, (2008) 3786-3795. DOI
  • "Synthesis, characterisation and luminescence properties of MCM-41 impregnated with an Eu3+ ß-diketonate complex", Sofia M. Bruno, Rute A. Sá Ferreira, Luís D. Carlos, Martyn Pillinger, Paulo Ribeiro-Claro, Isabel S. Gonçalves, Microporous and Mesoporous Materials, 113 (2008) 453-462. DOI

 

Lanthanide borohydrides for polymerization

  • "Lanthanide Borohydrido Complexes for MMA Polymerisation: Syndio- versus Iso- Stereocontrol", Denise Barbier-Baudry, Frédéric Bouyer, Ana Sofia Madureira Bruno, Marc Visseaux, Applied Organometallic Chemistry, 20 (2006) 24-31. DOI

Publications

One-Pot Intercalation Strategy for the Encapsulation of a CO-Releasing Organometallic Molecule in a Layered Double Hydroxide

Calhau, IB; Gomes, AC; Bruno, SM; Coelho, AC; Magalhaes, CIR; Romao, CC; Valente, AA; Goncalves, IS; Pillinger, M
2020, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 28, 2726-2736.
ISBN: 1099-0682

Efficient Isomerization of alpha-Pinene Oxide to Campholenic Aldehyde Promoted by a Mixed-Ring Analogue of Molybdenocene

Bruno, SM; Valente, AA; Pillinger, M; Arnelse, J; Romao, CC; Goncalves, IS
2019, ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 7, 16, 13639-13645.

Acid-catalyzed epoxide alcoholysis in the presence of indenyl molybdenum carbonyl complexes

Bruno, SM; Goncalves, IS; Pillinger, M; Romao, CC; Valente, AA
2018, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 855, 12-17.

High-yield synthesis and catalytic response of chainlike hybrid materials of the [(MoO3)(m)(2,2 '-bipyridine)(n)] family

Bruno, SM; Nogueira, LS; Gomes, AC; Valente, AA; Goncalves, IS; Pillinger, M
2018, NEW JOURNAL OF CHEMISTRY, 42, 20, 16483-16492.

Urinary Free Cortisol: Interference in the Determination

Prazeres, S; Bruno, SM; da Silva, TN; Godinho, C; Proenca, H; Rodrigues, I; Pinheiro, J; Castro, R; Mendo, S; Madureira, D
2017, REVISTA PORTUGUESA DE ENDOCRINOLOGIA DIABETES E METABOLISMO, 12, 1, 2-8.

Catalytic alcoholysis of epoxides using metal-free cucurbituril-based solids

Bruno, SM; Gomes, AC; Oliveira, TSM; Antunes, MM; Lopes, AD; Valente, AA; Goncalves, IS; Pillinger, M
2016, ORGANIC & BIOMOLECULAR CHEMISTRY, 14, 16, 3873-3877.

Crystal structure and temperature-dependent luminescence of a heterotetranuclear sodium-europium(III) beta-diketonate complex

Bruno, SM; Ananias, D; Paz, FAA; Pillinger, M; Valente, AA; Carlos, LD; Goncalves, IS
2015, DALTON TRANSACTIONS, 44, 2, 488-492.

Ring-opening of epoxides promoted by organomolybdenum complexes of the type [eta(5)-C5H4R)mo(CO)(2)(773-C3H5)] and [(eta(5)-C5H5) Mo(CO)(3)(CH2R)]

Bruno, SM; Gomes, AC; Abrantes, M; Valente, AA; Pillinger, M; Goncalves, IS
2015, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 799-800, 179-183.

Catalytic isomerisation of alpha-pinene oxide in the presence of ETS-10 supported ferrocenium ions

Bruno, SM; Gomes, AC; Coelho, AC; Brandao, P; Valente, AA; Pillinger, M; Goncalves, IS
2015, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 791, 66-71.

Catalytic olefin epoxidation with a carboxylic acid-functionalized cyclopentadienyl molybdenum tricarbonyl complex

Gomes, AC; Bruno, SM; Abrantes, M; Magalhaes, CIR; Goncalves, IS; Valente, AA; Pillinger, M
2014, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 760, 205-211.

Post-synthetic modification of crystal-like periodic mesoporous phenylene-silica with ferrocenyl groups

Gomes, AC; Lourenco, MAO; Bruno, SM; Ferreira, P; Valente, AA; Pillinger, M; Goncalves, IS
2014, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 751, 501-507.

Application of an indenyl molybdenum dicarbonyl complex in the isomerisation of alpha-pinene oxide to campholenic aldehyde

Bruno, SM; Gomes, AC; Gamelas, CA; Abrantes, M; Oliveira, MC; Valente, AA; Paz, FAA; Pillinger, M; Romao, CC; Goncalves, IS
2014, NEW JOURNAL OF CHEMISTRY, 38, 7, 3172-3180.

Isomerization of alpha-pinene oxide in the presence of methyltrioxorhenium(VII)

Bruno, SM; Pillinger, M; Kuhn, FE; Goncalves, IS; Valente, AA
2013, CATALYSIS COMMUNICATIONS, 35, 40-44.

Synthesis and characterization of CpMo(CO)(3)(CH2-pC(6)H(4)-CO2CH3) and its inclusion compounds with methylated cyclodextrins. Applications in olefin epoxidation catalysis

Gomes, AC; Bruno, SM; Tome, C; Valente, AA; Pillinger, M; Abrantes, M; Goncalves, IS
2013, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 730, 116-122.

Intercalation of a molybdenum eta(3)-allyl dicarbonyl complex in a layered double hydroxide and catalytic performance in olefin epoxidation

Gomes, AC; Bruno, SM; Gamelas, CA; Valente, AA; Abrantes, M; Goncalves, IS; Romao, CC; Pillinger, M
2013, DALTON TRANSACTIONS, 42, 23, 8231-8240.

Preparation of crystal-like periodic mesoporous phenylene-silica derivatized with ferrocene and its use as a catalyst for the oxidation of styrene

Gomes, AC; Ferreira, MJ; Bruno, SM; Bion, N; Ferreira, P; Valente, AA; Pillinger, M; Rocha, J; Goncalves, IS
2013, DALTON TRANSACTIONS, 42, 40, 14612-14620.

Photoluminescent Metal-Organic Frameworks - Rapid Preparation, Catalytic Activity, and Framework Relationships

Silva, P; Ananias, D; Bruno, SM; Valente, AA; Carlos, LD; Rocha, J; Paz, FAA
2013, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 32, 5576-5591.

Intercalation of a molybdenum(0)-tetracarbonyl-bipyridine complex in a layered double hydroxide

Gomes, AC; Bruno, SM; Valente, AA; Goncalves, IS; Pillinger, M
2013, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 744, 53-59.

Isomerisation of alpha-pinene oxide in the presence of indenyl allyl dicarbonyl molybdenum(II) and tungsten(II) complexes

Bruno, SM; Gamelas, CA; Gomes, AC; Valente, AA; Pillinger, M; Romao, CC; Goncalves, IS
2012, CATALYSIS COMMUNICATIONS, 23, 58-61.

Epoxidation of olefins using a dichlorodioxomolybdenum(VI)-pyridylimine complex as catalyst

Balula, SS; Bruno, SM; Gomes, AC; Valente, AA; Pillinger, M; Goncalves, IS; Macquarrie, DJ; Clark, JH
2012, INORGANICA CHIMICA ACTA, 387, 234-239.

Molybdenum(VI) catalysts obtained from eta(3)-allyl dicarbonyl precursors: Synthesis, characterization and catalytic performance in cyclooctene epoxidation

Gamelas, CA; Gomes, AC; Bruno, SM; Paz, FAA; Valente, AA; Pillinger, M; Romao, CC; Goncalves, IS
2012, DALTON TRANSACTIONS, 41, 12, 3474-3484.

[(E )-1-(Naphthalen-2-yl)ethylidene](naphthalen-1- ylmethyl)amine

Sofia M. Bruno, José A. Fernandes, Isabel S. Gonçalves, Filipe A. Almeida Paz
2012, ACTA CRYSTALLOGRAPHICA SECTION E, E68.

Structural Studies and Cytotoxicity of Trimethyl(ferrocenylmethyl)ammonium Iodide Encapsulated in beta-Cyclodextrin

Bruno, SM; Fernandes, JA; Marques, J; Neto, SC; Ribeiro-Claro, PJ; Pillinger, M; Paz, FAA; Marques, MPM; Braga, SS; Goncalves, IS
2011, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 32, 4955-4963.

Oxidation of Ethylbenzene in the Presence of an MCM-41-Supported or Ionic Liquid-Standing Bischlorocopper(II) Complex

Gago, S; Bruno, SM; Queiros, DC; Valente, AA; Goncalves, IS; Pillinger, M
2011, CATALYSIS LETTERS, 141, 7, 1009-1017.

Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor

Abrantes, M; Bruno, SM; Tome, C; Pillinger, M; Goncalves, IS; Valente, AA
2011, CATALYSIS COMMUNICATIONS, 15, 1, 64-67.

Epoxidation of cyclooctene using soluble or MCM-41-supported molybdenum tetracarbonyl-pyridylimine complexes as catalyst precursors

Gomes, AC; Bruno, SM; Gago, S; Lopes, RP; Machado, DA; Carminatti, AP; Valente, AA; Pillinger, M; Goncalves, IS
2011, JOURNAL OF ORGANOMETALLIC CHEMISTRY, 696, 22, 3543-3550.

Thermal Transformation of a Layered Multifunctional Network into a Metal-Organic Framework Based on a Polymeric Organic Linker

Silva, P; Vieira, F; Gomes, AC; Ananias, D; Fernandes, JA; Bruno, SM; Soares, R; Valente, AA; Rocha, J; Paz, FAA
2011, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 133, 38, 15120-15138.

Propylammonium 4,4,4-trifluoro-1-(naphthalen-2-yl)butane-1,3-dionate

Fernandes, JA; Bruno, SM; Goncalves, IS; Paz, FAA
2011, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 67, O3384-U938.

Grafting of Molecularly Ordered Mesoporous Phenylene-Silica with Molybdenum Carbonyl Complexes: Efficient Heterogeneous Catalysts for the Epoxidation of Olefins

Coelho, AC; Balula, SS; Bruno, SM; Alonso, JC; Bion, N; Ferreira, P; Pillinger, M; Valente, AA; Rocha, J; Goncalves, IS
2010, ADVANCED SYNTHESIS & CATALYSIS, 352, 10, 1759-1769.

Structural and Photoluminescence Studies of a Europium(III) Tetrakis (beta-diketonate) Complex with Tetrabutylammonium, Imidazolium, Pyridinium and Silica-Supported Imidazolium Counterions

Bruno, SM; Ferreira, RAS; Paz, FAA; Carlos, LD; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2009, INORGANIC CHEMISTRY, 48, 11, 4882-4895.

MCM-41 derivatised with pyridyl groups and its use as a support for luminescent europium(III) complexes

Bruno, SM; Coelho, AC; Ferreira, RAS; Carlos, LD; Pillinger, M; Valente, AA; Ribeiro-Claro, P; Goncalves, IS
2008, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 24, 3786-3795.

Synthesis, characterisation and luminescence properties of MCM-41 impregnated with an Eu3+ beta-diketonate complex

Bruno, SM; Ferreira, RAS; Carlos, LD; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2008, MICROPOROUS AND MESOPOROUS MATERIALS, 113, 1-3, 453-462.

New chloro and triphenylsiloxy derivatives of dioxomolybdenum(VI) chelated with pyrazolylpyridine ligands: Catalytic applications in olefin epoxidation

Bruno, SM; Pereira, CCL; Balula, MS; Nolasco, M; Valente, AA; Hazell, A; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2007, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 261, 1, 79-87.

Synthesis and catalytic properties in olefin epoxidation of dioxomolybdenurn(VI) complexes bearing a bidentate or tetradentate salen-type ligand

Bruno, SM; Balula, SS; Valente, AA; Paz, FAA; Pillinger, M; Sousa, C; Klinowski, J; Freire, C; Ribeiro-Claro, P; Goncalves, IS
2007, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 270, 1-2, 185-194.

Dioxomolybdenum(VI) modified mesoporous materials for the catalytic epoxidation of olefins

Bruno, SM; Fernandes, JA; Martins, LS; Goncalves, IS; Pillinger, M; Ribeiro-Claro, P; Rocha, J; Valente, AA
2006, CATALYSIS TODAY, 114, 2-3, 263-271.

Synthesis and catalytic properties in olefin epoxidation of chiral oxazoline dioxomolybdenum(VI) complexes

Bruno, SM; Monteiro, B; Balula, MS; Pedro, FM; Abrantes, M; Valente, AA; Pillinger, M; Ribeiro-Claro, P; Kuhn, FE; Goncalves, IS
2006, JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 260, 1-2, 11-18.

Catalytic properties of the dioxomolybdenum siloxide MoO2(OSiPh3)(2) and its 2,2 '-bipyridine adduct MoO2(OSiPh3)(2)(bpy)

Bruno, SM; Monteiro, B; Balula, MS; Lourenco, C; Valente, AA; Pillinger, M; Ribeiro-Claro, P; Goncalves, IS
2006, MOLECULES, 11, 4, 298-308.

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